Search results for " chiral"

LC-Polymers with Axial Chirality

1991

Abstract Liquid crystalline polymers with axial chirality are prepared. These polymers are chiral, not due to a single asymmetric carbon atom, but due to a larger molecular fragment, which is chiral as a whole. They exhibit cholesteric and chiral smectic C* phases. Dielectric spectroscopy proves strong ferroelectric properties in the chiral smectic C* phases of these polymers.

Special Calixarenes by Directed Syntheses

1997

The synthesis of special calixarenes and calixarene-like macrocyclic compounds via stepwise procedures and fragment condensation is reviewed. Among the compounds available are exo- and endo-calixarenes consisting of different phenolic units, having bridges other than methylene or showing inherent chirality (Cn-symmetry). Macrobi- and -tricyclic molecules such as bridged calixarenes, double calixarenes, bicyclocalixarenes and annelated calixarenes are also described. Single crystal X-ray structures are reported for several compounds. Some properties like conformational barriers, pKa values or the ability to complex metal ions are discussed, showing the potential of these compounds which may …

Enantioselective recognition of alfa-amino acids by binary complexes fluorophore/cyclodextrin

Binary complexes heptakis-(6-amino)-(6-deoxy)-beta-cyclodextrin/fluorophore: structural investigation and chiral recognition

Complete One-Loop Renormalization of the Higgs-Electroweak Chiral Lagrangian

2018

The electroweak sector of the Standard Model can be formulated in a way similar to Chiral Perturbation Theory (ChPT), but extended by a singlet scalar. The resulting effective field theory (EFT) is called Higgs-Electroweak Chiral Lagrangian (EWCh$\mathcal{L}$) and is the most general approach to new physics in the Higgs sector. It solely assumes the pattern of symmetry breaking leading to the three electroweak Goldstone bosons (i.e. massive $W$ and $Z$) and the existence of a Higgs-like scalar particle. The power counting of the EWCh$\mathcal{L}$ is given by a generalization of the momentum expansion of ChPT. It is connected to a loop expansion, making the theory renormalizable order by ord…

Effective theory approaches to heavy meson resonances based on non-perturbative low energy two-meson dynamics

2019

This dissertation provides a theoretical effective description of a special class of hadronic meson states with charm and bottom quark content and their associated phenomenology. The considered states are difficult to be accommodated in CQMs and are candidates to be interpreted as meson molecules. This relies on the assumption that their main properties can be described by means of an effective low energy interaction of two more fundamental mesons. We have paid special attention to the relevant symmetries of QCD and two-body unitarity to construct the low energy effective meson-meson interactions. We have investigated the predictions of the Next-to-Leading Order (NLO) Unitary Heavy Meson Ch…

Chiral Magneto-Electrochemistry

2018

Magneto-electrochemistry (MEC) is a unique paradigm in science, where electrochemical experiments are carried out as a function of an applied magnetic field, creating a new horizon of potential scientific interest and technological applications. Over time, detailed understanding of this research domain was developed to identify and rationalize the possible effects exerted by a magnetic field on the various microscopic processes occurring in an electrochemical system. Notably, until a few years ago, the role of spin was not taken into account in the field of magneto-electrochemistry. Remarkably, recent experimental studies reveal that electron transmission through chiral molecules is spin se…

Two component chiral gels: a study of properties and behavior as recognition systems

Amino acid-­deriving chiral polymers with potential for biotechnological applications

2017

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First observation and study of the K± → π±π0e+e− decay

2018

The NA48/2 experiment at CERN reports the first observation of the K-+/- -> pi(+/-)pi(0)e(+)e(-) decay from an exposure of 1.7 x 10(11) charged kaon decays recorded in 2003-2004. A sample of 4919 candidates with 4.9% background contamination allows the determination of the branching ratio in the full kinematic region, BR(K-+/- -> pi(+/-)pi(0)e(+)e(-)) = (4.24 +/- 0.14) x 10(-6). The study of the kinematic space shows evidence for a structure dependent contribution in agreement with predictions based on chiral perturbation theory. Several P- and CP-violating asymmetries are also evaluated.