Search results for " Stability"
showing 10 items of 1355 documents
Solubility and stability of liebigite, Ca2UO2(CO3)3·10H2O(cr), in dilute to concentrated NaCl and NaClO4 solutions at T = 22–80 °C
2019
Abstract The solubility and thermodynamic stability of a synthetic liebigite was investigated in NaCl and NaClO4 solutions within a wide range of ionic strength (0.03 m ≤ Im ≤ 5.61 m), pH (7 ≤ pHm ≤ 9, with pHm = –log [H+]) and temperature (22 °C ≤ T ≤ 80 °C) conditions. A comprehensive characterization of the synthetic solid phase using XRD, quantitative chemical analysis, TG–DTA, SEM–EDS, IR and Raman spectroscopy confirmed the stoichiometry of Ca2UO2(CO3)3·10H2O(cr). At room temperature, liebigite remains stable and controls the solubility of U(VI) in the investigated NaCl and NaClO4 systems with Im ≤ 0.51 m. For the same temperature but high ionic strength (5.61 m NaCl), liebigite trans…
Thermodynamic study of the interaction of long open-chain polyazaalkanes with cobalt(II) and nickel(II) ions
1993
Complexation equilibria between the open-chain terminally methylated polyamines 1,14-bis(methylamino)-3,6,9,12- tetraazatetradecane (L1), 1,17-bis(methylamino)-3,6,9,12,15-pentaazaheptadecane (L2), 1,20-bis(methylamino)- 3,6,9,12,15,18-hexaazaicosane (L3) and 1,23-bis(methylamino)-3,6,9,12,15,18,21-heptaazatricosane (L4) with Co2+ and Ni2+ have been studied by means of potentiometric and spectrophotometric methods in 0.15 mol dm−3 NaClO4 aqueous solution at 298.15 K The stability constants for the complexes formed have been determined from e.m.f, data. All these ligands form mononuclear ML2+ complexes of similar stability with Co2+ and Ni2+. Binuclear Co2L44+, Ni2L34+ and Ni2L44+ are also f…
Internal Structure and Dynamics of the Decamer D(ATGCAGTCAG) 2 In Li + -H 2 O Solution: A molecular Dynamics Simulation Study
2003
Molecular dynamics simulation of the decamer d(ATGCAGTCAG) 2 in aqueous solution, electroneutralized by Li + ions has been carried out. Emphasis is on the verification of the equilibrium conditions and the related structural and dynamical properties. Applicability of the kinetic part of Boltzmann's H function as a measure of thermodynamic equilibrium is tested. Overall structural stability has been confirmed by different RMSDs. Conformational and helicoidal parameters have been analyzed statistically and dynamically. Dynamical analysis reveals the existence of dynamical sub-states, which typically appear as abrupt changes from a mean level to another in the value of parameter. In statistica…
Complex formation equilibria between the acetazolamide ((5-acetamido-1,3,4-thiadiazole)-2-sulphonamide), a potent inhibitor of carbonicanhydrase, and…
1990
Abstract The stability constants for the equilibrium of complexation between acetazolamide and the divalent metal ions copper(II), nickel(II), zinc(II), and cobalt(II) have been determined by potentiometry both in water and in water-ethanol 50 vol. % solutions in 0.15 mol dm −3 NaNO 3 at 25°C. This mixed solvent has been used in order to obtain higher concentrations of acetazolamide in solution. For copper(II) and nickel(II), the binuclear species [Cu 2 (Acm) 2 ] and [Ni 2 (Acm) 3 ] 2− are detected in both solvents together with hydroxo species. The values of the stability constants are always higher in the mixed solvent than in water. For cobalt(II) and zinc(II), while in aqueous solution …
Thermal and Chemical Stability of Thiol Bonding on Gold Nanostars
2015
The stability of thiol bonding on the surface of star-shaped gold nanoparticles was studied as a function of temperature in water and in a set of biologically relevant conditions. The stability was evaluated by monitoring the release of a model fluorescent dye, Bodipy-thiol (BDP-SH), from gold nanostars (GNSs) cocoated with poly(ethylene glycol) thiol (PEG-SH). The increase in the BDP-SH fluorescence emission, quenched when bound to the GNSs, was exploited to this purpose. A maximum 15% dye release in aqueous solution was found when the bulk temperature of gold nanostars solutions was increased to T = 42 °C, the maximum physiological temperature. This fraction reduces 3-5% for temperatures …
The SESAMO early warning system for rainfall-triggered landslides
2016
The development of Web-based information systems coupled with advanced monitoring systems could prove to be extremely useful in landslide risk management and mitigation. A new frontier in the field of rainfall-triggered landslides (RTLs) lies in the real-time modelling of the relationship between rainfall and slope stability; this requires an intensive monitoring of some key parameters that could be achieved through the use of modern and often low-cost technologies. This work describes an integrated information system for early warning of RTLs that has been deployed and tested, in a prototypal form, for an Italian pilot site. The core of the proposed system is a wireless sensor network coll…
Global exponential stability of delayed Markovian jump fuzzy cellular neural networks with generally incomplete transition probability
2014
The problem of global exponential stability in mean square of delayed Markovian jump fuzzy cellular neural networks (DMJFCNNs) with generally uncertain transition rates (GUTRs) is investigated in this paper. In this GUTR neural network model, each transition rate can be completely unknown or only its estimate value is known. This new uncertain model is more general than the existing ones. By constructing suitable Lyapunov functionals, several sufficient conditions on the exponential stability in mean square of its equilibrium solution are derived in terms of linear matrix inequalities (LMIs). Finally, a numerical example is presented to illustrate the effectiveness and efficiency of our res…
Asymptotic stability of solutions to Volterra-renewal integral equations with space maps
2012
Abstract In this paper we consider linear Volterra-renewal integral equations (VIEs) whose solutions depend on a space variable, via a map transformation. We investigate the asymptotic properties of the solutions, and study the asymptotic stability of a numerical method based on direct quadrature in time and interpolation in space. We show its properties through test examples.
Distributed Consensus in Networks of Dynamic Agents
2006
Stationary and distributed consensus protocols for a network of n dynamic agents under local information is considered. Consensus must be reached on a group decision value returned by a function of the agents' initial state values. As a main contribution we show that the agents can reach consensus if the value of such a function computed over the agents' state trajectories is time invariant. We use this basic result to introduce a protocol design rule allowing consensus on a quite general set of values. Such a set includes, e.g., any generalized mean of order p of the agents' initial states. We demonstrate that the asymptotical consensus is reached via a Lyapunov approach. Finally we perfor…
Asynchronous L1 control of delayed switched positive systems with mode-dependent average dwell time
2014
Abstract This paper investigates the stability and asynchronous L 1 control problems for a class of switched positive linear systems (SPLSs) with time-varying delays by using the mode-dependent average dwell time (MDADT) approach. By allowing the co-positive type Lyapunov–Krasovskii functional to increase during the running time of active subsystems, a new stability criterion for the underlying system with MDADT is first derived. Then, the obtained results are extended to study the issue of asynchronous L 1 control, where “asynchronous” means that the switching of the controllers has a lag with respect to that of system modes. Sufficient conditions are provided to guarantee that the resulti…