Search results for " Scanning"

showing 10 items of 988 documents

Forensic tools for the diagnosis of electrocution death: Case study and literature review

2018

Diagnosis of death by electrocution may be difficult when electric marking is not visible or unclear. Accordingly, the body of a man who appeared to have died from accidental electrocution was carefully forensically analysed. Macroscopic and microscopic analysis of the current mark was carried out using a variable-pressure scanning electron microscope equipped with energy dispersive X-ray microanalyser to highlight skin metallisation, indicating the presence of iron and zinc. The histological findings of electrocution myocardial damage were supported by the results of biochemical analysis which demonstrated the creatine kinase-MB and cardiac troponin I elevation. The effects of electric cu…

endothelial perforationMaleForensic pathologyPathologymedicine.medical_specialtyElectrocution death; biochemical analysis; endothelial perforation; energy dispersive X-ray analysis; metallisation; scanning electron microscopeCardiac troponinFatal outcomebiochemical analysiAutopsybiochemical analysis; Electrocution death; endothelial perforation; energy dispersive X-ray analysis; metallisation; scanning electron microscope; Autopsy; Cause of Death; Electric Injuries; Fatal Outcome; Forensic Pathology; Humans; Male; Microscopy Electron Scanning; Middle Aged; Medicine (all)Electron01 natural sciencesElectric current flowenergy dispersive X-ray analysis03 medical and health sciencesFatal Outcome0302 clinical medicineSettore MED/43 - Medicina Legalebiochemical analysismetallisationCause of DeathHumansMedicineScanning030216 legal & forensic medicineForensic PathologyMicroscopybusiness.industryMedicine (all)010401 analytical chemistryscanning electron microscopeGeneral MedicineMiddle Agedenergy dispersive X-ray analysiElectrocution deathpeople.cause_of_death0104 chemical sciencesElectric InjuriesElectrocutionMicroscopy Electron ScanningAutopsybusinesspeopleEndothelial surfaceMedico-Legal Journal
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High‐resolution 3D forest structure explains ecomorphological trait variation in assemblages of saproxylic beetles

2022

1. Climate, topography and the 3D structure of forests are major drivers affecting local species communities. However, little is known about how the specific functional traits of saproxylic (wood-living) beetles, involved in the recycling of wood, might be affected by those environmental characteristics. 2. Here, we combine ecological and morphological traits available for saproxylic beetles and airborne laser scanning (ALS) data in Bayesian trait-based joint species distribution models to study how traits drive the distributions of more than 230 species in temperate forests of Europe. 3. We found that elevation (as a proxy for temperature and precipitation) and the proportion of conifers p…

environmental gradientLiDARairborne laser scanning; Bayesian modelling; Coleoptera; environmental gradient; functional traits; HMSC; LiDAR; phylogenyDIVERSITYMELANISMairborne laser scanningECOLOGYphylogenyfunctional traits3D-mallinnusPREDICTORSEcology Evolution Behavior and SystematicskovakuoriaisetlajistokartoitusfylogeniaEcologybayesilainen menetelmäeliöyhteisötilmastonmuutoksetHMSCmetsätEVOLUTIONColeopteraMORPHOLOGICAL TRAITSFUNCTIONAL TRAITS1181 Ecology evolutionary biologyBIODIVERSITYABUNDANCEBayesian modellingympäristönmuutoksetlaserkeilausRESPONSESFunctional Ecology
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Synthesis and characterization of a novel high luminescent gold-2-mercapto-1-methyl-imidazole complex

2010

Synthesis and characterization of a new gold-2-mercapto-1-methyl imidazole are reported. This new organic material shows an extraordinary fluorescence activity (superfluorescence) up to 220°C with an unusual quantum yield of 0.2. Both fluorescence and NMR spectroscopy were applied to understand the behavior of the gold-2-mercapto-1-methylimidazole complex. Results suggest that the superfluorescence activity can be attributed to the shrinking of the HOMO-LUMO band gap energy following complexation of the organic imidazole system with gold. Copyright © 2010 John Wiley & Sons, Ltd.

fluorescence spectrofotometryLuminescenceMagnetic Resonance SpectroscopyBand gapSettore AGR/13 - Chimica AgrariaBiophysicsQuantum yieldPhotochemistryimidazolechemistry.chemical_compoundNMR spectroscopyOrganic chemistryImidazoleThermal analysisCalorimetry Differential ScanningImidazolesNuclear magnetic resonance spectroscopyFluorescenceCharacterization (materials science)Spectrometry Fluorescencethermal analysichemistryChemistry (miscellaneous)Goldsuperfluorescencequantum yieldLuminescenceLuminescence
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Sorption kinetic of aroma compounds by edible bio-based films from marine-by product macromolecules: Effect of relative humidity conditions

