Search results for " coupling"
showing 10 items of 724 documents
Adenine and 2-aminopurine: Paradigms of modern theoretical photochemistry
2006
Distinct photophysical behavior of nucleobase adenine and its constitutional isomer, 2-aminopurine, has been studied by using quantum chemical methods, in particular an accurate ab initio multiconfigurational second-order perturbation theory. After light irradiation, the efficient, ultrafast energy dissipation observed for nonfluorescent 9H-adenine is explained here by the nonradiative internal conversion process taking place along a barrierless reaction path from the initially populated 1 (ππ* L a ) excited state toward a low-lying conical intersection (CI) connected with the ground state. In contrast, the strong fluorescence recorded for 2-aminopurine at 4.0 eV with large decay lifetime …
Summary of Week VII
2018
International audience; Week VII of the INT program 2018 “Probing Nucleons and Nuclei in High Energy Collisions” was dedicated to topics at the interface of the electron-ion collider (EIC), heavy ion and proton-nucleus collisions. The EIC will provide complementary tools to investigate and constrain the initial state in HIC collisions, as well as transport properties of QCD matter which can be extracted from observables that are sensitive to final states interactions such as pt-broadening and energy loss. The contributed talks and discussions covered a variety of physics topics from saturation physics and the origin of multi-particle correlations in HIC to jet quenching and the strong coupl…
Reversible Strong Coupling in Silver Nanoparticle Arrays Using Photochromic Molecules
2012
International audience; In this Letter, we demonstrate a reversible strong coupling regime between a dipolar surface plasmon resonance and a molecular excited state. This reversible state is experimentally observed on silver nanoparticle arrays embedded in a polymer film containing photochromic molecules. Extinction measurements reveal a clear Rabi splitting of 294 meV, corresponding to ∼13% of the molecular transition energy. We derived an analytical model to confirm our observations, and we emphasize the importance of spectrally matching the polymer absorption with the plasmonic resonance to observe coupled states. Finally, the reversibility of this coupling is illustrated by cycling the …
The FLO Diffusive 1D-2D Model for Simulation of River Flooding
2016
An integrated 1D-2D model for the solution of the diffusive approximation of the shallow water equations, named FLO, is proposed in the present paper. Governing equations are solved using the MArching in Space and Time (MAST) approach. The 2D floodplain domain is discretized using a triangular mesh, and standard river sections are used for modeling 1D flow inside the section width occurring with low or standard discharges. 1D elements, inside the 1D domain, are quadrilaterals bounded by the trace of two consecutive sections and by the sides connecting their extreme points. The water level is assumed to vary linearly inside each quadrilateral along the flow direction, but to remain constant …
Cross-Frequency Coupling in Developmental Perspective
2019
It is generally assumed that different electroencephalogram (EEG) frequency bands are somehow related to different computational modes in the brain. Integration of these computational modes is reflected in the phenomenon of cross-frequency coupling (CFC). On slow temporal scales, CFC may reflect trait-like properties, which posits a question of its developmental trends. This is the first study that explored source-level CFC measures in a developmental perspective using both cross-sectional and longitudinal designs. CFC measures demonstrated good test-retest stability and proved to be higher in adults in cortical areas participating in sensory-motor integration, response inhibition, and atte…
IEEE Std. 1459 power quantities ratio approaches for simplified harmonic emissions assessment
2018
The paper investigates the suitability of using power ratio parameters for harmonic emissions assessment at the point of common coupling (PCC). The study is carried out starting from the IEEE Std. 1459-2010 apparent power decomposition, where power factors are defined for evaluating line utilization and harmonic pollution levels. In addition, the study investigates the behavior of new parameters, which are expressed in terms of ratio between IEEE Std. 1459-2010 power quantities. The study is carried out for both single-phase and three-phase case, also considering the presence of capacitors. ? 2018 IEEE.
Quantum and classical dynamics of heavy quarks in a quark-gluon plasma
2018
We derive equations for the time evolution of the reduced density matrix of a collection of heavy quarks and antiquarks immersed in a quark gluon plasma. These equations, in their original form, rely on two approximations: the weak coupling between the heavy quarks and the plasma, the fast response of the plasma to the perturbation caused by the heavy quarks. An additional semi-classical approximation is performed. This allows us to recover results previously obtained for the abelian plasma using the influence functional formalism. In the case of QCD, specific features of the color dynamics make the implementation of the semi-classical approximation more involved. We explore two approximate…
Determination of the non-abelian Debye screening mass using classical chromodynamics
2014
Tässä työssä tutkitaan gluonin Debye-massaa, ja sen aika- ja miehityslukudis- tribuutioriippuvuutta käyttäen klassista väridynamiikkaa kahdessa paikkaulot- tuvuudessa. Työssä tutkitaan myös ominaista liikemääräskaalaa ja miehitys- lukudistribuutioita. Gluonin Debye-massa määritetään sovittamalla suora glu- onien dispersiorelaatioon pienellä liikemäärällä. Tuloksia verrataan termisestä kenttäteoriasta johdetun kaavan ennusteisiin. Aluksi tutustutaan raskasionifysiikkaan liittyvään viitekehykseen. Tämän jälkeen kerrataan nopeasti klassinen Yang-Mills teoria jatkumossa ja hilalla. Käydään läpi Fourier kiihdytetty Coulombin mitan kiinnitysmenetelmä yk- sityiskohtaisesti jatkumossa ja hilalla. T…
Thieme Chemistry Journals Awardees – Where Are They Now? Molybdenum(V)-Mediated Synthesis of Nonsymmetric Diaryl and Aryl Alkyl Chalcogenides
2017
Oxidative chalcogenation reaction using molybdenum(V) reagents provides fast access to a wide range of nonsymmetric aryl sulfides and selenides. The established protocol is tolerated by a variety of labile functions, protecting groups, and aromatic heterocycles. In particular, when labile moieties are present, the use of molybdenum(V) reagents provides superior yields compared to other oxidants.
Simulation of Fatigue Delamination Growth in Composites with Different Mode Mixtures
2007
A numerical model, obtained by implementing a cyclic damage model in the framework of an interface element, is here proposed to reproduce the crack growth in laminated composites subjected to cyclically repeated loads. This model, which differs from the few studies in the literature on the topic, applies not only to single fracture modes but also to mixed modes, and to constant or variable crack growth rates. The applied load (in terms of force or displacement) is assumed to oscillate between a minimum and a maximum constant value. The Paris curve can be reproduced with accuracy once some parameters in the numerical model are tuned with experiments. These parameters are preliminarily found…