Search results for " Phase"
showing 10 items of 1862 documents
Preconcentration and speciation of chromium in waters using solid-phase extraction and atomic absorption spectrometry
2000
Abstract A method for the preconcentration and speciation of chromium was developed. After formation of an anionic compound with ethylenediaminetetraacetic acid (CrY − ), Cr (VI) and Cr (III) are retained on a strong anionic phase (SAX) and controlled elution with 0.5 M NaCl permits their speciation. The retention and elution conditions were optimised, and interferences due to the presence of other ions such as Mg(II), Mn(II), Sn(II), Fe(III), Ba(II), Al(III), Ca(II), chloride, iodine, bromide, fluoride, sulphate, phosphate, bicarbonate and nitrate were studied. The detection limits were 0.4 μg l −1 and 1.1 μg l −1 for Cr(III) and Cr(VI), respectively, and reproducibility was 9%. The result…
Enantiomerization of an inherently chiral resorcarene derivative: determination of the interconversion barrier by computer simulation of the dynamic …
2001
Abstract The inherently chiral tetrabenzoxazine resorcarene derivative 1 shows characteristic plateau-formation during enantioselective HPLC separation on the chiral stationary phase Chiralpak AD. By computer assisted peak form analysis of the elution profiles, obtained from temperature dependent dynamic HPLC (DHPLC) experiments, with ChromWin, the enantiomerization barrier Δ G # (298 K)=92±2 kJ mol −1 and the activation parameters Δ H # =53.0±1.8 kJ mol −1 and Δ S # =−131±14 J (K mol) −1 were determined.
N-Glycosylation modification of proteins is an early marker of the enterocytic differentiation process of HT-29 cells
1990
International audience; The human colon cancer cell line HT-29 remains totally undifferentiated when glucose is present in the culture medium (HT-29 Glc+), while the same cells may undergo typical enterocytic differentiation after reaching confluence when grown in glucose-deprived medium (HT-29 Glc-). Recently, we demonstrated a deficiency in the overall N-glycan processing in confluent undifferentiated cells, whereas differentiated cells follow a classical pattern of N-glycosylation. The main changes in N-glycosylation observed in confluent undifferentiated cells may be summarised as follows: 1) the conversion of high mannose into complex glycopeptides is greatly decreased; 2) this decreas…
New approach for harmonic mitigation in single-phase five-level CHBMI with fundamental frequency switching
2017
The main objective of this paper is to study and analyse the voltage output waveform of a multilevel inverter, to suggest a new approach for harmonic mitigation improving the converter performance. These last type of converters represent a new technology in the field of DC/AC electrical energy conversion, presenting advantages respect to the traditional converters. In fact, the multilevel power converters present a low harmonic content and a high voltage level. The paper considers a five-level single-phase cascaded H-bridge inverter and fundamental frequency modulation techniques. The voltage waveform analysis has allowed to identify a working area of the converter where there are lowest va…
Synchronization techniques for power quality instruments
2004
The measurement of voltage characteristics in power systems requires the accurate estimation of the power supply frequency and signal synchronization, even in the presence of disturbances. The authors developed and tested two innovative techniques for instrument synchronization. The first is based on signal spectral analysis techniques performed by means of the Chirp-Z transform analysis. The second is a phase-locked loop (PLL) software based on a time-domain coordinate transformation and an innovative phase-detection technique. To evaluate how synchronization techniques are adversely affected by the application of a disturbing influence, experimental tests were carried out, taking into acc…
Identification of Defensive Performance Factors in the 2010 FIFA World Cup South Africa
2016
The aim of this study was to determine the efficacy of defensive play in elite football, to identify variables associated with the direct recovery of ball possession, and to propose a model for predicting the success of defensive transitions. We analyzed 804 transitions in the final stages of the Fedération Internationale Football Association (FIFA) World Cup 2010, and investigated the following variables using univariate, bivariate, and multivariate analyses: duration of defensive transition, possession loss zone, position of players at the start and end of the defensive transitions, defensive organization, general defensive approach, time of the match, position of defense, zone in which t…
The cost of green roofs disposal in a life cycle perspective: covering the gap.
2012
Abstract This study is aimed at providing a contribution in overcoming the current gap, especially in Life Cycle Costing (LCC) and Benefit – Cost (BCA) analyses, due to the lack concerning the green roof disposal costs. Therefore, we have applied to an actual extensive green roof the LCC methodology suggested by D. G. Woodward (that appears like one of the most formalized and generalizable), but we have extended the analysis to the disposal phase. This will allow a complete and proper application of the LCC methodology in order of achieving an economic accounting of this component through its life cycle. In this way, it is possible to achieve the complete evaluation of the “green roof” perf…
Die Wirkung funktionaler, emotionaler und relationaler Nutzendimensionen auf die Markenloyalität
2005
Drawing on existing marketing literature three dimensions of utility are suggested: functional, emotional and relational. It is argued that the importance of these dimensions vary over time. In the early phase of the product life cycle, the functional utility is crucial for the success in the market place. Over time the emotional and relational dimension become more and more important. An empircial study carried out in the telecom industry provides evidence that this shift of importance actually takes place. The managerial implication is twofold. Firstly, the value proposition needs to be adapted in order to meet customer expectations. Secondly, an organizational change is necessary to be a…
Embedding “substrate” in environmental assessment of green roofs life cycle: evidences from an application to the whole chain in a Mediterranean site
2012
Abstract A classical LCA methodology is here applied to green roofs including in this analysis also the whole life cycle of the substrate, that represented a lack of previous LCA studies on green roofs. This inclusion will allow a complete and proper application of the LCA methodology to achieve an environmental accounting of the “green roof” performance. We have here chosen to approach the problem by analysing a specific substrate, that is used within an actual extensive green roof. Afterwards, we have applied the LCA methodology to the whole actual extensive green roof whose substrate under analysis is part of. In this manner, we achieved an environmental accounting of the “green roof” pe…
A parametric study on unbalanced three phase islanded microgrids with inverter interfaced units
2013
In this paper, the solution of the power flow for unbalanced three phase microgrids systems is proposed. The study aims at the integration of inverter interfaced units using the control law used for primary voltage and frequency regulation, so as to take into account possible small variations of these parameters to account for sudden load changes. The proposed study deals with unbalanced systems which is the typical case of small distribution systems and shows how the power losses term varies as the regulators parameters vary as well, thus showing that these are sensitive parameters that could have an important role in optimal management of such systems.