Search results for " assi"
showing 10 items of 676 documents
A modified surgical approach for hard and soft tissue reconstruction of severe periimplantitis defects – Laser‐assisted periimplant defect regenerati…
2019
Robotic-Assisted Neck Dissection: Our Experience
2021
Abstract Introduction Robotic neck dissection surgery allows less invasiveness to significantly improve the aesthetic impact even though it does not compromise the principles of radical cancer procedure. Objective The aim of our work is to describe our personal experience with robotic neck dissection surgery. Methods A retrospective study was conducted by analyzing 10 patients subjected to a robotic neck dissection surgery. In the period from August 2012 to December 2018, these patients have been treated exclusively with robotic lateral-cervical dissection. Five of them were subjected to robotic-assisted transaxillary neck dissection (RATAND) and the other 5 treated with robotic-assisted re…
The role of extrinsic and intrinsic factors on departure decisions of a long-distance migratory passerine
2013
[EN] Factors determining departure decisions of migrants from a stopover site can be extrinsic and/or intrinsic but the relative role of each of these factors on departure decisions is still poorly known. Date and wind should be the main factors determining departure decisions in a long-distance migrant, which is expected to minimise duration of migration. Date was considered as an intrinsic factor and wind as an extrinsic one. We analysed the capture-recapture data of a long-distance migrant European songbird, the sedge warbler Acrocephalus schoenobaenus,from a stopover site in northern Iberia during the autumn migration period to quantify the relative importance of several factors on emig…
Microwave-assisted tandem cross metathesis intramolecular Aza-Michael reaction: an easy entry to cyclic beta-amino carbonyl derivatives.
2007
Hoveyda−Grubbs catalyst in combination with BF3·OEt2 efficiently promotes tandem cross metathesis intramolecular aza-Michael reaction between enones and unsaturated carbamates resulting in the creation of β-amino carbonyl units. The use of microwave irradiation dramatically accelerates the process, enhancing the synthetic utility of this methodology for the preparation of these types of derivatives. When enantiomerically enriched α-branched amines were used as starting materials, the process was also very efficient, although with modest selectivity in the newly created stereocenter. The use of microwave irradiation led to an interesting effect, inverting the selectivity in the addition proc…
Preguntas educativas para la tecnología digital como respuesta
2020
espanolEl desarrollo educativo con tecnologia digital no solo admite sofisticados artefactos tecnologicos, sino tambien inexorables preguntas. Este trabajo tiene como objetivo explorar de forma interrogativa la relacion entre educacion y tecnologia digital a traves de la caracterizacion de una serie de ambitos y preguntas que exigen rutas de reflexion, trabajo e investigacion mas alla de la pregunta por el material didactico en la educacion. Se inscribe en la reflexion pedagogica y busca aportar elementos que permitan identificar futuros itinerarios, paradojas o problemas de investigacion. El procedimiento metodologico, de corte cualitativo, fue el codiseno participativo en tres fases no se…
Ultrasound assisted reductive cleavage of eudesmane and guaiane γ-enonelactones. Synthesis of 1α,7α,10αH-guaian-4,11-dien-3-one and hydrocolorenone f…
2001
Abstract Ultrasound enhances the rate of reductive cleavage of the C6–oxygen bond of sesquiterpene enonelactones. trans-Eudesmanolides 1c–1g, cis-eudesmanolides 2a–2c, and trans-guaianolides 4a–4d react with Zn in acetic acid–H2O under sonochemical conditions to afford the corresponding sesquiterpene acids 3a–3g and 5a–5d, respectively in good yields. Starting from 5d two natural guaianes 1α,7α,10αH-guaian-4,11-dien-3-one (6) and hydrocolorenone (7) have been prepared in good yields through a straightforward sequence.
ChemInform Abstract: Ultrasound-Assisted Reductive Cleavage of Eudesmane and Guaiane γ-Enonelactones. Synthesis of 1α,7α,10αH-Guaian-4,11-dien-3-one …
2010
Abstract Ultrasound enhances the rate of reductive cleavage of the C6–oxygen bond of sesquiterpene enonelactones. trans-Eudesmanolides 1c–1g, cis-eudesmanolides 2a–2c, and trans-guaianolides 4a–4d react with Zn in acetic acid–H2O under sonochemical conditions to afford the corresponding sesquiterpene acids 3a–3g and 5a–5d, respectively in good yields. Starting from 5d two natural guaianes 1α,7α,10αH-guaian-4,11-dien-3-one (6) and hydrocolorenone (7) have been prepared in good yields through a straightforward sequence.
ChemInform Abstract: Ultrasound-Assisted Reductive Cleavage of Sesquiterpene γ- Enonelactones.
2010
Abstract Ultrasound enhances the rate of reductive cleavage of the C 6 -oxygen bond of several cis - and trans - sesquiterpene γ-enonelactones. Interestingly ultrasound overrides the stereoelectronic requirements for the reductive cleavage of the most usually occurring sesquiterpene trans -lactones.
Problematiche domestiche per la terza età
2015
L’ampia e crescente diffusione del Morbo di Alzheimer, la limitata e non risolutiva efficacia delle terapie disponibili e le enormi risorse necessarie per la sua gestione (sociali, emotive, organizzative ed economiche), che ricadono in gran parte sui familiari e che spesso comportano la delocalizzazione dell’anziano malato verso le residenze per “non-autosufficienti”, la rendono una delle patologie a più grave impatto sociale del mondo. Per tale ragione, nel nostro Paese le risposte progettuali alle diverse problematiche attinenti agli anziani affei da demenza o da Alzheimer sono oggi sempre più urgenti e complesse e in termini architettonici ve- dono la proposizione, tra le tipologie più r…
Solving Graph Coloring Problems Using Learning Automata
2008
The graph coloring problem (GCP) is a widely studied combinatorial optimization problem with numerous applications, including time tabling, frequency assignment, and register allocation. The growing need for more efficient algorithms has led to the development of several GCP solvers. In this paper, we introduce the first GCP solver that is based on Learning Automata (LA). We enhance traditional Random Walk with LA-based learning capability, encoding the GCP as a Boolean satisfiability problem (SAT). Extensive experiments demonstrate that the LA significantly improve the performance of RW, thus laying the foundation for novel LA-based solutions to the GCP.