Search results for " atom"
showing 10 items of 1526 documents
Analytical methodologies for atomic spectrometric determination of metallic oxides in UV sunscreen creams.
2000
In this study, methodologies for determining titanium oxide, zinc oxide and iron oxide are proposed and assayed in commercial sunscreen products. The proposed methodology for TiO2, determination in sunscreens is based on a microwave-assisted treatment for digesting the organic components in a closed teflon reactor in presence of HNO3 and HCl. Titanium is determined by inductive coupled plasma emission spectrometry (ICP-AES). The proposed methodologies for measuring ZnO and Fe2O3 are based on a sample emulsification in water with a non ionic tensioactive and IBMK, followed by Zn and Fe determination by flame atomic absorption spectrometry (FAAS). The methodologies allow a precise and accurat…
Continuous frames for unbounded operators
2021
Few years ago G\u{a}vru\c{t}a gave the notions of $K$-frame and atomic system for a linear bounded operator $K$ in a Hilbert space $\mathcal{H}$ in order to decompose $\mathcal{R}(K)$, the range of $K$, with a frame-like expansion. These notions are here generalized to the case of a densely defined and possibly unbounded operator on a Hilbert space $A$ in a continuous setting, thus extending what have been done in a previous paper in a discrete framework.
The General Antiparticle Spectrometer (GAPS) - Hunt for dark matter using low energy antideuterons
2011
The GAPS experiment is foreseen to carry out a dark matter search using a novel detection approach to detect low-energy cosmic-ray antideuterons. The theoretically predicted antideuteron flux resulting from secondary interactions of primary cosmic rays with the interstellar medium is very low. So far not a single cosmic antideuteron has been detected by any experiment, but well-motivated theories beyond the standard model of particle physics, e.g., supersymmetry or universal extra dimensions, contain viable dark matter candidates, which could led to a significant enhancement of the antideuteron flux due to self-annihilation of the dark matter particles. This flux contribution is believed to…
Full configuration interaction calculation of the low lying valence and Rydberg states of BeH
2007
The all-electron full configuration interaction (FCI) vertical excitation energies for some low lying valence and Rydberg excited states of BeH are presented in this article. A basis set of valence atomic natural orbitals has been augmented with a series of Rydberg orbitals that have been generated as centered onto the Be atom. The resulting basis set can be described as 4s2p1d/2s1p (Be/H) + 4s4p3d. It allows to calculate Rydberg states up to n= {3,4,5} of the s, p, and d series of Rydberg states. The FCI vertical ionization potential for the same basis set and geometry amounts to 8.298 eV. Other properties such as FCI electric dipole and quadrupole moments and FCI transition dipole and qua…
Mixed‐valence trinuclear manganese clusters : Influence of the electronic transfer on the magnetic properties
1990
The magnetic behavior of mixed‐valence trinuclear clusters d4‐d4‐d5 is discussed on the basis of a model which takes into account valence delocalization and Heisenberg exchange. This model considers the competing effect between the electronic transfer and the localization of the extra electron due to an asymmetry of the triangular entity. The magnetic properties of the mixed‐valence oxo‐centered Mn(II)‐Mn(III)‐Mn(III) complexes formulated as Mn3O(O2CR)6L3 (R=Me, L=pyridine) are discussed on the basis of the developed model, supporting a significant intramolecular electron transfer. A comparison of these results to those previously reported by assuming a valence‐trapped model is given. Carlo…
Complete-active-space second-order perturbation theory (CASPT2//CASSCF) study of the dissociative electron attachment in canonical DNA nucleobases ca…
2015
Low-energy (0-3 eV) ballistic electrons originated during the irradiation of biological material can interact with DNA/RNA nucleobases yielding transient-anion species which undergo decompositions. Since the discovery that these reactions can eventually lead to strand breaking of the DNA chains, great efforts have been dedicated to their study. The main fragmentation at the 0-3 eV energy range is the ejection of a hydrogen atom from the specific nitrogen positions. In the present study, the methodological approach introduced in a previous work on uracil [I. González-Ramírez et al., J. Chem. Theory Comput. 8, 2769-2776 (2012)] is employed to study the DNA canonical nucleobases fragmentations…
Use and limitations of ICP-OES in wine analysis
1989
At present, some 50 inorganic components in wine can be detected, of which 8 are mineral matter at concentrations down to 1 mg/l, about 25 are trace elements with concentrations of 0.001–0.1 mg/l, and about 20 are ultratrace elements at concentrations below 1 μg/1. It has been shown that ICP-OES, a typical multielement detection method, permits the fast and reliable simultaneous determination of whole range of these inorganic species in wine, and thus can help in solving practical problems in wine manufacture. For instance, the metal content of wine can be checked, and corrosion and contamination monitored. Ten trace elements (Al, Cd, Co, Cr, Cu, Fe, Mn, Pb, V, Zn) which may be toxic or to …
Activity investigation of pinostrobin towards herpes simplex virus-1 as determined by atomic force microscopy
2009
In the present study, the antiviral activity of pinostrobin towards herpes simplex virus-1 (HSV-1) was investigated by MTT assay and atomic force microscopy. Pinostrobin can inhibit HSV-1 replication with 50% effective concentration (EC(50)) of 22.71 ± 1.72 μg/ml. MTT assay showed HSV-1 was significantly inhibited when pretreated with pinostrobin, with the inhibition of 85.69 ± 2.59%. Significant changes in morphology and size of HSV-1 were observed by atomic force microscopy (AFM) in response to pinostrobin treatment. AFM topography and phase images showed that with increasing time, the envelope was shedded and damaged, finally leading to virus inactivation. With increasing concentration, …
Low-temperature atomic layer deposition of SiO2/Al2O3 multilayer structures constructed on self-standing films of cellulose nanofibrils
2018
In this paper, we have optimized a low-temperature atomic layer deposition (ALD) of SiO 2 using AP-LTO® 330 and ozone (O 3 ) as precursors, and demonstrated its suitability to surface-modify temperature-sensitive bio-based films of cellulose nanofibrils (CNFs). The lowest temperature for the thermal ALD process was 80°C when the silicon precursor residence time was increased by the stop-flow mode. The SiO 2 film deposition rate was dependent on the temperature varying within 1.5–2.2 Å cycle −1 in the temperature range of 80–350°C, respectively. The low-temperature SiO 2 process that resulted was combined with the conventional trimethyl aluminium + H 2 O process in order to prepare thin mul…
Detection of bias errors in ETAASDetermination of copper in beer and wine samples
2005
A method that evidences changes in the shape of the absorbance profiles obtained by graphite furnace atomic absorption spectrometry (ETAAS) is proposed. The method is based upon the apparent content curves model previously described for molecular spectroscopy and it permits the detection of possible sources of bias errors. Moreover, a procedure that allows to detect the existence of constant and/or proportional errors is also described. Both models has been applied to the determination of copper in wine and beer samples with and without pre-treatment of the samples. Results obtained evidence the usefulness of the proposed models.