Search results for " Materials Science"
showing 10 items of 7414 documents
Biodegradable Ultrasmall-in-Nano Gold Architectures: Mid-Period In Vivo Distribution and Excretion Assessment
2018
Crystal structure and Hirshfeld surface analysis of (Z)-4-chloro-N′-(4-oxothiazolidin-2-ylidene)benzenesulfonohydrazide monohydrate
2018
The asymmetric unit of the title thiazole derivative containing a sulfonylhydrazinic moiety, C9H8ClN3O3S2·H2O, consists of two independent molecules and two water molecules. The central parts of the molecules are twisted as both the molecules are bent at both the S and N atoms. In the crystal, N—H...N, N—H...O, C—H...O and O—H...O hydrogen-bonding interactions connect the molecules, forming layers parallel to the ab plane. Two-dimensional fingerprint plots associated with the Hirshfeld surface show that the largest contributions to the crystal packing come from O...H/H...O (32.9%) and H...H (22.6%) interactions.
Tunable Interaction Strength and Nature of the S···Br Halogen Bonds in [(Thione)Br2] Systems
2015
The strength and nature of the S···Br and Br···Br interactions were systematically tuned by altering the electron donor properties of the thione group. Three new halogen-bonded compounds, [(N-methylbenzothiazole-2-thione)Br2]·0.5CH2Cl2 (1), [(2(3H)-benzothiazolethione)Br2] (2), and [(2-benzimidazolethione)Br]·[Br3] (3), were synthesized and studied structurally by using X-ray crystallography and computationally by using charge density analysis based on QTAIM calculations. Analysis of the interaction strength indicated a formation of surprisingly strong S···Br halogen bonds in 1 (−104 kJ mol–1, and RBrS = 0.64) and 2 (−116 kJ mol–1, and RBrS = 0.63) with a substantial covalent contribution. …
Investigation of Nonlinear Optical Processes in Mercury Sulfide Quantum Dots
2022
European Regional Development Fund (1.1.1.5/19/A/003), State Assignment to Higher Educational Institutions of Russian Federation (FZGU-2020-0035), Russian Foundation for Basic Research (18-29-20062). Institute of Solid State Physics, University of Latvia as the Center of Excellence acknowledges funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.
Photobleaching and Recovery Kinetics of a Palette of Carbon Nanodots Probed by In Situ Optical Spectroscopy
2022
Carbon dots (CDs) are a family of fluorescent nanoparticles displaying a wide range of interesting properties, which make them attractive for potential applications in different fields like bioimaging, photocatalysis, and many others. However, despite many years of dedicated studies, wide variations exist in the literature concerning the reported photostability of CDs, and even the photoluminescence mechanism is still unclear. Furthermore, an increasing number of recent studies have highlighted the photobleaching (PB) of CDs under intense UV or visible light beams. PB phenomena need to be fully addressed to optimize practical uses of CDs and can also provide information on the fundamental m…
Estimation of the Time-Variant Velocity of a Single Walking Person in Two-Dimensional Non-Stationary Indoor Environments Using Radio-Frequency Techni…
2020
Accurate estimation of the time-variant (TV) velocity of moving persons/objects in indoor spaces is of crucial importance for numerous wireless indoor applications. This article introduces a novel iterative procedure to estimate the TV velocity, i.e., TV speed and TV angle-of-motion (AOM), of a single moving person in 2D indoor environments by using radio-frequency (RF) techniques. The indoor area is equipped with a distributed 2 × 2 multiple-input multiple-output (MIMO) system. The proposed method is divided into two parts. In the first part, we estimate the path gains and the instantaneous Doppler frequencies by fitting the exact spectrograms of the complex channel gains of a 2D no…
Calcium mediated polyelectrolyte adsorption on like-charged surfaces.
2011
International audience; Monte Carlo simulations within the primitive model of calcium-mediated adsorption of linear and comb polyelectrolytes onto like-charged surfaces are described, focusing on the effect of calcium and polyion concentrations as well as on the ion pairing between polymers and calcium ions. We use a combination of Monte Carlo simulations and experimental data from titration and calcium binding to quantify the ion pairing. The polymer adsorption is shown to occur as a result of surface overcharging by Ca2+ and ion pairing between charged monomers and Ca2+. In agreement with experimental observations, the simulations predict that the polymer adsorption isotherm goes through …
The Other Side as a Rule Rather than an Exception
2015
Abstract Currently, intercultural and heterogeneous realities set the tone in 21st literary education. Therefore, the role of multicultural children's literature plays an essential role in order to reflect this intercultural diversity in Spanish classrooms. In this regard, The Other Side (2001) portrays an African American experience where interaction, communication and negotiation become crucial aspects for their protagonists. In this way, this picture book can be used not only to teach English as a foreign language in primary school, but also to show values like respect, tolerance and partnership.
Clean Agent Selection Approached by Fuzzy TOPSIS Decision-Making Method
2008
Abstract. It is well known that halons are ozone-depleting substances and their release into the atmosphere has contributed in the last decades to the reduction in the ozone layer. In consequence to the Montreal Protocol, an international agreement designed to gradually eliminate the use of such substances, fire protection industry researchers faced the challenge of finding effective solutions to replace halon extinguishers. This research aims to provide a method to support the decision maker in the selection of the most suitable extinguisher substance for a specific application. According to such framework, a set of quantitative and qualitative criteria has been established in the decision…
L'écart et l'entre-deux : traduire la culture
2011
Comparative linguistics seems to suggest that the gap between two languages can be filled by grammar. But mapping the structural gaps between languages hardly makes for the more fundamental gap that is created by the writing of a new text, a supposedly identical addendum to the first. Writing that new text entails questions about the nature of texts, their intentions, their interpretations. Translation must therefore develop a hermeneutical approach. This critical stance is about sorting out what belongs to the languages and what belongs to the text as a specific unit, as a cultural and authorial unit. Because of its cultural nature, translation questions the way one can carry meaning acros…