Search results for " Plastic"

New biodegradable hydrogels based on a photo-cross-linkable polyaspartamide and poly(ethylene glycol) derivatives. Release studies of an anticancer d…

2001

The functionalization of α,β-poly(N-2-hydroxyethyl)-dl-aspartamide (PHEA) with glycidyl methacrylate (GMA) gives rise to a water-soluble photosensitive copolymer PHEA-GMA (PHG). Aqueous solutions of PHG alone or in combination with various concentrations of poly(ethylene glycol) dimethacrylate or poly(ethylene glycol) diacrylate (PEGDA) have been exposed to a source of UV rays at 313 nm in order to obtain polymeric networks. All samples have been prepared both as water-swellable microparticles and as gel systems. Microparticles have been characterised by Fourier transform IR spectrophotometry, dimensional analysis and swelling measurements in aqueous media mimicking biological fluids. In vi…

New Photosensitive Polymers:  Synthesis and Free Radical Polymerization of Oxypyridinium and Oxyisoquinolinium Functionalized Methacrylate and Styren…

2002

Polymerizable hydroxypyridinium and hydroxyisoquinolinium salts 1a−4a, 2d, and 3d have been prepared from vinylbenzyl chloride or glycidyl methacrylate and 3-hydroxypyridine (2), 4- or 5-hydroxyisoquinoline (1, 3), and 8-hydroxyquinoline (4). Radical homo- and copolymerization with styrene or methyl methacrylate of the salts 1a−3a, 2d, and 3d produced (co)polymers 1e, 2e, 2f, 3f, 1g, 2g, 2h, and 3h. The photosensitive dipolar oxypyridinium or oxyisochinolinium betaine structures were generated in solutions with triethylamine from the low molecular weight and polymeric salt precursors. For the model compounds 1b−4b and (co)polymers 1e, 2e, 2f, 3f, 1g, 2g, 2h, and 3h, the degradation of the l…

Energy-Residual-Based approach to gradient plasticity

2008

The “energy-residual-based approach” mentioned in the title consists in a thermodynamically consistent procedure for the formulation of a phenomenological plasticity model of either strain gradient, or nonlocal (integral) type. The authors have developed this procedure on the last ten years. It seem therefore appropriate to present an update of this theory at this forum. For brevity we shell limit ourselves to strain gradient plasticity.

A link between the residual-based gradient plasticity theory and the analogous theories based on the virtual work principle

2009

A link is shown to exist between the so-called residual-based strain gradient plasticity theory and the analogous theories based on the (extended) virtual work principle (VWP). To this aim, the former theory is reformulated and cast in a residual-free form, whereby the insulation condition and the (nonlocal) Clausius–Duhem inequality, on which the theory is grounded, are substituted with equivalent residual-free ingredients, namely the energy balance condition and the residual-free form of the Clausius–Duhem inequality. The equivalence of the residual-free formulation to the original one is shown, also in their ability to cope with energetic size effects and interfacial energy ones. It emer…

Unified thermodynamic framework for nonlocal/gradient continuum theories

2003

Abstract A thermodynamic framework, equipped with the concept of nonlocality (energy) residual, is utilized to address nonlocal/gradient internal variable material models. A unified procedure is provided for either nonlocal and gradient materials, which makes it possible to determine the thermodynamic restrictions upon the constitutive equations, and in particular the pertinent state equations, the consistent form of the dissipation power and the constitutive expression of the nonlocality residual. Additionally, for gradient models, the associated nonstandard boundary conditions are derived, pointing out their basically constitutive nature and their substantial differences from the standard…

Green Design of Novel Starch-Based Packaging Materials Sustaining Human and Environmental Health

2021

A critical overview of current approaches to the development of starch-containing packaging, integrating the principles of green chemistry (GC), green technology (GT) and green nanotechnology (GN) with those of green packaging (GP) to produce materials important for both us and the planet is given. First, as a relationship between GP and GC, the benefits of natural bioactive compounds are analyzed and the state-of-the-art is updated in terms of the starch packaging incorporating green chemicals that normally help us to maintain health, are environmentally friendly and are obtained via GC. Newer approaches are identified, such as the incorporation of vitamins or minerals into films and coati…

New approach for synthesis of poly(ethylglyoxylate) using Maghnite-H + , an Algerian proton exchanged montmorillonite clay, as an eco-catalyst

2017

International audience; In this works, we have explored a new method for a green synthesis of poly(ethylglyoxylate) (PEtG). This method consists on using a montmorillonite clay called Maghnite-H+ as an eco-catalyst to replace triethylamine which is toxic. Cationic polymerization experiments are performed in bulk conditions at three temperatures (-40 degrees C, 25 degrees C, 80 degrees C) and in THF solutions at room temperature (25 degrees C). At 25 degrees C, an optimum ratio of 5 wt% of catalyst leads to molar masses up to 22000 g/mol in THF solutions. Polymerizations in bulk conditions lead to slightly lower masses than experiments conducted in THF solutions. However, bulk polymerization…

Undecylenic acid: A tunable bio-based synthon for materials applications

2016

International audience; An undecylenic acid-based monoglyceride prepared from glycidol and undecylenic acid is used as suitable and tunable synthon for polymerization applications. Epoxidation and acrylation reactions lead to photopolymerizable monomers while transesterification with dimethyl carbonate, metathesis and aminolysis reactions provide access to polyhydroxyurethane-based materials. The successive intermediates were synthesized according to a green chemistry approach implicating solvent-less and catalyzed reactions, and were at each step fully characterized by infrared, 1H and 13C{1H} NMR spectroscopy, elemental analysis and mass spectrometry. Analyses of the resulting polymer mat…

Green Composites a base di materie plastiche post-consumo e cariche organiche naturali

2003

The Thin bilateral and bipedicled DIEAP flap for axillary reconstruction in hidradenitis suppurativa

2019

Reconstruction after resection of advanced stage hidradenitis suppurativa is currently performed with pedicled perforator flaps, that allow functional reconstruction and preservation of shoulder function. Skin availability is limited by the possibility of closing the donor site primarily. Bilateral cases need to be treated in two stages, since the operation is carried out in the lateral decubitus. In this manuscript the application of bilateral and bipedicled DIEAP flaps to bilateral and extensive cases is presented.Between October 2008 and October 2018, 39 patients were treated for axillary hidradenitis suppurativa. Of these, 11 patients had bilateral reconstruction with bilateral DIEAP fl…