Search results for " complex"

From genome to phenome and back: understanding the high metabolic veratility of Bulkholderia cepacia complex

2014

The Nhlangano gneiss dome in south-west Swaziland – A record of crustal destabilization of the eastern Kaapvaal craton in the Neoarchaean

2015

Abstract The Nhlangano granite-gneiss in south-west Swaziland, dated at 2.98 Ga, forms an elliptical dome of remobilised, migmatitic crust. Strongly deformed supracrustal rocks wrap around or form synformal keels infolded with subdomes of Nhlangano Gneiss and represent Mesoarchaean Pongola Supergroup strata at amphibolite- to granulite-facies metamorphic grade. Amphibolites represent the metamorphosed equivalents of Nsuze Group basalts and andesites on the basis of similar trace element and Nd isotope data. Garnetiferous Mahamba Gneiss, dated at c. 2.96 Ga, represents the metamorphosed equivalents of felsic to intermediate volcanic rocks and minor pelitic interflow sedimentary units of the …

Complex-forming properties of peat humic acids from a raised bog profiles

2013

Abstract Humic substances (HS) belong to the most powerful complex-forming agents, significantly affecting major and trace element speciation in natural environment. Several authors have focused on humic–metal interactions, using differing methods and comparing humic substances on different sources. However, the intrinsic differences among the HS of different origin and the impact of humification degree on the complex formation between humic substances and metals have not received the necessary attention until now. The aim of this study is to determine the Cu(II) complexing capacity and stability constants of Cu(II) complexes of humic acids (HA) isolated from two well-characterized raised b…

Age and isotopic evidence for the origin of the Archæan granitoid intrusives of the Johannesburg Dome, South Africa

1999

Abstract Results of RbSr, PbPb and SmNd whole rock, Rbr biotite and PbPb zircon evaporation analyses are presented for certain granitoid rocks from the Johannesburg Dome. These data indicate that the granodiorite, granite and leucosome from migmatite were emplaced ∼ 3090 Ma ago, were genetically related and were derived primarily from a source between ∼ 3300 and ∼ 3500 Ma old. A portion of the granodiorite and granite might have been derived from a source between ∼ 4000 and ∼ 4300 Ma old. The tonalite was emplaced ∼ 3170 Ma ago and was derived from a source between 3.3 and 3.5 Ga old. RbSr biotite-whole rock ages, ranging between about ∼ 2614 and ∼ 2080 Ma, probably reflect complete r…

Continental extension: From core complexes to rigid block faulting

2005

Extension of overthickened continental crust is commonly characterized by an early core complex stage of extension followed by a later stage of crustal-scale rigid block faulting. These two stages are clearly recognized during the extensional destruction of the Alpine orogen in northeast Corsica, where rigid block faulting overprinting core complex formation eventually led to crustal separation and the formation of a new oceanic backarc basin (the Ligurian Sea). Here we investigate the geodynamic evolution of continental extension by using a novel, fully coupled thermomechanical numerical model of the continental crust. We consider that the dynamic evolution is governed by fault weakening, …

Tectono-Magmatic Evolution, Age and Emplacement of the Agardagh Tes-Chem Ophiolite in Tuva, Central Asia: Crustal Growth by Island arc Accretion

2004

Publisher Summary The Agardagh Tes–Chem ophiolite in Tuva, Central Asia, is part of the Central Asian Mobile Belt which formed during subduction–accretion processes lasting from the early Neoproterozoic to the late Palaeozoic. The Agardagh Tes–Chem ophiolite marks the northwestern border of the Tuva–Mongolian Massif (TMM), which comprises several intrusive and metamorphic complexes. These complexes consist of metatonalites, gneisses, migmatites, amphibolites, marbles, quartzites, low-grade metasedimentary rocks and minor ultramafic lenses, and radiometric ages range between 536 and 464 Ma. Field observations suggest that the southwestern part of the Tes–Chem unit represents the lower to int…

Diorganotin(IV) complexes ofD-galacturonic acid: solid-state and solution-phase structural study

2003

Three diorganotin(IV) complexes of D-galacturonic acid (H2GalA; R = Me, n-Bu, Ph), two of which are new derivatives (R = Me, Ph), have been synthesized and their solid-state and solution-phase investigated by IR, Mossbauer, 1H, 13C and 119Sn NMR spectroscopy. The FTIR data suggest that H2GalA, in the dialkyltin derivatives, behaves as a dianionic ligand, coordinating the tin(IV) atom through an ester-type carboxylate and deprotonated alcoholic hydroxo groups, whereas a bridging carboxylate occurs in the diphenyltin(IV) complex. Octahedral and trigonal bipyramidal local geometries on tin(IV) atoms are proposed for dialkyltin(IV)GalA and diphenyltin(IV)GalA complexes respectively on the basis…

A Germanium Isocyanide Complex Featuring (n → π*) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C-H Bond Activation under Mild Con…

2012

Reaction of the diarylgermylene Ge(ArMe6)2 [ArMe6 = C6H3-2,6-(C6H2-2,4,6-(CH3)3)2] with tert-butyl isocyanide gave the Lewis adduct species (ArMe6)2GeCNBut, in which the isocyanide ligand displays a decreased C–N stretching frequency consistent with an n → π* back-bonding interaction. Density functional theory confirmed that the HOMO is a Ge–C bonding combination between the lone pair of electrons on the germanium atom and the C–N π* orbital of the isocyanide ligand. The complex undergoes facile C–H bond activation to produce a new diarylgermanium hydride/cyanide species and isobutene via heterolytic cleavage of the N–But bond. peerReviewed

CD3 immunohistochemistry is helpful in the diagnosis of giant cell arteritis.

2018

Objective. To evaluate whether CD3 staining performed routinely on temporal artery biopsy specimens might improve the sensitivity of temporal artery biopsy in patients with biopsy-negative GCA. Methods. Two hundred and seventy biopsies were considered for this study, stained with haematoxylin and eosin and with an anti-CD3 antibody. Results. The addition of CD3 staining modified the sensibility and the specificity of the histologic examination in 89.47 and 95.00%, respectively, with a positive and negative predictive values of 97.00 and 79.78%. Conclusion. The addition of CD3 immunostaining to the classic histologic evaluation is accompanied by a significant increase in the sensibility with…

THE COMPLEX, YET SMALL WORLD OF GLOBAL MULTINATIONALS – INSIGHTS ON SOME APPARENT PARADOXES

2013

Globalization, as it is today, shapes a complex, networked world – that embeds all the features (both vantages and liabilities) of a complex adaptive system. Being one of the biggest networks that define this world, the system of international business – characterized by diversity, (nondeterministic) interconnectivity and uncertainty – is also characterized by the small-world syndrome. Global multinationals are the best supporting agents in order to dismantle the apparent paradox of the complex, yet small world (and others like it).