Search results for " Spectra"
showing 10 items of 709 documents
Differences of stabilized organic carbon fractions and microbiological activity along Mediterranean Vertisols and Alfisols profiles
2010
This study examined the chemical and structural properties of humic substances and microbiological activity in order to verify differences in carbon dynamics along soil profiles in two Vertisols (Typic Haploxerert and Xeric Epiaquert) and two Alfisols (Mollic Haploxeralf and Ultic Haploxeralf) developed under Mediterranean climate in Italy. Humification parameters, thermal methods, including differential scanning calorimetry (DSC) and thermogravimetry (TG), together with Fourier transform infrared (FT-IR) and fluorescence spectroscopies were used to characterize humic acids (HA). Microbiological activity of soils was assessed by basal respiration, metabolic quotient (qCO2) and Cmic:Corg rat…
ExTTF-Based Dyes Absorbing over the Whole Visible Spectrum
2011
International audience; New push−pull dyes featuring π-extended tetrathiafulvalene (exTTF) as the donor group and tricyanofuran (TCF) as the acceptor group were synthesized and characterized. Their broad absorption covers the entire visible spectral range and enters the near-infrared region. Electrochemistry and theoretical calculations provided an understanding of these singular electronic properties. The new dyes are appealing candidates as light harvesters in photovoltaic devices.
Exciton emission and defect formation in yttrium trifluoride
2005
Two intrinsic emission bands at 220 and 280 nm have been detected in nominally pure YF3 powders at 10 K. Excitation spectra for both emissions have a sharp peak at 12 eV near the edge of interband transition. Observed emissions are assigned to the radiative decay of self-trapped excitons in YF3. The strong thermal quenching of intrinsic luminescence was observed at temperature above 120 K. It was supposed that non-radiative decay of self-trapped exciton at high temperatures lead to defect formation in YF3. (© 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
Syntheses and properties of some exo,exo-bis(isodicyclopentadienyl)titanium low-valent complexes
2002
Abstract The paramagnetic compounds exo,exo-bis(η5-isodicyclopentadienyl)chlorotitanium(III) (3) and its analogue with trimethylsilyl-substituted isodicyclopentadienide (isodiCp) ligand (4), and the similar pair of diamagnetic exo,exo-bis(isodicyclopentadienyl)[η2-bis(trimethylsilyl)ethyne]titanium(II) complexes 5 and 6 were obtained by common reduction procedures from exo,exo-bis(isodicyclopentadienyl)titanium(IV) dichloride (1) and exo,exo-bis[η5-2-(trimethylsilyl)isodicyclopentadienyl]titanium(IV) dichloride (2), respectively. As indicated by ESR spectroscopy compound 3 is a dimer in the solid state and in frozen toluene glass but monomeric in toluene solution. Compound 4 is monomeric in…
DeepIndices : Une nouvelle approche des indices de télédétection basée sur l'optimisation et l'approximation de fonctions par DeepLearning. Applicati…
2021
National audience; L'une des avancées les plus importantes dans le domaine de l'observation de la terre est la découverte des indices spectraux, ils ont notamment prouvé leur efficacité dans la caractérisation des surfaces agricoles, mais ils sont généralement définis de manière empirique. Cette étude basée sur l'intelligence artificielle et le traitement du signal, propose une méthode pour trouver un indice optimal. Et porte sur l'analyse d'images issues d'une caméra multi-spectrale, utilisée dans un contexte agricole pour l'acquisition en champ proche de végétation. À partir de six bandes spectrales, cinq modèles ont été testés et déployés dans un framework d'apprentissage profond. Les pe…
Spectra and essential spectral radii of composition operators on weighted Banach spaces of analytic functions
2008
AbstractWe determine the spectra of composition operators acting on weighted Banach spaces Hv∞ of analytic functions on the unit disc defined for a radial weight v, when the symbol of the operator has a fixed point in the open unit disc. We also investigate in this case the growth rate of the Koenigs eigenfunction and its relation with the essential spectral radius of the composition operator.
Ultrarelativistic bound states in the spherical well
2016
We address an eigenvalue problem for the ultrarelativistic (Cauchy) operator $(-\Delta )^{1/2}$, whose action is restricted to functions that vanish beyond the interior of a unit sphere in three spatial dimensions. We provide high accuracy spectral datafor lowest eigenvalues and eigenfunctions of this infinite spherical well problem. Our focus is on radial and orbital shapes of eigenfunctions. The spectrum consists of an ordered set of strictly positive eigenvalues which naturally splits into non-overlapping, orbitally labelled $E_{(k,l)}$ series. For each orbital label $l=0,1,2,...$ the label $k =1,2,...$ enumerates consecutive $l$-th series eigenvalues. Each of them is $2l+1$-degenerate. …
Die Dissoziationskonstanten von 2,2?-Dihydroxydiphenylmethanderivaten
1973
The pK-values of the first and second degree of dissociation of 2.2′-dihydroxy-5-methyl-3′.5′-dinitro-diphenylmethane, 2.2′-dihydroxy-5-methyl-5′-nitro-diphenylmethane and 2.2′-dihydroxy-5.5′-dimethyl-3′-nitro-diphenylmethane were determined in aqueous solution at 25°C spectrophotometrically. Comparing the observed pK-values with those of 2-methyl-4.6-dinitrophenol, 2-methyl-4-nitrophenol, 2.4-dimethyl-6-nitro-phenol and 2.4-dimethylphenol, we found a decrease of the values of pK1 and an increase of pK2. We explain this by the formation of an intramolecular hydrogen bridge which stabilizes the anion of the half dissociated form. This assumption is supported by the UV spectra.
Spectral adaptation of hyperspectral flight lines using VHR contextual information
2014
Abstract: Due to technological constraints, hyperspectral earth observation imagery are often a mosaic of overlapping flight lines collected in different passes over the area of interest. This causes variations in aqcuisition conditions such that the reflected spectrum can vary significantly between these flight lines. Partly, this problem is solved by atmospherical correction, but residual spectral differences often remain. A probabilistic domain adaptation framework based on graph matching using Hidden Markov Random Fields was recently proposed for transforming hyperspectral data from one image to better correspond to the other. This paper investigates the use of scale and angle invariant…
Simulation of the VUV spectral emission from the JT-60SA divertor
2021
A divertor survey dual-spectrometer is being designed by an EU-Japan team [1] to be installed on JT-60SA [2], the new fusion experiment expected to start operating in 2020. Positioned on an upper port, the primary role of the spectrometer is to analyse the radiation losses in the divertor region and to aid studying the physics of the divertor plasmas, including plasma detachment. Its spatial resolution capability is around 10 cm at the divertor and its two branches together cover the wavelength range from 10 to 130 nm, to satisfy the physics scope [3]. The spectrometer Lines Of Sight (LOS) are mapped onto a 2D SOLEDGE [4] simulations of the divertor region carried out for different density …