Search results for " clusters"
showing 10 items of 1091 documents
Box 5: Surface Crystallography Terminology
2009
The crystalline nature of the surface differs from the bulk because atoms on the surface experience a different force field due to unterminated bonds, oxidation by adatoms etc. [1]. Free energy minimisation leads to reconstruction of the surface layer from the bulk by formation of dimers and displacement of atoms from their normal sites.
Real-space Wigner-Seitz Cells Imaging of Potassium on Graphite via Elastic Atomic Manipulation
2015
Atomic manipulation in the scanning tunnelling microscopy, conventionally a tool to build nanostructures one atom at a time, is here employed to enable the atomic-scale imaging of a model low-dimensional system. Specifically, we use low-temperature STM to investigate an ultra thin film (4 atomic layers) of potassium created by epitaxial growth on a graphite substrate. The STM images display an unexpected honeycomb feature, which corresponds to a real-space visualization of the Wigner-Seitz cells of the close-packed surface K atoms. Density functional simulations indicate that this behaviour arises from the elastic, tip-induced vertical manipulation of potassium atoms during imaging, i.e. el…
Poly[μ2-chloro-μ2-1,4-oxathiane-κ2S:S-copper(I)]
2007
The title complex, [CuCl(C4H8OS)]n, contains infinite spiral (CuS)n chains linked by bridging Cl atoms into layers. The Cl atoms do not form polymeric fragments with CuI, but combine into isolated centrosymmetric Cu2Cl2 units. The compound is non-isomorphous with the Br-containing analogue, which contains Cu8S8 rings linked by Br atoms into chains. The O atom of the 1,4-oxathiane molecule does not realize its coordination abilities in the known copper(I)-halide complexes, while in copper(II)-halide complexes, oxathiane is coordinated via the S and O atoms. This falls into a pattern of the preferred interactions, viz. weak acid (CuI atom) with weak base (S atom) and harder acid (CuII atom)…
"Table 20" of "Energy dependence of event shapes and of alpha(s) at LEP-2."
1999
Distribution of Oblateness at cm energy 183 GeV.
Lamb shift of a uniformly accelerated hydrogen atom in the presence of a conducting plate
2009
We investigate the effects of acceleration on the energy-level shifts of a hydrogen atom interacting with the electromagnetic field and in the presence of an infinite perfectly conducting plate. We consider the contributions of vacuum fluctuations and of the radiation reaction field to the Lamb shift, and we discuss their dependence from the acceleration of the atom. We show that, because of the presence of the boundary, both vacuum field fluctuations and radiation reaction field contributions are affected by atomic acceleration. In particular, the effect of the vacuum field fluctuations on the energy-level shifts is not equivalent to that of a thermal field. We also discuss the dependence …
The limits of the rotating wave approximation in electromagnetic field propagation in a cavity
2005
We consider three two-level atoms inside a one-dimensional cavity, interacting with the electromagnetic field in the rotating wave approximation (RWA), commonly used in the atom-radiation interaction. One of the three atoms is initially excited, and the other two are in their ground state. We numerically calculate the propagation of the field spontaneously emitted by the excited atom and scattered by the second atom, as well as the excitation probability of the second and third atom. The results obtained are analyzed from the point of view of relativistic causality in the atom-field interaction. We show that, when the RWA is used, relativistic causality is obtained only if the integrations …
Causality, non-locality and three-body Casimir–Polder energy between three ground-state atoms
2006
The problem of relativistic causality in the time-dependent three-body Casimir–Polder interaction energy between three atoms, initially in their bare ground-state, is discussed. It is shown that the non-locality of the spatial correlations of the electromagnetic field emitted by the atoms during their dynamical self-dressing may become manifest in the dynamical three-body Casimir–Polder interaction energy between the three atoms.
One-sided atomic deflection in the optical Stern-Gerlach effect and coherent trapping
2002
In the optical Stern-Gerlach effect, the interaction of a traveling two-level atom with the electromagnetic field of an optical cavity causes a splitting of the atomic trajectory. One may ask if it is possible to single out particular initial configurations of the system that will lead to selective scattering, in which the atoms follow only one trajectory. We show that these configurations consist of a coherent superposition of the atomic internal states, and of a field phase state or a field coherent state, with a precise phase relation between the two subsystems: The same configurations which produce the so-called atomic coherent trapping in the Jaynes-Cummings model.
Fragmentation of gold clusters stored in a penning trap
1994
The collision-induced dissociation of positively charged gold clusters (2 to 23 atoms) stored in a Penning trap has been studied. After collisions with rare gases, excited clusters predominantly decay by emission of one or two atoms. The loss of two atoms occurs most likely through the emission of a dimer rather than a sequential evaporation. The minimum kinetic energies of clusters required to induce dissociation exhibit a pronounced odd-even effect. Clusters with an even number of delocalized electrons are more stable than the odd ones.
Blue luminescence in ZnO single crystals, nanopowders, ceramic
2007
The luminescence spectra and luminescence decay processes were studied in a ZnO single crystal, nanopowders and ceramic at liquid helium and room temperature under VUV synchrotron radiation as well as under pulsed laser excitation. The exciton-exciton and exciton-multiphonon processes were compared in different ZnO nanopowders (commercial powder, powders obtained by vaporization-condensation technique) and ceramic. The possibility of luminescence decay time modification by Al3+ doping was shown.