Search results for " conversion"
showing 10 items of 447 documents
High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy
2015
In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca_(2.8)Lu_(0.15)Ag_(0.05)Co_4O_(9+δ) and half-Heusler Ti_(0.3)Zr_(0.35)Hf_(0.35)CoSb_(0.8)Sn_(0.2) alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153 K. At ΔT ≈ 756 K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic l…
Molecular design of the diketopyrrolopyrrole-based dyes with varied donor units for efficient dye-sensitized solar cells
2014
Abstract Three types of novel diketopyrrolopyrrole-based organic dyes ( Type 1 – 3 ) with phenyl unit as an additional π -bridge and triphenylamine or phenothiazine as the donors are designed and synthesized for dye-sensitized solar cells (DSSCs). Type 1 dyes incorporating the donor segment directly to the diketopyrrolopyrrole core lead to a better electron communication between the donor and acceptor, allowing an efficient charge transfer process. Type 2 and Type 3 dyes with a phenyl unit between the donor and diketopyrrolopyrrole unit show lower delocalization of the excited state. Compared with Type 3 dyes, Type 1 dyes exhibit higher conjugated skeleton co planarity and shorter electron …
Highly efficient and stable dye-sensitized solar cells based on SnO2nanocrystals prepared by microwave-assisted synthesis
2012
Highly efficient dye-sensitized solar cells (DSSCs) with excellent long-term stability were fabricated based on tin(IV) oxide (SnO2) nanocrystals with tunable morphologies and band energy levels. The nanocrystals were prepared by a facile, fast, and energy-saving microwave-assisted solvothermal reaction. Through variation of the precursor base used during nanocrystal synthesis control over morphology was achieved—precursor metal cations are known to have a strong influence on the growth process of SnO2 nanostructures. A simple and economic way to prepare semiconducting pastes for photoanodes was devised. The photovoltaic performance of dye-sensitized solar cells based on SnO2 photoanodes wa…
High efficiency single-junction semitransparent perovskite solar cells
2014
Semitransparent perovskite solar cells with a high power conversion efficiency (PCE) above 6% and 30% full device transparency have been achieved by implementing a thin perovskite layer and a simple foil compatible layout.
Efficiency comparison between SiC- and Si-based active neutral-point clamped converters
2015
This paper presents an efficiency comparison between silicon-carbide technology and silicon technology. In order to achieve this, the efficiency of an active neutral-point clamped converter built up with silicon carbide power-devices is compared with the efficiency of an active neutral-point clamped converter built up with silicon power-devices, under a particular operating mode and a particular selection of devices. Firstly, overall losses of both converters are estimated. Then, experimental tests are carried out to measure their overall losses and efficiency. Finally, experimental results are compared with the estimations to support the analysis. The efficiency of the SiC converter is hig…
Optimized blue light generation in optically contacted walk-off compensated RbTiOAsO4 and KTiOP1−yAsyO4
1999
Abstract We study type II 1.32 μm second harmonic generation (SHG) in a RbTiOAsO 4 optically contacted walk-off compensated device. The reduction of the effective walk-off angle by a factor of 3.7 with respect to KTiOPO 4 for the same interaction leads to an enhancement by a factor of 10 of the conversion efficiency. A model is proposed for both type I and type II SHG in such a structure. The angular tuning curve is a multi-peaked one, as predicted by the model. The enhancement of the SHG conversion efficiency allows us to optimize the generation of blue laser light at 440 nm: a specially designed KTiOP 0.98 As 0.02 O 4 solid solution crystal achieves angular non-critical phase matching at …
Parametric conversion in micrometer and sub-micrometer structured ferroelectric crystals by surface poling
2012
We report on recent technological improvements concerning nonlinear patterning of lithium niobate and lithium tantalate in the micrometer and submicrometer scales using surface periodic poling for ferroelectric domain inversion. The fabricated samples were employed for frequency doubling via quasiphase-matching both in bulk and guided wave geometries, including forward and backward configurations and wavelength conversion in bands C and L. We also investigated short-period quasiperiodic samples with randomly distributed mark-to-space ratios.
Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and Mini-modules
2020
The rapid improvement in the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has prompted interest in bringing the technology toward commercialization. Capitalizing on existing industrial processes facilitates the transition from laboratory to production lines. In this work, we prove the scalability of thermally co-evaporated MAPbI3 layers in PSCs and mini-modules. With a combined strategy of active layer engineering, interfacial optimization, surface treatments, and light management, we demonstrate PSCs (0.16 cm2 active area) and mini-modules (21 cm2 active area) achieving record PCEs of 20.28% and 18.13%, respectively. Un-encapsulated PSCs retained ∼90% of their initial…
Isomeric state of 80Y and its role in the rp-process
2003
The HIGISOL facility has been used to investigate carefully the isomeric transition 228.5 keV in 80Y. We have measured the electron internal conversion coefficient for this transition αK = 0.50 ± 0.07 which gives the value for half-life of “bare” isomeric state T 1/2 = 6.8 ± 0.5 s. The isomeric state should play an important role in the rp-process calculations.
Improvement of DSSC performance by voltage stress application
2016
Dye-sensitized solar cells (DSSCs) are promising third generation photovoltaic devices given their potential low cost and high efficiency. Some factors still affect DSSCs performance, such structure of electrodes, electrolyte compositions, nature of the sensitizers, power conversion efficiency, long-term stability, etc. In this work we discuss the effect of electrical stresses, which allow to improve DSSC performance. We have investigated the outcomes of forward and reverse DC bias stress as a function of time, voltage, and illumination level in the DSSCs sensitized with the N719, Ruthenium complex based dye. We demonstrate that all the major solar cell parameters, i.e., open circuit voltag…