Search results for " Scanning"
showing 10 items of 988 documents
Crystal growth and hysteresis phenomena of rubidium tetrachlorozincate Rb2ZnCl4
1988
Abstract Phase transitions in Rb2ZnCl4 crystals grown by various methods are examined with differential scanning calorimetry and dielectric measurements. For most of the studied samples the permittivity along the ferroelectric axis shows a large thermal hysteresis over a wide temperature range including the incommensurate phase and the lock-in point. This hysteresis depends on the presence of different defects which appear during crystal growth or after a thermal and mechanical treatment. It is shown that dielectric measurements are quite well suited to characterize the crystals exhibiting on incommensurate phase and a ferroelectric phase.
Structural characterization, thermal, dielectric, vibrational properties and molecular dynamics of (C5H5NH)3BiCl6
2009
Abstract (C5H5NH)3BiCl6 crystallizes at room temperature in the triclinic space group P 1 ¯ . The crystal is built up of the separated BiCl 6 3 - octahedral anions and pyridinium cations. Differential scanning calorimetry (DSC) and dilatometric measurements disclose structural phase transition of first-order type at 265/302 K (cooling/heating). The dielectric investigations reveal a step-wise change of the electric permittivity at Tc characteristic of the crystals with the high-temperature plastic-like phase. Temperature-dependent infrared spectra for polycrystalline samples have been taken between 20 and 306 K to clarify the cation dynamics contribution to the mechanism of the phase transi…
Influence of poloxamers on the dissolution performance and stability of controlled-release formulations containing Precirol® ATO 5
2005
Abstract Lipid excipients are usually used for the development of sustained-release formulations. When used in relatively high quantities, Precirol ® ATO 5 imparts sustained-release properties to solid oral dosage forms, by forming a lipid matrix. To control or adjust the drug release kinetics from such lipid matrix however, one must often resort to complementary ingredients or techniques. This study investigates the influence of poloxamers (Lutrol ® ) included in lipid matrices composed of glyceryl palmitostearate (Precirol ® ATO 5) on their dissolution performance and their stability. The addition of these hydrophilic polymers in the lipid matrix increased the amount of theophylline relea…
Application of Organic Monolithic Materials to Enantioseparation in Capillary Separation Techniques.
2017
This review article is primarily focused on the state-of-the-art of enantioseparations on organic monolithic materials. The article gives an overview of the chiral stationary phases and its application in capillary electrochromatography (CEC), and capillary- and nano-liquid chromatography (cLC and nLC). Since thousands of publications have been emerged from 2000’s and citing all these papers would extend the scope of this review; then, recent developments from last 10 years (2006 to 2016) will be mentioned. Mostly, stationary phases based on copolymers obtained from chiral functional monomers and surface modifications of organic monoliths with chiral ligands will be discussed. The effective…
COMPARATIVE-STUDY ON INCLUSION-COMPOUNDS OF 4-BIPHENYLACETIC ACID WITH BETA-CYCLODEXTRIN, HYDROXYPROPYLATED-BETA-CYCLODEXTRINS, AND METHYLATED-BETA-C…
1994
AbstractThe inclusion behavior of Hydroxypropyl-β-Cyclodextrin (HP-β-Cyd) and of methylated-β-Cyclodextrins, heptakis-(2,6-di-O-methyl)-β-Cyclodextrin (DM-β-Cyd) and heptakis-(2,3,6-tri-O-methyl)-β-Cyclodextrin (TM-β-Cyd), in solution and solid state was compared with that of natural β-Cyclodextrin (β-Cyd) using an anti-inflammatory drug, 4-biphenylacetic acid (BPAA), as a guest molecule. The solubility of BPAA with β-Cyd and β-Cyd derivatives in aqueous solution were determined. Stability constants were calculated by phase solubility method at various pH values and temperatures. The formation of inclusion complexes with β-Cyd and β-Cyd derivatives in the solid slate were confirmed by infra…
