Search results for " characterization"

showing 10 items of 310 documents

Taking advantage of the functional synergism between carbon nanotubes and graphene nanoplatelets to obtain polypropylene-based nanocomposites with en…

2020

Carbon Nanotubes (CNT) and Graphene Nanoplatelets (GNP) were incorporated in Polypropylene (PP) as single filler (CNT=1, 2 and 4 %wt. and GNP=2, 4, and 6 %wt.) and in hybrid form (CNT:GNP weight ratio 2:2, 2:4 and 4:2) using a prototype miniature Twin Screw Extruder (TSE) coupled with a double slit rheological die, in order to assess in-line the extent of nanofiller dispersion and to deliver PP-based nanocomposites with enhanced thermo-oxidative stability. The morphological, electrical and mechanical properties, as well as the resistance to thermal and photo degradation of the composites containing single nanofillers (PP/CNT and PP/GNP) were compared with those of hybrid PP based nanocompos…

MorphologyFiller (packaging)Materials sciencePolymers and PlasticsHybrid PP based nanocompositesGeneral Physics and Astronomy02 engineering and technologyCarbon nanotubeOxidative resistance010402 general chemistryIn-line rheology characterization01 natural scienceslaw.inventionchemistry.chemical_compoundRheologylawMaterials ChemistryPhotodegradationPolypropyleneScience & TechnologyNanocompositeOrganic ChemistryMechanical behaviour021001 nanoscience & nanotechnologyDurability0104 chemical sciencesSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialichemistryChemical engineering0210 nano-technologyDispersion (chemistry)European Polymer Journal
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Pt(II) nitrile complexes: New insights on old complexes from a combined experimental and theoretical study

2017

Abstract The spectroscopic characterization of cis - and trans -[PtCl 2 (NCR) 2 ] (R = CH 3 , Ph, CH 2 Ph) was reported in solid state and solution phase. Moreover, the X-ray structures of cis -[PtCl 2 (NCCH 3 ) 2 ], cis - and trans -[PtCl 2 (NCPh) 2 ] were redetermined at low temperature. FT-IR and NMR showed a blue-shift and a slight shielding of the νCN and δ ( 13 C CN ) values, respectively, in a counterintuitive way with respect to the well known improved reactivity towards nucleophiles of nitriles ligands coordinated to platinum(II), when compared to their free forms. These spectroscopic behaviors were also confirmed by theoretical experiments at DFT level. Moreover, DFT approach show…

NitrileStereochemistrySolid-statechemistry.chemical_elementTheoretical calculations010402 general chemistry01 natural sciencesMedicinal chemistryCP MAS NMR studyInorganic Chemistrychemistry.chemical_compoundNucleophilePlatinum nitrile complexesMaterials ChemistryOrbital controlReactivity (chemistry)Platinum nitrile complexePhysical and Theoretical Chemistry010405 organic chemistrySolution phase0104 chemical sciencesBenzonitrilechemistrySettore CHIM/03 - Chimica Generale E InorganicaCP MAS NMR study; Platinum nitrile complexes; Spectroscopic characterization; Theoretical calculationsSpectroscopic characterizationPlatinum
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Some experimental issues of AFM tip blind estimation. The effect of noise and resolution

2006

The convolution of tip shape on sample topography can introduce significant inaccuracy in an AFM image, when the tip radius is comparable to the typical dimension of the sample features to be observed. The blind estimation method allows one to obtain information on the AFM tip through an unknown characterizer sample and thus to perform the deconvolution of the tip shape from an image. When applying the blind estimation method to determine the AFM tip shape, some apparently trivial issues relating to the experimental operating parameters must be taken into account. In this paper, the effects of the operating parameters, e.g., sampling intervals (resolution) and instrumental noise, have been …

Noise (signal processing)Applied MathematicsAcousticsResolution (electron density)Sampling (statistics)atomic force microscopy tip characterization blind estimationRadiusSample (graphics)ConvolutionDimension (vector space)StatisticsDeconvolutionInstrumentationEngineering (miscellaneous)Mathematics
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Non-invasive characterization of archaeological polychrome pottery and metallic artefacts: advantage and limits of XRF in situ analysis

2014

Non-invasive characterization polychrome pottery metallic artefacts XRF
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Population genetics of cucumber mosaic virus infecting medicinal, aromatic and ornamental plants from northern Italy

2012

An epidemiological survey carried at the Herb Garden of Casola Valsenio (Emilia Romagna region; Northern Italy) from 2006 to 2009 resulted in finding Cucumber mosaic virus (CMV) as the infectious agent of several ornamental, medicinal and aromatic plants. All CMV-infected plant species showed leaf symptoms followed, in some cases, by flower colour-breaking and stunting. Genetic analysis consisted in the characterization of movement protein gene of each CMV-isolate by single strand polymorphism analysis and sequencing. Phylogenetic trees identified only two isolates as member of subgroup II, while all other isolates were part of subgroup IA. This survey confirms an unexpected increment of CM…

Nonsynonymous substitutionORNAMENTAL PLANTSMolecular Sequence DataPopulationPopulation geneticsBiologyGENETIC CHARACTERIZATIONCucumovirusNucleotide diversityCucumber mosaic virusVirologyGenetic variationBotanyCluster AnalysisSelection GeneticeducationPhylogenyGeneticseducation.field_of_studySequence Homology Amino AcidPhylogenetic treeCMVGenetic Variationfood and beveragesSettore AGR/12 - Patologia VegetaleSequence Analysis DNAGeneral MedicinePlantsPlant Viral Movement ProteinsGenetics PopulationAmino Acid SubstitutionItalyGenetic structureRNA ViralOFFICINAL PLANTSCMV Population genetics
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Hydro-Mechanical Behaviour of a Sand-Bentonite Mixture for the Confinement of Nuclear Wastes

