6533b7d0fe1ef96bd125b95f
RESEARCH PRODUCT
Thieme Chemistry Journals Awardees – Where Are They Now? Molybdenum(V)-Mediated Synthesis of Nonsymmetric Diaryl and Aryl Alkyl Chalcogenides
Sebastian B. BeilPeter WinterscheidSiegfried R. WaldvogelDieter SchollmeyerPeter Franzmannsubject
inorganic chemicalschemistry.chemical_classificationmolybdenum pentachloridedisulfides010405 organic chemistryArylOrganic Chemistrychemistry.chemical_elementMolybdenum pentachloride010402 general chemistryoxidative coupling01 natural sciences0104 chemical scienceschemistry.chemical_compoundchemistryMolybdenumReagentcross-couplingOrganic chemistryOxidative coupling of methaneC–S bond formationAlkyldescription
Oxidative chalcogenation reaction using molybdenum(V) reagents provides fast access to a wide range of nonsymmetric aryl sulfides and selenides. The established protocol is tolerated by a variety of labile functions, protecting groups, and aromatic heterocycles. In particular, when labile moieties are present, the use of molybdenum(V) reagents provides superior yields compared to other oxidants.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-02-02 | Synlett |