Search results for " Phase"
showing 10 items of 1862 documents
Impact of the ΔPhe configuration on the Boc-Gly-ΔPhe-NHMe conformation: experiment and theory
2019
Conformational propensities of N-t-butoxycarbonyl-glycine-(E/Z)-dehydrophenylalanine N′-methylamides (Boc-Gly-(E/Z)-ΔPhe-NHMe) in chloroform were investigated by NMR and IR techniques. The low-temperature crystal structure of the E isomer was determined by single crystal X-ray diffraction and the experimental data were elaborated by theoretical calculations using DFT (B3LYP, M06-2X) and MP2 approaches. The β-turn tendencies for both isomers were determined in the gas phase and in the presence of solvent. The obtained results reveal that the configuration of ΔPhe residue significantly affects the conformations of the studied dehydropeptides. The tendency to adopt β-turn conformations is sign…
Specific Heat and Transport Functions of Water
2020
Numerous water characteristics are essentially ascribed to its peculiarity to form stronghydrogen bonds that become progressively more stable on decreasing the temperature. However, thestructural and dynamical implications of the molecular rearrangement are still subject of debate andintense studies. In this work, we observe that the thermodynamic characteristics of liquid water arestrictly connected to its dynamic characteristics. In particular, we compare the thermal behaviourof the isobaric specific heat of water, measured in different confinement conditions at atmosphericpressure (and evaluated by means of theoretical studies) with its configurational contribution obtainedfrom the value…
Insights into the compositional evolution of crustal magmatic systems from coupled petrological-geodynamical models
2020
Funding was provided by the VAMOS Research Center, University of Mainz (Germany) and by the ERC Consolidator Grant MAGMA (project #771143). The evolution of crustal magmatic systems is incompletely understood, as most studies are limited either by their temporal or spatial resolution. Exposed plutonic rocks represent the final stage of a long-term evolution punctuated by several magmatic events with different chemistry and generated under different mechanical conditions. Although the final state can be easily described, the nature of each magmatic pulse is more difficult to retrieve. This study presents a new method to investigate the compositional evolution of plutonic systems while consid…
Positive solutions for singular (p, 2)-equations
2019
We consider a nonlinear nonparametric Dirichlet problem driven by the sum of a p-Laplacian and of a Laplacian (a (p, 2)-equation) and a reaction which involves a singular term and a $$(p-1)$$ -superlinear perturbation. Using variational tools and suitable truncation and comparison techniques, we show that the problem has two positive smooth solutions.
Multiple solutions for parametric double phase Dirichlet problems
2020
We consider a parametric double phase Dirichlet problem. Using variational tools together with suitable truncation and comparison techniques, we show that for all parametric values [Formula: see text] the problem has at least three nontrivial solutions, two of which have constant sign. Also, we identify the critical parameter [Formula: see text] precisely in terms of the spectrum of the [Formula: see text]-Laplacian.
Any AND-OR Formula of Size N Can Be Evaluated in Time $N^{1/2+o(1)}$ on a Quantum Computer
2007
Consider the problem of evaluating an AND-OR formula on an $N$-bit black-box input. We present a bounded-error quantum algorithm that solves this problem in time $N^{1/2+o(1)}$. In particular, approximately balanced formulas can be evaluated in $O(\sqrt{N})$ queries, which is optimal. The idea of the algorithm is to apply phase estimation to a discrete-time quantum walk on a weighted tree whose spectrum encodes the value of the formula.
Quantum Random Walks – New Method for Designing Quantum Algorithms
2008
Quantum walks are quantum counterparts of random walks. In the last 5 years, they have become one of main methods of designing quantum algorithms. Quantum walk based algorithms include element distinctness, spatial search, quantum speedup of Markov chains, evaluation of Boolean formulas and search on "glued trees" graph. In this talk, I will describe the quantum walk method for designing search algorithms and show several of its applications.
Copolymerization of VDF and HFP in Supercritical Carbon Dioxide: A Robust Approach for Modeling Precipitation and Dispersion Kinetics
2012
A kinetic model is developed for the heterogeneous free-radical copolymerization of vinylidene fluoride and hexafluoropropylene in supercritical CO 2. The model accounts for polymerization in both the dispersed (polymer-rich) phase and in the continuous (polymer-free) supercritical phase, for radical interphase transport, diffusion limitations, and chain-length-dependent termination in the polymer-rich phase. A parameter evaluation strategy is developed and detailed to estimate most of the kinetic parameters a priori while minimizing their evaluation by direct fitting. The resulting model predictions compare favorably with the experimental results of conversion and MWD at varying monomer fe…
Generation of Bound States of Three Ultrashort Pulses With a Passively Mode-Locked High-Power Yb-Doped Double-Clad Fiber Laser
2004
We report the generation of high-power ultrashort bound states of three pulses in an ytterbium-doped double-clad fiber laser. The laser is mode-locked through nonlinear polarization rotation technique in a unidirectional cavity configuration. A pair of diffraction grating is incorporated in the cavity to compensate for the normal dispersion of the fiber. The laser generates chirped bound states of three pulses with either equal or different time separations, with more than 500-pJ energy per pulse. These pulses are subsequently compressed to 100 fs with a compression factor of more than 40.
A general procedure for the construction of Gorges polygons for multi-phase windings of electrical machines
2018
This paper presents a simple and effective procedure for the determination of the Gorges polygon, suitable for all possible winding configurations in electrical machines. This methodology takes into account the determination of a Winding Distribution Table (WDT), in which all the information about the distribution of the currents along the stator periphery is computed and from which the Görges polygon are easily derived. The proposed method can be applied to both symmetrical and asymmetrical multi-phase windings, including concentrated, fractional, reduced and dead-coil ones. The examples provided in this paper demonstrate the versatility of the proposed method.