Search results for " Stab"
showing 10 items of 1773 documents
PBI-based composite membranes for polymer fuel cells
2010
Abstract In the present study poly(2,2-(2,6-pyridin)-5,5-bibenzimidazole) was used for the preparation of novel MEAs for high-temperature polymer fuel cells (HT-PEMFCs). We prepared hybrid materials with two types of silica fillers in order to increase the MEA performances using this polymer. The membranes were characterized in terms of their microstructure and thermal stability. Cell operation tests and Electrochemical Impedance Spectroscopy were used for the characterization of the MEAs. A maximum power density of about 80 mW cm−2 was obtained at 300 mA cm−2 by using an imidazole-modified silica filler. The EIS technique showed that the fillers chiefly help to reduce the charge transfer r…
Biomolecular-solvent stereodynamic coupling probed by deuteration.
1983
Thermodynamic interpretation of experiments with isotopically perturbed solvent supports the view that solvent stereodynamics is directly relevant to thermodynamic stability of biomolecules. According with the current understanding of the structure of the aqueous solvent, in any stereodynamic configuration of the latter, connectivity pathways are identifiable for their topologic and order properties. Perturbing the solvent by isotopic substitution or, e.g., by addition of co-solvents, can therefore be viewed as reinforcing or otherwise perturbing these topologic structures. This microscopic model readily visualizes thermodynamic interpretation. In conclusion, the topologic stereodynamic str…
Self-Diffusion of Associating Star-Shaped Polymers
2016
The dynamics of associating bonds in transient polymer networks exerts a paramount influence on their relaxation and time-dependent mechanical properties. In particular, diffusive motion of polymers mediated by the dissociation and association equilibrium of reversible junctions can affect the materials’ structural stability, dynamic mechanical properties, and a broad spectrum of functionality that arises from the constant motion of polymer chains. In this work, forced Rayleigh scattering is used to measure the diffusion of terpyridine end-functionalized four-arm poly(ethylene glycol) polymers transiently interlinked by zinc ions in organic solvent across a wide range of length and time sca…
Use of stable isotopes to investigate dispersal of waste from fish farm as a function of hydrodynamics.
2006
Stable isotopes were used to examine differential effects of fish farm waste on the water column and sediments. To achieve this objective, we chose 3 marine fish farms located along the coast of Sicily (Mediterranean Sea) as point-source disturbances, and a control area. The hypothesis that carbon and nitrogen isotope composition of particulate (POM) and sedimentary (SOM) organic matter varied with increasing distance (from cages to 1000 m) was tested at 3 levels of hydrodynam- ics: low (mean velocity of current (MVC) ~12 cm s -1 ), intermediate (MVC ~22 cm s -1 ), and high (MVC ~40 cm s -1 ). Different isotopic signals from allochthonous (fish waste) over natural (phytoplankton, terrigenou…
Role of peat organic matter on isotopic composition of most abundant benthic organisms in intertidal habitats of SW Iceland
2008
The transfer of peat organic matter (OM) from tidal pools of upper littoral to downstream rocky shores and its potential incorporation into marine biota were investigated using the stable isotope approach. Samplings were carried out in September 2004 in two SW Icelandic sites (Osar and Hvassahraun), where we selected (1) areas with shores where grass gently declined towards rocks and, on reaching the sea line, formed small tidal peat pools and (2) areas where grass and rocky shores were not contiguous, rather the grass lower limits were several hundreds of meters back from the shore. In both grass and no grass areas, in the intertidal zone, all benthic organisms and all potential OM sources…
Sources of organic matter for inter-tidal consumers in Ascophyllum-shores (Sw Iceland): a multi stable isotope approach.
2007
Stable isotopes were used to examine the origin of organic matter in Icelandic Ascophyllum-based habitats, the role of different organic matters in filling intertidal food webs and the food preferences of the most abundant suspension feeders, grazers and predators. We selected three intertidal sites on the SW coast of Iceland where we sampled in early September 2004, organic matter sources (POM, SOM and most abundant primary producers, A. nodosum and F. vesciculosus) and the most abundant macrofauna species (barnacles, mussels, gastropods, sponge and crabs). Even though the primary production (Ascophyllum-based) was the same at the three study sites, the isotopic composition of common-among…
The influence of counterions and hydrophobic moieties on the thermostability of Langmuir-Blodgett multilayers
1994
Abstract Langmuir-Blodgett (LB) multilayers with various counterions and different organic moieties (one- and two-chain fatty acids, polymeric acid) are prepared to investigate on line temperature-dependent structural changes and desorption by small-angle X-ray scattering (SAXS), interference-enhanced reflection and Nomarsky microscopy. On temperature increase a sequence of phase transitions can be observed. A crystalline LB film melts to a fluid phase and eventually desorbs either from droplets or from a homogeneous film. The phase sequence depends on the counterion: nickel stearate and magnesium stearate melt while the layered structure is conserved; SAXS measurements reveal a continuous,…
B-DNA Structure and Stability as Function of Nucleic Acid Composition. Dispersion-Corrected DFT Study of Dinucleoside-Monophosphate Single and Double…
2013
actions of the sugar-phosphate skeleton with water; (6) hydrophobic interactions of the DNA cylindrical core, made up by the hydrogen-bonded and stacked nitrogen bases, with the water solvent. Recently, there has been increasing effort in developing and applying quantum chemical methods able to reproduce the structure of native B-DNA and to correctly describe the energy involved in the intrastrand and interstrand noncovalent interactions between the nucleotide monomers. This topic has been approached by both wave function methods and density functional theory. [2] Water solvent and sodium counterions also play an important role in the formation and relative stabilization of the double-helic…
Effective complexation of psychotropic phenethylammonium salts from a disodium dipyrazolate salt of macrocyclic structure
2002
The equilibrium stability constants (Ks) of ammonium pyrazolate complexes [L2−]2RN(R′)H2+ (3, R′ = H and 4, R′ = Me) formed from a macrocyclic disodium dipyrazolate salt 2[L2−] 2Na+ and ammonium salts (RNH3+X− or RN(Me)H2+X−) of psychotropic drugs and neurotransmitter catecholamines have been evaluated by electrochemical methods in DMSO solution. The resulting Ks values demonstrate that, except for (±)-amphetamine, the complexes formed by lipophilic primary [mescaline, (+)-amphetamine, (±)-p-methoxyamphetamine (PMA), (±)-3,4-methylenedioxyamphetamine (MDA)] and secondary [(±)-methamphetamine, (+)-methamphetamine and (±)-3,4-methylenedioxymethamphetamine (MDMA ‘ecstasy’)] phenethylamines are…
Sustainable nanocomposites based on halloysite nanotubes and pectin/polyethylene glycol blend
2013
Abstract This study was focused on the preparation and characterization of biofilms based on pectin/polyethylene glycol 20000 (PEG) blend and halloysite nanotubes (HNTs). The obtained blends loaded with a natural nanoclay are proposed as sustainable alternative to the polymers produced from non-renewable resources such as fossil fuels. Properties of technological interest have been monitored and they were correlated to the structural features of the nanocomposites. It turned out that the wettability of the films can be tuned by changing the composition and the distribution of HNTs into the material as well as the surface roughness. The tensile properties of the blend are enhanced by the pre…