Search results for " atom"
showing 10 items of 1526 documents
Densified low-hygroscopic form of P2O5 glass
2011
P2O5 compound is an archetypical glass-forming oxide with a record-high hygroscopicity, which makes both the study and potential industrial uses of the glass extremely difficult. We found that the quenching from the P2O5 melt under ultrahigh pressures enables obtaining densified P2O5 glasses with a residual densification up to 12% at normal conditions. These glasses have a low hygroscopicity and can exist under air conditions for several weeks. An examination of the structure of the new form of P2O5 glass reveals a significant increase in neighbors of terminal oxygen atoms in the second coordination sphere and a cardinal decrease of the volume of nanovoids in the glassy matrix. The research…
Magnetic octupole moment of Yb-173 using collinear laser spectroscopy
2021
The hyperfine constants of the $4{f}^{14}6s6p^{3}P_{2}^{o}$ state in neutral Yb have been measured using three different dipole transitions. This state was recently shown to have a comparatively large hyperfine magnetic octupole splitting, and thus a puzzlingly large magnetic octupole moment. The measurement is performed using collinear laser spectroscopy on a fast atomic beam, which provides a straightforward route to probing long-lived metastable atomic states with high resolution. From the combined analysis of all three lines we find no significant evidence for a nonzero octupole moment in $^{173}\mathrm{Yb}$.
ESR response to 60Co-rays of ammonium tartrate pellets using as additive
2007
Abstract This work presents experimental results regarding a new ammonium tartrate blend for ESR dosimetry, with a higher sensitivity and a lower lowest detectable dose (LDD) to Co 60 γ -rays than the recently used pure ammonium tartrate. The blend composed by ammonium tartrate and gadolinium-oxide ( Gd 2 O 3 ) shows a greater sensitivity ( ∼ 2 times) and a smaller LDD than ammonium tartrate. The increased sensitivity was mainly attributed to the great atomic number ( Z = 64 ) of gadolinium, that increases the effective atomic number of the blend; the interaction probability with photons and consequently the radical yield is therefore enhanced. Moreover ammonium tartrate with Gd 2 O 3 has a…
Spectroscopy of an optical excited Ga doped SiO2 surface
2007
Abstract We present the first spectroscopical analysis of the Ga/SiO2 surface interaction in hot environment. This interaction gives rise to inclusions of Ga atoms inside the silica matrix that produce structural changes and modify the SiO2 optical characteristics. This paper discusses both the time- and the frequency-resolved spectra of the fluorescence emission following UV pulsed laser excitation of the so “doped” silica in the range 15,000–28,000 cm−1. The investigation is completed by the electron paramagnetic resonance (EPR) spectra of two high-purity synthetic silica samples of commercial origin after thermal treatment in presence and in absence of a Ga atmosphere.
An Experimental and Computational Study on the Effect of Al(OiPr)3 on Atom-Transfer Radical Polymerization and on the Catalyst-Dormant Chain Halogen …
2005
International audience; Compound Al(OiPr)3 is shown to catalyze the halide-exchange process leading from [Mo(Cp)Cl2(iPrN=CH-CH=NiPr)] and CH3CH(X)COOEt (X=Br, I) to the mixed-halide complexes [Mo(Cp)ClX(iPrN=CH-CH=NiPr)]. On the other hand, no significant acceleration is observed for the related exchange between [MoX3(PMe3)3] (X=Cl, I) and PhCH(Br)CH3, by analogy to a previous report dealing with the RuII complex [RuCl2(PPh3)3]. A DFT computation study, carried out on the model complexes [Mo(Cp)Cl2(PH3)2], [MoCl3(PH3)3], and [RuCl2(PH3)3], and on the model initiators CH3CH(Cl)COOCH3, CH3Cl, and CH3Br, reveals that the 16-electron RuII complex is able to coordinate the organic halide RX in a…
A new off-line ion source facility at IGISOL
2019
An off-line ion source station has been commissioned at the IGISOL (Ion Guide Isotope Separator On-Line) facility. It offers the infrastructure needed to produce stable ion beams from three off-line ion sources in parallel with the radioactive ion beams produced from the IGISOL target chamber. This has resulted in improved feasibility for new experiments by offering reference ions for Penning-trap mass measurements, laser spectroscopy and atom trap experiments.
Two-color ionization of hydrogen by short intense pulses
2010
Photoelectron energy spectra resulting by the interaction of hydrogen with two short pulses having carrier frequencies, respectively, in the range of the infrared and XUV regions have been calculated. The effects of the pulse duration and timing of the X-ray pulse on the photoelectron energy spectra are discussed. Analysis of the spectra obtained for very long pulses show that certain features may be explained in terms of quantum interferences in the time domain. It is found that, depending on the duration of the X-ray pulse, ripples in the energy spectra separated by the infrared photon energy may appear. Moreover, the temporal shape of the low frequency radiation field may be inferred by …
Narrow and contrast resonance of increased absorption in Λ-system observed in Rb cell with buffer gas
2009
International audience; We report observation of a narrow (sub-natural) and high-contrast resonance of increased absorption (“bright” resonance) in Rb cell with Ne buffer gas under previously unexplored experimental conditions for coupling and probe radiation configuration. The coupling laser-stabilized frequency is detuned by ~3 GHz from 5S1/2, Fg=3 → 5P3/2, Fe=2,3,4 transitions, while the probe laser frequency is scanned across these transitions. We believe the bright resonance formation, occurring when the probe laser frequency is blue-shifted from the coupling frequency by a value of the ground state hyperfine splitting, is caused predominantly by a 2-photon absorption of the probe radi…
Ab initio study on the mechanism of the HCO+O2→HO2+CO reaction
2003
Abstract The gas-phase reaction HCO+O 2 →CO+HO 2 has been investigated by means of ab initio calculations. The mechanism can proceed through either a direct hydrogen abstraction or addition of O 2 to the formyl radical. The energy barriers calculated at the QCISD(T)/6-311G(2df,2p) level of theory upon QCISD/6-311G(d,p) optimized structures are, respectively, of 2.98 kcal mol −1 for the direct abstraction and of 2.26 kcal mol −1 for the addition. Thus, the results obtained show that there is not a dominant pathway in the HCO+O 2 reaction under atmospheric conditions of temperature and pressure.
Calculation of the rate constants for hydrogen abstraction reactions by Hydroperoxyl radical from Methanol, and the investigation of stability of CH3…
2020
Abstract Master equation (ME) with Lennard-Jones potential utilized to simulate the collision between CH3OH and HO2 radical in the presence of bath gas. The reaction mechanism explored through the lowest doublet potential energy surface at CCSD(T)/aug-cc-pVTZ//B3LYP/aug-cc-pVTZ level of theory that is barrierless and forms shallow energized intermediate at the entrance channel. The investigation of the fractional population showed that lifetime of CH3OH.HO2 intermediate (INT*) is fairly short due to its shallow depth, and at the low temperature, most reaction takes place by re-dissociation back to reactants and also when the pressure is high enough, the INT* is thermalized and comes into eq…