2019

International audience; Edible films based on gelatin and chitosan have high gas and aroma barrier properties. This study focused on their capability to sorbed/retain aroma compounds (1-hexanal, 2-hexen-1-ol, 1-hexanol, 3-hexanone and phenol) at three relative humidity level (≤2%, 53% or 84% RH). Whatever the relative humidity condition, the order of sorption is keton (3-hexanone) < aldehyde (1-hexanal) < aliphatic alcohols (2-hexen-1-ol and 1-hexanol) < phenol. This order could be related to the intrinsic chemical properties of aroma compounds. The increase in moisture enhanced the sorption at the highest RH for all the aroma compounds. However, a competition between water and aliphatic al…

food.ingredientChromatography GasAntiplasticization030309 nutrition & dieteticsActive edible filmsGelatinStructure propertiesAnalytical Chemistry03 medical and health scienceschemistry.chemical_compound0404 agricultural biotechnologyfood[SDV.IDA]Life Sciences [q-bio]/Food engineeringPhenolRelative humidityAroma0303 health sciencesChitosanVolatile Organic CompoundsAroma sorptionMoisturebiologyCalorimetry Differential ScanningPhenolChemistryPlasticizationPlasticizerTemperatureSorptionHumidity04 agricultural and veterinary sciencesGeneral MedicineKetonesbiology.organism_classification040401 food scienceKinetics13. Climate actionAlcoholsGelatinAdsorptionGlass transitionGlass transitionFood ScienceNuclear chemistry
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Microstructure and characteristic properties of dogfish skin gelatin gels prepared by freeze/spray-drying methods

2020

International audience; The effects of two pretreatments (microwaves or oven-drying) on the dogfish (Squalus acanthias) skin as well as two drying processes (freeze-drying or spray-drying) on the extracted gelatins were studied. Thus six types of gelatins were obtained, three of which were freeze-dried (FG) and the others were spray-dried (SG), from the untreated skin (US), microwaves-pretreated skin (MS) and oven-pretreated skin (OS). The highest yield (8.67%) was obtained for the OSFG, while the lowest one (3.06%) was measured for the OSSG. Interestingly, all gelatins exhibited relatively high protein (84.02-89.53%), and low lipid (0.50-1.71%) and ash (3.05-7.17%) contents. In addition, g…

food.ingredientDogfish skinColor02 engineering and technologyBiochemistryGelatinPhysico-chemical properties03 medical and health scienceschemistry.chemical_compoundIngredientfoodSqualus acanthiasHardnessStructural BiologyAmideSpectroscopy Fourier Transform InfraredAnimalsTransition TemperatureAmino AcidsDesiccationMicrowavesMicrostructureMolecular BiologySkin030304 developmental biology0303 health sciencesChromatographyCalorimetry Differential ScanningHigh proteinGeneral Medicine021001 nanoscience & nanotechnologyMicrostructureAmidesFreeze DryingchemistryDogfishYield (chemistry)Spray dryingMicroscopy Electron ScanningGelatin0210 nano-technologyGels[SDV.AEN]Life Sciences [q-bio]/Food and NutritionInternational Journal of Biological Macromolecules
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Impact of electron beam irradiation on fish gelatin film properties

2016

International audience; The objective of this work was to display the effect of electron beam accelerator doses on properties of plasticized fish gelatin film. Electron spin resonance indicates free radical formation during irradiation, which might induce intermolecular cross-linking. Tensile strength for gelatin film significantly increases after irradiation (improved by 30% for 60 kGy). The vapour permeability is weakly affected by irradiation. Surface tension and its polar component increase significantly and are in accordance with the increase of wettability. So, irradiation may change the orientation of polar groups of gelatin at the film surface and crosslink the hydrophobic amino aci…

food.ingredientMaterials scienceMechanical and water barrier propertiesCross linkingFree RadicalsSurface Properties[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionMechanical-propertiesGamma-irradiationElectrons02 engineering and technologyGelatinAnalytical ChemistryCrystallinity0404 agricultural biotechnologyfoodUltimate tensile strength[SDV.IDA]Life Sciences [q-bio]/Food engineeringAnimalsThermal stabilityIrradiationEnvironmental scanning electron microscopeWater-vapor permeabilityRadiationCalorimetry Differential ScanningSkin gelatinProtein filmsFishes[ SDV.IDA ] Life Sciences [q-bio]/Food engineeringWater04 agricultural and veterinary sciencesGeneral Medicine021001 nanoscience & nanotechnology040401 food scienceEdible filmsChemical engineeringElectron beam irradiationGluten filmsBiodegradationGelatinWettingGelatin network0210 nano-technologyGlass transition[SDV.AEN]Life Sciences [q-bio]/Food and NutritionSurface hydrophobicityFood ScienceCross-linking
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Effect of oxidoreduction potential and of gas bubbling on rheological properties and microstructure of acid skim milk gels acidified with glucono-del…

