Search results for " chiral"

Modification of Dzyaloshinskii-Moriya-Interaction-Stabilized Domain Wall Chirality by Driving Currents

2018

We measure and analyze the chirality of Dzyaloshinskii-Moriya-interaction (DMI) stabilized spin textures in multilayers of $\mathrm{Ta}|{\mathrm{Co}}_{20}{\mathrm{F}}_{60}{\mathrm{B}}_{20}|\mathrm{MgO}$. The effective DMI is measured experimentally using domain wall motion measurements, both in the presence (using spin-orbit torques) and absence of driving currents (using magnetic fields). We observe that the current-induced domain wall motion yields a change in effective DMI magnitude and opposite domain wall chirality when compared to field-induced domain wall motion (without current). We explore this effect, which we refer to as current-induced DMI, by providing possible explanations for…

Novel σ1 antagonists designed for tumor therapy: Structure – activity relationships of aminoethyl substituted cyclohexanes

2021

Abstract Depending on the substitution pattern and stereochemistry, 1,3-dioxanes 1 with an aminoethyl moiety in 4-position represent potent σ1 receptor antagonists. In order to increase the stability, a cyclohexane ring first replaced the acetalic 1, 3-dioxane ring of 1. A large set of aminoethyl substituted cyclohexane derivatives was prepared in a six-step synthesis. All enantiomers and diastereomers were separated by chiral HPLC at the stage of the primary alcohol 7, and their absolute configuration was determined by CD spectroscopy. Neither the relative nor the absolute configuration had a large impact on the σ1 affinity. The highest σ1 affinity was found for cis-configured benzylamines…

πNscattering in relativistic baryon chiral perturbation theory reexamined

2011

We have analyzed pion-nucleon scattering using the manifestly relativistic covariant framework of infrared regularization up to $\mathcal{O}({q}^{3})$ in the chiral expansion, where $q$ is a generic small momentum. We describe the low-energy phase shifts with a similar quality as previously achieved with heavy baryon chiral perturbation theory, $\sqrt{s}\ensuremath{\lesssim}1.14$ GeV. New values are provided for the $\mathcal{O}({q}^{2})$ and $\mathcal{O}({q}^{3})$ low-energy constants, which are compared with previous determinations. This is also the case for the scattering lengths and volumes. Finally, we have unitarized the previous amplitudes and as a result the energy range where data …

Measurements of the Generalized Electric and Magnetic Polarizabilities of the Proton at LowQ2Using the Virtual-Compton-Scattering Reaction

2006

Experimental details of a virtual Compton scattering (VCS) experiment performed on the proton at the MIT-Bates out-of-plane scattering facility are presented. The VCS response functions ${P}_{LL}\ensuremath{-}{P}_{TT}/\phantom{{P}_{TT}\ensuremath{\varepsilon}}\ensuremath{\varepsilon}$ and ${P}_{LT}$ have been measured at ${Q}^{2}=0.057\phantom{\rule{0.28em}{0ex}}{\mathrm{GeV}}^{2}/{c}^{2}$. The generalized electric and magnetic polarizabilities, $\ensuremath{\alpha}({Q}^{2})$ and $\ensuremath{\beta}({Q}^{2})$, and the mean-square electric polarizability radius$\ensuremath{\langle}{r}_{\ensuremath{\alpha}}^{2}\ensuremath{\rangle}$ are obtained from a dispersion analysis of the data. The resu…

Aggregati supramolecolari di tensioattivi in fase gassosa: formazione e solubilizzazione di aminoacidi

A theoretical and experimental study of the racemization process of hexaaza[5]helicenes

2014

A dynamic 1H NMR study, together with DFT calculations, of bis-([1,2,3]triazolo)[1,5-a:5′,1′-k][1,10]phenanthroline 2 has allowed to identify the ring and open forms of a new example of ring/chain tautomerism, as well as their interconversion barriers (ring/ring and ring/open). The barrier of the exchange process between the chain forms and the ring form was found higher than the 'racemization' process in the closed form, so the ring opening does not contribute to the 'racemization'. The di-1,10-methyl and di-1,10-iodo derivatives have been prepared and their properties calculated.

Enantioselective Strecker Reaction Catalyzed by an Organocatalyst Lacking a Hydrogen-Bond-Donor Function

2007

Chiral Self‐Sorting of trans ‐Chelating Chiral Ligands upon Formation of Pd II Complexes (Eur. J. Inorg. Chem. 15/2014)

2014

The importance of supramolecular reaction media in catalysis

Influence of thermally induced structural transformations on the magnetic and luminescence properties of tartrate-based chiral lanthanide organic-fra…

2020

This work reports on the synthesis and characterization of five enantiomeric pairs of isostructural 3D metal-organic frameworks (MOFs) with the general formula {[Ln2(μ4-tar)2(μ-tar)(H2O)2]·xH2O}n [where Ln(iii) = Tb (Tb-L and Tb-D), Dy (Dy-L and Dy-D), Ho (Ho-L and Ho-D), Er (Er-L and Er-D) and Tm (Tm-L and Tm-D); tar = tartrate (d- or l-) and x = 3 or 4 depending on the counterpart], which possess interesting luminescence and magnetic properties. These MOFs undergo progressive and reversible dehydration processes upon controlled heating yielding three crystalline phases (Ln-L′, Ln-L′′ and Ln-L′′′). Alternating current magnetic measurements on Tb, Dy and Er-based compounds exhibit field ind…