Search results for " PLASMA"
showing 10 items of 2522 documents
Application of stable isotopes and AF4/ICP-SFMS for simultaneous tracing and quantification of iron oxide nanoparticles in a sediment–slurry matrix
2016
One major challenge in nanomaterial analysis, especially in complex environmental matrices, is the unambiguous differentiation between natural and engineered nanomaterials (ENMs). Particularly with regard to the investigation of ENM's/engineered nanoparticle's (ENPs) fate, analytical methods are needed allowing for tracing and sensitive quantification. Several ENPs are metal-based and contain elements being omnipresent in environmental matrices (e.g., Al, Ti, Zn, Fe and non-metal Si) – hence, high background levels of these elements are expected, compromising sensitive detection. In this work we developed successfully a combined approach of stable isotope labeling (tracing) and reverse post…
Determination of arsenic compounds in beverages by high-performance liquid chromatography-inductively coupled plasma mass spectrometry.
2005
Arsenic compounds including arsenous acid (As(III)), arsenic acid (As(V)), dimethylarsinic acid (DMA) and monomethylarsonic acid (MMA) were separated by high-performance liquid chromatography (HPLC) and detected by inductively coupled plasma mass spectrometry (ICP-MS). A Hamilton PRX-100 anionic-exchange column and a pH 8.5 K(2)HPO(4)/KH(2)PO(4) 5.0x10(-3)molL(-1) mobile phase were used to achieve arsenic speciation. The separation of arsenic species provided peaks of As(III) at 2.75min, DMA at 3.33min, MMA at 5.17min and As(V) at 12.5min. The detection limits, defined as three times the standard deviation of the lowest standard measurements, were found to be 0.2, 0.2, 0.3 and 0.5ngmL(-1) f…
Active alkaline traps to determine acidic-gas ratios in volcanic plumes: Sampling techniques and analytical methods
2014
In situ measurements have been the basis for monitoring volcanic gas emissions for many years and—being complemented by remote sensing techniques—still play an important role to date. Con- cerning in situ techniques for sampling a dilute plume, an increase in accuracy and a reduction of detection limits are still necessary for most gases (e.g., CO2, SO2, HCl, HF, HBr, HI). In this work, the Raschig-Tube tech- nique (RT) is modified and utilized for application on volcanic plumes. The theoretical and experimental absorption properties of the RT and the Drechsel bottle (DB) setups are characterized and both are applied simultaneously to the well-established Filter packs technique (FP) in the …
Development and Optimization of Pre-Concentration Procedure of Rare-Earth Elements (REEs) in Their Minerals, Using Microwave - Assisted Sample Dissol…
2015
Abstract The aim of this research was to develop and optimize a procedure for determination of REEs in xenotime and monazite samples collected from Bangka Island, which were compared to Standard Monazite (71 AG) of Bureau of Analyzed Samples, London. ICP-OES method was used for the determination. The samples were dried and sterilized by heating for a week at 110 °C, before digesting with nitric acid and hydrofluoric acid, using a microwave-assisted digestion system. After a careful line selection, at the detection limits for all REEs in the ng/mL the REEs were reliably obtained at the 0.09 – 38% level.
A Unifying Framework for Perturbative Exponential Factorizations
2021
We propose a framework where Fer and Wilcox expansions for the solution of differential equations are derived from two particular choices for the initial transformation that seeds the product expansion. In this scheme, intermediate expansions can also be envisaged. Recurrence formulas are developed. A new lower bound for the convergence of theWilcox expansion is provided, as well as some applications of the results. In particular, two examples are worked out up to a high order of approximation to illustrate the behavior of the Wilcox expansion.
On critical behaviour in generalized Kadomtsev-Petviashvili equations
2016
International audience; An asymptotic description of the formation of dispersive shock waves in solutions to the generalized Kadomtsev–Petviashvili (KP) equation is conjectured. The asymptotic description based on a multiscales expansion is given in terms of a special solution to an ordinary differential equation of the Painlevé I hierarchy. Several examples are discussed numerically to provide strong evidence for the validity of the conjecture. The numerical study of the long time behaviour of these examples indicates persistence of dispersive shock waves in solutions to the (subcritical) KP equations, while in the supercritical KP equations a blow-up occurs after the formation of the disp…
SPS-assisted preparation of the Magnéli phase WO2.90 for thermoelectric applications
2013
We describe the preparation and simultaneous consolidation of WO2.90 by spark plasma sintering (SPS). SPS allows for the direct manufacturing of large amounts of consolidated material. Synchrotron powder X-ray diffraction indicates that the material is single phase. Microstructure analysis indicates that the pellet is fully dense, allowing high-temperature thermoelectric properties to be reliably measured. The as-prepared samples of WO2.90 reach a ZT of 0.1 at 1100 K.
Efficiency of a digital particle image velocimetry (DPIV) method for monitoring the surface velocity of hyper-concentrated flows
2018
Digital particle image velocimetry records high resolution images and allows the identification of the position of points in different time instants. This paper explores the efficiency of the digital image-technique for remote monitoring of surface velocity and discharge measurement in hyper-concentrated flow by the way of laboratory experiment. One of the challenges in the application of the image-technique is the evaluation of the error in estimating surface velocity. The error quantification is complex because it depends on many factors characterizing either the experimental conditions or/and the processing algorithm. In the present work, attention is devoted to the estimation error due …
New Theoretical Solution of Stage-Discharge Relationship for Slit Weirs
2018
In this paper, the flow-process of a slit weir was analyzed on the basis of a theorem of dimensional analysis and incomplete selfsimilarity theory. The theoretically deduced stage-discharge formula then was calibrated using experimental data obtained for a ratio between the weir and the channel width, ranging from 0.05 to 0.25. The deduced stage-discharge relationship allowed measuring discharge values characterized by errors that, for 98% of the measured values, were less than or equal to 5%. The performance of the proposed theoreticalstage-discharge formula also was improved by introducing the Reynolds number (for 98.5% of the measured values the error was less than or equal to 5%, and th…
Resonance between Cantor sets
2007
Let $C_a$ be the central Cantor set obtained by removing a central interval of length $1-2a$ from the unit interval, and continuing this process inductively on each of the remaining two intervals. We prove that if $\log b/\log a$ is irrational, then \[ \dim(C_a+C_b) = \min(\dim(C_a) + \dim(C_b),1), \] where $\dim$ is Hausdorff dimension. More generally, given two self-similar sets $K,K'$ in $\RR$ and a scaling parameter $s>0$, if the dimension of the arithmetic sum $K+sK'$ is strictly smaller than $\dim(K)+\dim(K') \le 1$ (``geometric resonance''), then there exists $r<1$ such that all contraction ratios of the similitudes defining $K$ and $K'$ are powers of $r$ (``algebraic resonance…