Search results for " Structure"
showing 10 items of 25475 documents
Hierarchies of knowledge, incommensurabilities and silences in South African ECD policy: Whose knowledge counts?
2017
AbstractPolicy for young children in South Africa is now receiving high-level government support through the ANC’s renewed commitment to redress poverty and inequity and creating ‘a better life for all’ as promised before the 1994 election. In this article, I explore the power relations, knowledge hierarchies and discourses of childhood, family and society in National Curriculum Framework (NCF) as it relates to children’s everyday contexts. I throw light on how the curriculum’s discourses relate to the diverse South African settings, child rearing practices and world-views, and how they interact with normative discourses of South African policy and global early childhood frameworks. The NCF…
Hétérogénéité spatiale : principes et méthodes
2004
Spatial Heterogeneity : Principles and Methods This article has a dual purpose . First , it describes the main econometric specifications which can be used to represent spatial heterogeneity , reflected in an instability of parameters in space and / or a heteroscedasticity of error terms . Only the specifications valid in cross-section are examined . Second , it explains the links between spatial heterogeneity and autocorrelation , the other major feature of localised data , defined by the absence of independence between geographical observations . In particular , we look at the extent to which traditional tests of heteroscedasticity or instability need to be amended to take account of spat…
Service-learning in physical education teacher education: towards a critical and inclusive perspective
2020
The purpose of this study was to analyse the impact of service-learning (SL) in physical education teacher education students (PETEs). The PETEs (n = 169) completed one of the editions of a SL program carried out between 2015–2018. This program consisted of designing and leading motor game sessions to facilitate the inclusion of 116 children with special educational needs (SEN). The program was based on Kolb’s learning stages to promote reflection and critical thinking. Reflective journals were used as an instrument to gather information from their experiences. These data were analysed qualitatively through a multiphase approach, initial open-coding and axial coding, using NVivo (10) softwa…
The effect of blue-light-blocking lenses on retinal straylight
2021
Sometimes yellow-tinted lenses are recommended to help improve visual quality. As yellow lenses filter blue light, it is believed that their use could decrease the intensity of scattered light in the eye (retinal straylight). However, the results of some studies have contradicted this assumption (Van Os et al. 2017). Currently various nontinted blue-light-blocking lenses are used to protect the eyes from short-wavelength light. The objective of this study was to determine whether blue-light-blocking lenses affect the levels of retinal straylight in the eye. A straylight meter (C-Quant, Oculus) was used for retinal straylight measurements. The measurements were performed under four different…
Pd2Au36(SR)(24) cluster: structure studies
2015
The location of the Pd atoms in Pd2Au36(SC2H4Ph)(24), is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.
Two new organic-selenate salts: syntheses and crystal structures of bis(di-iso-propylammonium) selenate and di-n-butylammonium hydrogenoselenate
2017
Abstract Two new dialkyammonium selenate salts [i-Pr2NH2]2[SeO4] (1) and [n-Bu2NH2][HSeO4] (2) have been isolated and characterized by single-crystal X-ray diffraction. Salt 1 crystallizes in the monoclinic system, space group P21/n with a=8.7190(5), b=8.8500(4), c=22.5953(9) Å, β=94.6290(17)°, V=1737.84(14) Å3 and Z=4. Salt 2 crystallizes in the monoclinic system space group P21/n with a=10.9328(9), b=8.1700(6), c=13.8095(11) Å, β=97.130(3)°, V=1223.94(17) Å3 and Z=4. In both salts, dialkylammonium cations and selenate anions are connected through NH···O and OH···O hydrogen bonds. In the crystal structure, 1 and 2 are organized in layer-like arrangements. Structural characterizations were …
Charge radius changes of even-even neutron-rich Tellurium isotopes
2005
Laser spectroscopy based on resonant ionization of laser-desorbed atoms has been used to study the neutron-rich tellurium isotopes with the COMPLIS facility at ISOLDE-CERN. The isotope shift and the hyperfine structure of several neutron-rich Te isotopes: $^{120–136}$Te and $^{123m–133m}$Te have been measured. From the hyperfine structure and the isotope shift we can extract the magnetic and quadrupole moments and the change in the mean square charge radius respectively. The mean square charge radii of the even-even isotopes have been deduced and their comparison with the known data for the other elements near Z=50 is presented. The experimental $\delta$ is compared with that obtained from …
The NUMEN project @ LNS: Status and perspectives
2017
The NUMEN project aims at accessing experimentally driven information on Nuclear Matrix Elements (NME) involved in the half-life of the neutrinoless double beta decay (0νββ), by high-accuracy measurements of Heavy Ion (HI) induced Double Charge Exchange (DCE) reaction cross sections. In particular, the (18O,18Ne) and (20Ne,20O) reactions are used as tools for β+β+ and β−β− decays, respectively. In the experiments, performed at INFN - Laboratory Nazionali del Sud (LNS) in Catania, the beams are accelerated by the Superconducting Cyclotron (CS) and the reaction ejectiles are detected the MAGNEX magnetic spectrometer. The measured cross sections are challengingly low (a few nb), being the tota…
Spectroscopic characterization of alkaline earth uranyl carbonates
2005
A series of alkaline uranyl carbonates, M[UO{sub 2}(CO{sub 3}){sub 3}].nH{sub 2}O (M=Mg{sub 2}, Ca{sub 2}, Sr{sub 2}, Ba{sub 2}, Na{sub 2}Ca, and CaMg) was synthesized and characterized by inductively coupled plasma mass spectrometry (ICP-MS) and atomic absorption spectrometry (AAS) after nitric acid digestion, X-ray powder diffraction (XRD), and thermal analysis (TGA/DTA). The molecular structure of these compounds was characterized by extended X-ray absorption fine-structure (EXAFS) spectroscopy and X-ray photoelectron spectroscopy (XPS). Crystalline Ba{sub 2}[UO{sub 2}(CO{sub 3}){sub 3}].6H{sub 2}O was obtained for the first time. The EXAFS analysis showed that this compound consists of …
Total absorption γ -ray spectroscopy of niobium isomers
2019
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