2009

Milk oxidoreduction potential was modified using gases during the production of a model dairy product and its effect on gel setting was studied. Acidification by glucono-delta-lactone was used to examine the physicochemistry of gelation and to avoid variations due to microorganisms sensitive to oxidoreduction potential. Four conditions of oxidoreduction potential were applied to milk: milk was gassed with air, nongassed, gassed with N(2), or gassed with N(2)H(2). The rheological properties and microstructure of these gels were determined using viscoelasticimetry, measurement of whey separation, and confocal laser scanning microscopy. It appeared that a reducing environment led to less-aggre…

food.ingredientMicroorganism[ SDV.AEN ] Life Sciences [q-bio]/Food and NutritionGluconatesGluconolactoneMatrix (chemical analysis)Lactones0404 agricultural biotechnologyfoodRheologySkimmed milkGeneticsConfocal laser scanning microscopyFood and NutritionAnimalsFood scienceChemistry0402 animal and dairy sciencefood and beverages04 agricultural and veterinary sciencesHydrogen-Ion ConcentrationMicrostructure040401 food science040201 dairy & animal scienceMilkChemical engineeringAlimentation et NutritionFood TechnologyAnimal Science and ZoologyGasesRheology[SDV.AEN]Life Sciences [q-bio]/Food and NutritionOxidation-Reductionδ lactoneFood Science
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Structure of calcium and zinc pectinate films investigated by FTIR spectroscopy

2010

International audience; Calcium and zinc pectinate gels were prepared using a method which allowed calcium or zinc to diffuse from the cross-linking solution through a dialysis membrane to form a gel with amidated low-methoxyl pectin. The gel thus obtained was then dried, and the film structure was studied using FTIR spectroscopy as a function of the cation content (0%, 5%, 10%, and 15% w/v). Important consideration was given to the three functional groups (amide, carboxyl ester, and carboxylate groups) present in the pectin. When the zinc content was increased, the three wavenumber values corresponding to these three functional groups did not change significantly, while for calcium pectina…

food.ingredientPectinCoordination numberInorganic chemistrychemistry.chemical_elementZincCalciumBiochemistryAnalytical ChemistryDialysis tubingchemistry.chemical_compoundfoodX-Ray DiffractionAmideSpectroscopy Fourier Transform InfraredCarboxylateFourier transform infrared spectroscopyFilmChemistryOrganic ChemistryGeneral MedicinePectin[SDV.BBM.BP]Life Sciences [q-bio]/Biochemistry Molecular Biology/BiophysicsZincFTIR spectroscopyMicroscopy Electron ScanningPectinsCalcium[SDV.AEN]Life Sciences [q-bio]/Food and Nutrition
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Influence of low methoxyl pectin gel textures and in vitro release of rutin from calcium pectinate beads.

2013

This study described the preparation and characterization of low methoxyl pectin (LMP) gels and beads for controlled release applications. The rheological characterization of the various formulations was proposed. Then the mechanical and morphological characterizations of beads were determined. Finally, the controlled release studies taking rutin as a model drug was evaluated. The results showed that Young's modulus values of non-amidated LMP gels decrease when adding up to 15% sorbitol. Calcium pectinate beads loaded with rutin are about 600 μm, oblong shaped with dense matrix. Beads containing sodium bicarbonate showed about 80% lower rutin encapsulation efficiency by increasing the pH of…

food.ingredientPolymers and PlasticsPectinRutinBuffersRutinchemistry.chemical_compoundfoodRheologyElastic ModulusMaterials ChemistrymedicineSodium bicarbonateChromatographyViscosityOrganic ChemistryHydrogen-Ion ConcentrationControlled releaseIn vitroMicrospheresSolutionschemistryMicroscopy Electron ScanningPectinsSorbitolSwellingmedicine.symptomRheologyGelsCarbohydrate polymers
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Supramolecular Hydro- and Ionogels: A Study of Their Properties and Antibacterial Activity.

2017

Diimidazolium-based organic salts, bearing peptides or amino acids as anions have been synthesised and tested for their gelling ability in biocompatible solvents. These low molecular weight salts were successfully used as gelators in phosphate buffered saline (PBS) solution and ionic liquids. Then, the properties of the obtained soft materials were analysed in terms of melting temperature and gel strength as accounted for by rheological investigations. The gel-phase formation was studied by using UV/Vis and resonance light scattering measurements, whereas the morphology of the soft materials was analysed by using polarised optical microscopy and scanning electron microscopy. To get informat…

gelantibacterial activity; gels; hydrogels; ionic liquids; ionogels; Chemistry (all)Scanning electron microscopeSupramolecular chemistryIonic Liquids02 engineering and technologyMicrobial Sensitivity Tests010402 general chemistryGram-Positive Bacteria01 natural sciencesCatalysischemistry.chemical_compoundRheologyantibacterial activityX-Ray DiffractionPhase (matter)Gram-Negative BacteriaOrganic chemistryThermal stabilityhydrogelsionic liquidOrganic ChemistryChemistry (all)ImidazolesGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesAnti-Bacterial AgentsionogelchemistryChemical engineeringionogelsSelf-healing hydrogelsIonic liquidMicroscopy Electron ScanningSolventshydrogel0210 nano-technologyAntibacterial activityRheologyGelsChemistry (Weinheim an der Bergstrasse, Germany)
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