6533b86efe1ef96bd12cb2f0

RESEARCH PRODUCT

High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy

Le Thanh HungEugen StamateLi HanMan Hoang VietSøren LinderothG. Jeffrey SnyderBenjamin BalkeNini PrydsNgo Van Nong

subject

Materials scienceRenewable Energy Sustainability and the EnvironmentDopingAlloyEnergy conversion efficiencyMetallurgyAnalytical chemistryEnergy Engineering and Power TechnologyCold sideengineering.materialElectrical contactsCobaltitechemistry.chemical_compoundFuel TechnologyNuclear Energy and EngineeringElectrical resistance and conductancechemistryThermoelectric effectengineering

description

In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca_(2.8)Lu_(0.15)Ag_(0.05)Co_4O_(9+δ) and half-Heusler Ti_(0.3)Zr_(0.35)Hf_(0.35)CoSb_(0.8)Sn_(0.2) alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153 K. At ΔT ≈ 756 K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic losses. The long-term stability investigation for two weeks at the hot and cold side temperatures of 1153/397 K shows that the segmented leg has good durability as a result of stable and low electrical resistance contacts.

https://doi.org/10.1016/j.enconman.2015.03.112