Search results for " circular dichroism"
showing 10 items of 134 documents
Magnetic Circular Dichroism in Two-Photon Photoemission
2009
We report the observation of magnetic circular dichroism (MCD) in two-photon photoemission (2PPE). The Heusler alloys Ni2MnGa and Co2FeSi were investigated by excitation with femtosecond laser light, showing MCD asymmetries of A=(3.5+/-0.5)x10;{-3} for Ni2MnGa and of A=(2.1+/-1.0)x10;{-3} for Co2FeSi, respectively. A theoretical explanation is provided based on local spin-density calculations for the magnetic dichroic response; the computed 2PPE MCD agrees well with the experiment. The observed 2PPE magnetic contrast represents an interesting alternative for future time-resolved photoemission studies on surface magnetism practicable in the laboratory.
Unconventional dihydrogen-bond interaction induced cyanide-bridged chiral nano-sized magnetic molecular wheel: synthesis, crystal structure and syste…
2019
A pair of cyanide-bridged 4d–3d heterobimetallic chiral macrocyclic enantiomeric magnetic complexes have been successfully assembled from the trans-dicyanoruthenium(III) building block [PPh4][Ru(Salen)(CN)2] (Salen = N,N-ethylenebis(salicylideneaminato)dianion) and [Mn((S,S/R,R)-Salcy)(H2O)2]ClO4 (Salcy = N,N′-(1,2-cyclohexanediylethylene)bis(salicylideneiminato)dianion) with the great help of the dihydrogen bond (DHB) interaction and characterized by elemental analysis, IR spectroscopy, circular dichroism (CD) and magnetic circular dichroism (MCD) spectroscopy. Single X-ray diffraction reveals that complex 1, {[Ru(Salen)(CN)2][R,R-Mn(Salcy)]}6·PPh3·6CH3CN·6CH3OH·12H2O, is a neutral dodecan…
Separation, isolation and stereochemical assignment of imazalil enantiomers and their quantitation in an in vitro toxicity test
2016
A simple method for the separation of the enantiomers of the fungicide imazalil was developed. Racemic imazalil was separated into its enantiomers with an enantiomeric purity of 99% using HPLC-UV with an enantioselective column (permethylated cyclodextrin) operated in reversed phase mode (water with 0.2% trimethylamine and 0.08% acetic acid and methanol). The absolute configuration of the separated enantiomers was assigned and unequivocally confirmed by optical rotation as well as by vibrational circular dichroism (VCD) and electronic circular dichroism (ECD) combined with ab-initio calculations. The same enantioselective column was also used to develop an HPLC-MS/MS method for the quantifi…
Investigations of Chl a aggregates cross-linked by dioxane in 3-methylpentane
1997
In this work, dioxane-bound aggregates of chlorophyll a are prepared in 3-methylpentane. The properties of the aggregates are studied by using steady-state and time-resolved spectroscopies. The Q -region absorption spectrum of the y chlorophyll a-dioxane aggregate shows four clearly resolvable narrow bands with comparable intensities. The band maxima are located at 683, 689, 698 and 702 nm. The emission spectrum consists of two emission bands centred at 699 and 702 nm suggesting the presence of two types of aggregates. High degree of fluorescence polarization is detected yielding the angles between the absorption transition moments with respect to the 702 nm emission transition moment. The …
Forever Young: Structural Stability of Telomeric Guanine Quadruplexes in the Presence of Oxidative DNA Lesions**
2021
International audience; Human telomeric DNA, in G-quadruplex (G4) conformation, is characterized by a remarkable structural stability that confers it the capacity to resist to oxidative stress producing one or even clustered 8-oxoguanine (8oxoG) lesions. We present a combined experimental/computational investigation, by using circular dichroism in aqueous solutions, cellular immunofluorescence assays and molecular dynamics simulations, that identifies the crucial role of the stability of G4s to oxidative lesions, related also to their biological role as inhibitors of telomerase, an enzyme overexpressed in most cancers associated to oxidative stress.
Half-metallic ferromagnetism with high magnetic moment and high Curie temperature in Co$_2$FeSi
2006
Co$_2$FeSi crystallizes in the ordered L2$_1$ structure as proved by X-ray diffraction and M\"o\ss bauer spectroscopy. The magnetic moment of Co$_2$FeSi was measured to be about $6\mu_B$ at 5K. Magnetic circular dichroism spectra excited by soft X-rays (XMCD) were taken to determine the element specific magnetic moments of Co and Fe. The Curie temperature was measured with different methods to be ($1100\pm20$)K. Co$_2$FeSi was found to be the Heusler compound as well as the half-metallic ferromagnet with the highest magnetic moment and Curie temperature.
Microscopic origin of magnetic anisotropy in martensitic Ni2MnGa
2011
The microscopic origin of magnetic anisotropy in the shape memory alloy Ni${}_{2}$MnGa is investigated by means of x-ray magnetic circular dichroism in transmission mode. Field- and angle-dependent dichroism spectra of epitaxial Ni${}_{2}$MnGa(101)/MgO(001) films reveal pronounced differences for magnetization aligned parallel and perpendicular to the film plane. These differences are related to an anisotropy of the orbital magnetic moment in agreement with the observed out-of-plane magnetocrystalline anisotropy. The spectral variation of the x-ray absorption originates from changes in the spin-projected density of states when the magnetization vector is rotated from the easy to the hard ma…
Properties of Co/sub 2/YZ Heusler compounds
2005
Heusler compounds of Co/sub 2/XY composition (Co/sub 2/Cr/sub 0.6/Fe/sub 0.4/Al, Co/sub 2/FeSi) offer a variety of half-metallic ferromagnetic materials. These were prepared by arc melting and comprehensively characterized by means of X-ray diffraction ( XRD), Mossbauer spectroscopy, magnetic X-ray circular dichroism spectroscopy (MXCD), superconducting quantum interference device (SQUID) magnetometry, electron spectroscopy for chemical analysis (ESCA), extended X-ray absorption fine structure (EXAFS) and Auger electron spectroscopy (AES) depth profiling. Structural disorder phenomena, magnetic hysteresis, magnetic moments, magnetic transition temperatures and Curie temperature were obtaine…
Field dependence of spin and orbital moments of Fe in L10 FePt magnetic thin films
2006
Abstract The field dependence of spin and orbital magnetic moments of Fe in L10 FePt magnetic thin films was investigated using X-ray magnetic circular dichroism (XMCD). The spin and orbital moments were calculated using the sum rules; it was found that the spin and orbital moment of Fe in L10 FePt films are ∼2.5 and 0.2 μB, respectively. The relative XMCD asymmetry at Fe L3 peak on the dependence of applied field suggested that the majority magnetic moment of L10 FePt films resulted from Fe.
Investigation of Elemental Magnetic Moments of CoCrPt Films Using X-Ray Magnetic Circular Dichroism
2006
The elemental magnetic moments of Co and Cr in CoCrPt films were investigated using xray magnetic circular dichroism (XMCD). The spin and orbital moments of Co was calculated using the sum rules; it was found that the magnetic moment of Co in CoCrPt films was dominated by spin moment contribution. The total magnetic moment of Co was found to be lower than that of bulk Co. Further, the Cr moment was aligned anti-ferromagnetically with respect to Co, resulting in a decrease of saturation magnetization (Ms) in CoCrPt films.