Search results for " Opera"
showing 10 items of 3606 documents
[Fe(TPT)(2/3){M(I)(CN)2}2]⋅nSolv (M(I) = Ag, Au): new bimetallic porous coordination polymers with spin-crossover properties.
2013
Two new heterobimetallic porous coordination polymers with the formula [Fe(TPT)2/3{MI(CN)2}2]¿nSolv (TPT=[(2,4,6-tris(4-pyridyl)-1,3,5-triazine]; MI=Ag (nSolv=0, 1¿MeOH, 2¿CH2Cl2), Au (nSolv=0, 2¿CH2Cl2)) have been synthesized and their crystal structures were determined at 120¿K and 293¿K by single-crystal X-ray analysis. These structures crystallized in the trigonal R-3m space group. The FeII ion resides at an inversion centre that defines a [FeN6] coordination core. Four dicyanometallate groups coordinate at the equatorial positions, whilst the axial positions are occupied by the TPT ligand. Each TPT ligand is centred in a ternary axis and bridges three crystallographically equivalent Fe…
Synthesis, structure, and nuclease properties of several binary and ternary complexes of copper(II) with norfloxacin and 1,10 phenantroline
2007
Three new binary Cu(II) complexes of norfloxacin have been synthesized and characterized. We also report the synthesis, characterization and X-ray crystallographic structures of a new binary compound, [Cu(HNor)(2)]Cl(2).2H(2)O (2) and two new ternary complexes norfloxacin-copper(II)-phen, [Cu(Nor)(phen)(H(2)O)](NO(3)).3H(2)O (4), and [Cu(HNor)(phen)(NO(3))](NO(3)).3H(2)O (5). The structure of 2 consists of two crystallographically independent cationic monomeric units of [Cu(HNor)(2)](2+), chloride anions, and uncoordinated water molecules. The Cu(II) ion is placed at a center of symmetry and is coordinated to two norfloxacin ligands which are related through the inversion center. The struct…
Coordination abilities of l-glutamic acid γ-monohydroxamic acid towards copper(II) in the absence and presence of some aliphatic amines
2012
Abstract Solution equilibrium studies on the Cu 2+ –(A)–(Glu-γ-ha) ternary systems ((A) = polyamine: ethylenediamine (en), diethylenetriamine (dien), N , N , N ′, N ″, N ″-pentamethyldiethylenetriamine (Me 5 dien); (Glu-γ-ha) = l -glutamic-γ-hydroxamic acid) have been performed by pH-potentiometry, UV–Vis spectrophotometry and EPR methods. The obtained results suggest the formation of the heteroligand complexes with [Cu(A)(Glu-γ-ha)] + stoichiometry in all studied systems. Our spectroscopic results indicate the tetragonal geometry for the [Cu(en)(Glu-γ-ha)] + species in which Glu-γ-ha acts as a tridentate ligand, the geometry slightly deviated from square pyramidal for [Cu(dien)(Glu-γ-ha)]…
Fluoroquinolone–metal complexes: A route to counteract bacterial resistance?
2014
Abstract Microbial resistance to antibiotics is one of the biggest public health threats of the modern world. Antibiotic resistance is an area of much clinical relevance and therefore research that has the potential to identify agents that may circumvent it or treat resistant infections is paramount. Solution behavior of various fluoroquinolone (FQ) complexes with copper(II) in the presence and absence of 1,10-phenanthroline (phen) was studied in aqueous solution, by potentiometry and/or spectrophotometry, and are herein described. The results obtained showed that under physiological conditions (micromolar concentration range and pH 7.4) only copper(II):FQ:phen ternary complexes are stable.…
Dynamic Demand and Mean-Field Games
2017
Within the realm of smart buildings and smart cities,\ud dynamic response management is playing an ever-increasing\ud role thus attracting the attention of scientists from different\ud disciplines. Dynamic demand response management involves a\ud set of operations aiming at decentralizing the control of loads\ud in large and complex power networks. Each single appliance\ud is fully responsive and readjusts its energy demand to the\ud overall network load. A main issue is related to mains frequency\ud oscillations resulting from an unbalance between supply and\ud demand. In a nutshell, this paper contributes to the topic by\ud equipping each signal consumer with strategic insight. In particu…
A stochastic integral of operator-valued functions.
2009
A stochastic integral of operator-valued functions.
A stochastic method for robustness analysis in sorting problems
2009
ELECTRE TRI is a multiple criteria decision aiding sorting method with a history of successful real-life applications. In ELECTRE TRI, values for certain parameters have to be provided. We propose a new method, SMAA-TRI, that is based on stochastic multicriteria acceptability analysis (SMAA), for analyzing the stability of such parameters. The stability analysis can be used for deriving robust conclusions. SMAA-TRI allows ELECTRE TRI to be used with uncertain, arbitrarily distributed values for weights, the lambda cutting level, and profiles. The method consists of analyzing finite spaces of arbitrarily distributed parameter values. Monte Carlo simulation is applied in this in order to desc…
Itô formula for an integro-differential operator without an associated stochastic process
2010
Heisenberg picture in the description of simplified stock markets
2008
Echi pompeiani ed ercolanesi nella scenografia teatrale del XIX secolo
2010
Tra le opere liriche messe in scena nel primo Ottocento, alcune erano ambientate nell’antichità greco-romana. Per la creazione di scenari che apparissero plausibili gli scenografi talora riproducevano monumenti reali, come quelli di Pompei ed Ercolano.