2019

The established concept for the protection of the biosphere from high-level nuclear wastes consists in the use of multi-barrier systems in deep geological repository, for which clayey geomaterials are key elements. Bentonite-based materials are selected as buffer and backfilling materials. Once in place, the barriers will be subjected to a series of severe loadings, including strong variations of suction (i.e. wetting and drying cycles). The paper presents selected results from a large ongoing research work to investigate the behaviour of bentonite-based materials in the context of nuclear waste disposal. In particular, the paper focuses on the response of a Sand/Bentonite mixture under dif…

Nuclear wasteSuctionRadioactive wasteContext (language use)Microstructural characterizationBentonite-based materialHydro-mechanical behaviourBentoniteDeep geological repositorymedicineEnvironmental scienceWater retention behaviourGeotechnical engineeringWettingSwellingmedicine.symptomDry density
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Use of Tiger Nut (Cyperus esculentus L.) Oil Emulsion as Animal Fat Replacement in Beef Burgers

2020

The present study evaluated the replacement of beef fat in beef burgers using a tiger nut (Cyperus esculentus L.) oil emulsion, in order to reduce total fat and saturated fatty acids in the studied samples. Three formulations were processed: Control&mdash

NutHealth (social science)Saturated fatANÁLISE SENSORIAL DE ALIMENTOSPlant Sciencelcsh:Chemical technologyHealth Professions (miscellaneous)Microbiologyfatty acid profilechemistry.chemical_compoundfat-replacer0404 agricultural biotechnologyCyperusphysicochemical characterizationlcsh:TP1-1185Food sciencesensory acceptancechemistry.chemical_classificationAnimal fatbiologyTigerdigestive oral and skin physiologyfungi0402 animal and dairy sciencefood and beverages04 agricultural and veterinary sciencesbiology.organism_classification040401 food science040201 dairy & animal scienceOleic acidchemistryChewinesssense organsFood SciencePolyunsaturated fatty acidFoods
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Occurrence and exposure assessment of mycotoxins in ready-to-eat tree nut products through ultra-high performance liquid chromatography coupled with …

2020

Tree nuts have become popular snacks due to their attributed benefits in the health state. Nevertheless, their susceptibility to fungal contamination lead to the occurrence of potentially dangerous mycotoxins. Hence, the aim of this work was to evaluate the presence of mycotoxins in ready-to-eat almonds, walnuts, and pistachios from Italian markets. The most relevant mycotoxin found in almonds was α-zearalanol in 18% of samples (n = 17) ranging from 3.70 to 4.54 µg/kg. Walnut samples showed frequent contamination with alternariol, present in 53% of samples (n = 22) at levels from 0.29 to 1.65 µg/kg. Pistachios (n = 15) were the most contaminated commodity, with β-zear…

NutTolerable daily intakeEndocrinology Diabetes and Metabolismlcsh:QR1-502AlternariolBiologyAlmondOrbitrap01 natural sciencesBiochemistrylcsh:MicrobiologyArticlelaw.inventionchemistry.chemical_compoundQ-Exactive Orbitrap0404 agricultural biotechnologylawmycotoxinsFood scienceMycotoxinPistachioMolecular Biologyalmonds; pistachios; walnuts; mycotoxins; Q-Exactive Orbitrap; risk characterizationExposure assessmentMycotoxinWalnuts010401 analytical chemistryRisk characterizationalmonds04 agricultural and veterinary sciencesContaminationAlternariabiology.organism_classification040401 food science0104 chemical scienceschemistrypistachios
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Characterization of multifunction meters based on integrated devices in the presence of harmonic distortion

2008

This paper is focused on the problem of the metrological characterization of multifunction static meters based on integrated devices, in both reference and actual operating conditions. The influence of the measurement transducers on the performance of such meters is also discussed. The analysis is supported by some experimental tests, which were carried out on a meter based on a commercial integrated device, both in the absence and in the presence of the measurement transducers.

Operating conditionExperimental testIntegrated deviceMetrological characterizationSettore ING-INF/07 - Misure Elettriche E Elettroniche
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Fiber-based measurement of temporal intensity and phase profiles of an optical telecommunication pulse through self-phase modulation

2018

International audience; We propose and experimentally validate an all-fiber based approach to characterize the phase and intensity profiles of optical pulses. Based on three optical spectra affected by different levels of self-phase modulation, we were able to reconstruct the temporal details of pulses typical of optical telecommunications.

Optical fiberMaterials scienceOptical communicationPhysics::OpticsPolarization-maintaining optical fiber02 engineering and technologyOptical time-domain reflectometerOptical modulation amplitudepulse characterization01 natural scienceslaw.invention010309 opticsOpticslaw0103 physical sciencesElectrical and Electronic EngineeringSelf-phase modulationfiber optics[PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics][ PHYS.PHYS.PHYS-OPTICS ] Physics [physics]/Physics [physics]/Optics [physics.optics]business.industrynonlinear optics021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic Materials0210 nano-technologybusinessUltrashort pulseBandwidth-limited pulse
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