Search results for " Solar"

Novel dithieno[3,2-b:2′,3′-d]pyrrole-based organic dyes with high molar extinction coefficient for dye-sensitized solar cells

2013

Abstract Three new metal-free organic dyes FD1 – 3 with a planar dithieno[3,2- b :2′,3′- d ]pyrrole unit as linker were synthesized and used for dye-sensitized solar cells with high molar extinction coefficients. In this work, dithieno[3,2- b :2′,3′- d ]pyrrole was employed as π-conjugated bridge to construct A–π– d –π–A organic dyes, where 9,9-dihexyl-9 H -fluorene was used as a donor, and cyanoacrylic acid as an electron acceptor. For a typical device, a solar energy conversion efficiency ( η ) of 6.36% based on FD2 was achieved under simulated AM 1.5 solar irradiation (100 mW cm −2 ) with a short-circuit photocurrent density ( J sc ) of 13.76 mA cm −2 , an open-circuit voltage ( V oc ) o…

Phenothiazine-based dyes with bilateral extension of π-conjugation for efficient dye-sensitized solar cells

2013

Four novel organic photo-sensitizers based on phenothiazine were designed, synthesized and characterized for efficient dye-sensitized solar cells. Anisole, octyloxybenzene and dodecyloxybenzene were incorporated into the phenothiazine by an Ullmann reaction. An additional octyloxybenzene was incorporated into one dye unit through a Suzuki coupling reaction. The modified phenothiazine moiety acts as an electron donor and cyanoacrylic acid acts as an electron acceptor and anchoring unit. The photophysical, electrochemical and sensitizing characteristics of the new dyes were evaluated. The bis(octyloxybenzene) substituted dye delivered the best performance with its sensitized solar cell displa…

Synthesis and Characterization of Extended Bis(terpyridine)ruthenium Amino Acids

2009

(Oligopyridine)ruthenium(II) complexes have been widely used in dye sensitized solar cells and other sophisticated optical devices due to their outstanding photophysical properties and their chemical stability. Herein, we describe the longitudinal extension of our previously reported bis(terpyridine)ruthenium(II) amino acid [Ru(tpy–NH2)(tpy–COOH)]2+ (tpy = 4′-substituted 2,2′:6′,2″-terpyridine) by insertion of para-phenylene spacers –C6H4– between the terpyridine and the functional groups. The influence of the para-phenylene spacer on the absorption and emission properties is investigated using UV/Vis absorption and emission spectroscopy and is discussed within a qualitative molecular orbit…

Photovoltaic effect in bulk heterojunction system with glass forming indandione derivative DMABI-6Ph

2018

The aim of the work is to evaluate possible use of 2-[[4-(bis(2-trityloxyethyl)amino)phenyl]methylene]indane-1,3-dione (DMABI-6Ph) as light absorbing material for solar cells. DMABI-6Ph is a perspective material due to its good photoelectrical, thermal and chemical properties. The main advantage of DMABI-6Ph is its ability to form amorphous films by wet-casting methods thus allowing using the compound in organic solar cells made from solution. For now most popular materials for solution processable solar cells are polymer P3HT and fullerene derivative PCBM, but lot of investigations are in the field of new low molecular weight materials to replace the polymer. Photoelectrical measurements w…

Indium Selenide Solar Cells

1981

Indium selenide photovoltaic devices are described. Transport and photovoltaic properties are discussed. Efficiencies of 6% are reported and ways of improvement are proposed.

Excited State N−H Tautomer Selectivity in the Singlet Energy Transfer of a Zinc(II)-Porphyrin-Truxene-Corrole Assembly

2017

International audience; An original corrole-containing polyad for S-1 energy transfer, in which one zinc(II)-porphyrin donor is linked to two free-base corrole acceptors by a truxene linker, is reported. This polyad exhibits a rapid zinc(II)-porphyrin*free-base corrole transfer (4.83x10(10)s(-1); 298K), even faster than the tautomerization in the excited state processes taking advantage of the good electronic communication provided by the truxene bridge. Importantly, the energy transfer process shows approximately 3-fold selectivity for one corrole N-H tautomer over the other even at low temperature (77K). This selectivity is due to the difference in the J-integral being effective in both t…

ENERGY FOR ROMANIA FROM RENEWABLE RESOURCES

2012

The European Union admits the fact that energy is essential, for the development of the European economy, but that it also constitutes a challenge, due to the impact on climate change. In Romania, as well as in all the countries of the European Union, which have chosen to promote renewable energy, governments have come up with support frameworks for investors in this field. In Romania’s case, the option for green schemes and compulsory quotas was selected, meaning that each energy producer, which produces renewable energy, receives a number of green certificates for each MW produced, depending on the technology it uses. The price of such a green certificate varies between 27 – 55 Euros. The…

Preliminary results of a PV closed greenhouse system for high irradiation zones in south Italy

2011

Colector de agua solar. Impulsando un nuevo modelo de consumo para un presente y un futuro sostenible

2014

La producción de energía mediante el uso indiscriminado de los recursos naturales no renovables como el carbón, el petróleo y el gas natural provoca una situación de agotamiento de dichos recursos con inevitables consecuencias para el medio ambiente. Son numerosas las formas de contaminación y los problemas ambientales que los seres humanos estamos provocando desde los inicios de la revolución industrial y, muy en particular, desde la segunda mitad del siglo pasado. Una contaminación sin fronteras asociada a todas las actividades humanas y que, junto a otros graves problemas, está degradando todos los ecosistemas y contribuyendo a un cambio climático cuyas consecuencias estamos viviendo ya.…

Development of Neural Network Prediction Models for the Energy Producibility of a Parabolic Dish: A Comparison with the Analytical Approach

2022

Solar energy is one of the most widely exploited renewable/sustainable resources for electricity generation, with photovoltaic and concentrating solar power technologies at the forefront of research. This study focuses on the development of a neural network prediction model aimed at assessing the energy producibility of dish–Stirling systems, testing the methodology and offering a useful tool to support the design and sizing phases of the system at different installation sites. Employing the open-source platform TensorFlow, two different classes of feedforward neural networks were developed and validated (multilayer perceptron and radial basis function). The absolute novelty of this approac…