Search results for " coordination"
showing 10 items of 215 documents
Ligands hybrides : synthèse et chimie de coordination
2011
This manuscript deals with the synthesis of hybrids ligands and their coordination ability. The first part is dedicated to Cp-imidazole, Cp-imidazolium and Cp-phosphine ligands. Several synthetic routes have been developed to reach these mixed ligands and their coordination chemistry has been studied with titanium. In a second part, a method developed in our laboratory to synthesize phosphine-olefines was applied to obtain a phosphino-diene bearing three potential coordination sites. We have studied the coordination modes of this hybrid ligand using various transition metals and some of the formed complexes were tested in catalysis. In the third part is described the coordination chemistry …
Pre-requisites of successful strategic electronic coordination : the moderation effect of the ownership mechanism of inter-organisational information…
2017
In this paper, we attempt to explain how the ownership mechanism of an interorganisational information system (IOS) may impact strategic information exchange (electronic coordination) induced by specific investments in the IOS. Recent research and practice show that heavy investments in IOSs demonstrate mixed results with respect to their impact on the electronic coordination. Consequently, the search of additional factors is needed to help and explain under what circumstances the IOS investments for strategic purposes become beneficial for the companies in a buyersupplier dyad. Transaction cost economics (TCE) and the hostage model are used as a framework for the research. 198 observations…
s-Block metal scorpionates – A new sodium hydrido-tris(3,5-dimethyl-1-pyrazolyl)borate salt showing an unusual core stabilized by bridging and termin…
2020
Abstract Dissolution of [(μ-Me2CO)3(NaTp*)2] (1) (Tp* = hydrido-tris(3,5-dimethyl-1-pyrazolyl)borate) in DMSO at room temperature leads to the growth of colourless crystals characterized as the new salt [Na2Tp*(μ-Me2SO)3(Me2SO)3] [NaTp* 2] (2). 2 crystallized in the trigonal space group R3 with Z = 3, a = 14.1227(2) Å, b = 14.1227(10) Å, c = 33.9685(2) Å, and V = 5867.35(17) Å3. Interestingly, anion and cation of 2 both contain the Tp* ligand. Moreover, the cationic moiety highlights an unusual sodium atom hexacoordinated by six DMSO molecules acting as O-bonded ligands. Three of which exhibit a bridging coordination mode and three are in terminal position. To the best of our knowledge, the…
Coordination Polymers
2018
Este documento ha sido elaborado en el marco de un proyecto de Renovación de Metodologías Docentes concedido por el servicio de Formación Permanente de la Universitat de Valencia (UV-SFPIE_RMD17-725369) Este documento forma parte de la asignatura Química Inorgánica Avanzada impartida en el Máster Universitario en Química This document is part of the course Advanced Inorganic Chemistry belonging to the Master in Chemistry
La ratification en trompe-l'il du TSCG en France
2013
International audience
Developmental Coordination Disorder, Historical Beginnings and Development
2015
<p><em>This article contains theoretical analysis about Developmental Coordination Disorder historical evolution. Studies include a wide variation in terminology and criteria to describe . Developmental Coordination Disorder. Developmental Coordination Disorder is a complex neurological condition, which affects muscle coordination and perception.</em></p>
Achieving Fair Bandwidth Distribution in WiFi Networks: A Game Theoretical Approach
2011
International audience; Achieving fair bandwidth distribution among uplink and downlink ows in IEEE 802.11 infrastructure networks is a complex issue, due to the well-known features of the Distributed Coordination Function (DCF) which regulates the access to the shared medium. Indeed, the dynamic adaptation of the contention windows causes phenomena of short-term unfairness, while the use of homogeneous contention parameters among the contending nodes makes the aggregated downlink bandwidth equal to the uplink bandwidth of a single node. We propose a dynamic tuning of the contention parameters used by the nodes, based on simple network monitoring functionalities and rational strategies. Spe…
A Novel Na(I) Coordination Complex with s-Triazine Pincer Ligand: Synthesis, X-ray Structure, Hirshfeld Analysis, and Antimicrobial Activity
2023
The pincer ligand 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (bpmt) was used to synthesize the novel [Na(bpmt)2][AuCl4] complex through the self-assembly method. In this complex, the Na(I) ion is hexa-coordinated with two tridentate N-pincer ligands (bpmt). The two bpmt ligand units are meridionally coordinated to Na(I) via one short Na-N(s-triazine) and two slightly longer Na-N(pyrazole) bonds, resulting in a distorted octahedral geometry around the Na(I) ion. In the coordinated bpmt ligand, the s-triazine core is not found to be coplanar with the two pyrazole moieties. Additionally, the two bpmt units are strongly twisted from one another by 64.94°. Based on Hirshf…
Fluorescent organometallic complexes : when the photovoltaic leads to theranostics
2013
The goal of my PhD thesis was to synthesize new molecules, which give access to fluorescentorganometallic complexes with interesting properties for photovoltaic and theranostic. In thisproject, several main points have been studied.The first part of this manuscript concerns the synthesis of new metallocene and metalloporphyrinsbasedorganometallic complexes to the design of solar cells. After a short introduction, wepresented the synthesis of titanium complexes and metalloporphyrins in the first chapter. Inparticular, we described the synthesis of model compounds and the difficulties encountered duringthe transition to porphyrin derivatives. However, in view of results obtained and opportuni…