Simulataneous application of charge coupled device array-detected Raman spectroscopy and differential scanning calorimetry to in situ investigation o…
1992
The combination of differential scanning calorimetry (DSC) with charge coupled device (CCD) array-detected Raman spectroscopy for the in situ investigation of phase transition is illustrated using ammonium nitrate as an example. This method aids unambiguous characterization of different phases by providing a simultaneous probe of thermodynamic and vibrational data. The availability of real-time vibrational data, including both the internal and external mode regions, is unique to array-detected Raman spectroscopy. The intensity changes of the symmetric stretching mode ν1 of the nitrate ions and the lattice vibrations, that accompany the phase transition IV → II of ammonium nitrate, are ratio…
Solid-State Transition Mechanisms of Ammonium Nitrate Phases IV, III, and II Investigated by Simultaneous Raman Spectrometry and Differential Scannin…
1993
The solid-state transition mechanisms of ammonium nitrate IV, III, and II were studied by measuring samples simultaneously by Raman spectrometry and differential scanning calorimetry (DSC). The Raman instruments were a Fourier transform Raman spectrophotometer and triple monochromator Raman spectrophotometer with charge-coupled-device (CCD) detector. The spectral data of the transitions were collected simultaneously with the calorimetric data in the temperature-scanning mode of the calorimeter and then isothermally between transitions. The phase transition from phase IV to phase III occurred through an intermediate phase II*, whose lifetime was seven minutes maximum when the onset temperat…
On structural phase transitions in piperidinium halogenoantimonates(III) and bismuthates(III): X-ray, calorimetric, dilatometric, dielectric and Rama…
2000
Abstract Three piperidinium analogues: (C5H10NH2)2BiCl5, (C5H10NH2)2BiBr5 and (C5H10NH2)2SbBr5 have been studied by means of differential scanning calorimetry, thermal expansion, dielectric and Raman scattering techniques. Each piperidinium salt undergoes one high-temperature structural phase transition, which has been classified as an “order–disorder” type. All transitions are connected with onset of reorientational motion of the organic cations. The X-ray studies on (C5H10NH2)2BiCl5 show that it crystallises in orthorhombic Pna21 space group. The structure has been refined to R=0.0336. It consists of one-dimensional (BiCl52−)n polyanionic chains and two non-equivalent piperidinium cations…
On structural phase transitions in the (C 5 H 12 N) 2 SbCl 5 crystals
2000
Abstract The results of the X-ray (at 295 and 355 K), dilatometric, differential scanning calorimetry and dielectric studies on a new piperidinium crystal, (C5H12N)2SbCl5, are presented. The anionic sublattice of the crystal is built up of infinite (SbCl52−)n chains composed of SbCl63− distorted octahedra connected with each other by corners. In voids of anionic sublattice two crystallographically independent piperidinium cations are located. At 295 K they are both in chair conformation. The compound undergoes three first-order phase transitions at 378.5 K (I→II), 339.5 K (II→III) and 205 K (III→IV). The mechanism of the (II→III) transition (Pna21→P212121) was proposed based on the X-ray da…
Crystal structure, phase transitions and ferroelastic properties of [(CH3)2NH2]3[Bi2Cl9]
2003
Abstract A sequence of structural phase transitions in [(CH3)2NH2]3[Bi2Cl9] (DMACB) is established on the basis of differential scanning calorimetry (DSC) and dilatometric studies. Four phase transitions are found: at 367/369, 340/341, 323/325 and 285/292 K (on cooling/heating). The crystal structure of DMACB is determined at 350 K. It crystallizes in monoclinic space group P21/n: a=8.062(2), b=21.810(4), c=14.072(3) A, β=92.63(3)°, Z=4, R1=0.0575, wR2=0.1486. The crystal is built of the double chain anions (“pleated ribbon structure”) and the dimethylammonium cations. Dielectric studies in the frequency range 75 kHz–900 MHz indicate relatively fast reorientation of the dimethylammonium cat…