Search results for " density of states"
showing 10 items of 31 documents
Characterization of the defect density states in MoOx for c-Si solar cell applications
2021
Thin layers of MoOx have been deposited by thermal evaporation followed by post-deposition annealing. The density of states distributions of the MoOx films were extracted deconvoluting the absorption spectra, measured by a photothermal deflection spectroscopy setup, including the small polaron contribution. Results revealed a sub-band defect distribution centered 1.1 eV below the conduction band; the amplitude of this distribution was found to increase with post-deposition annealing temperature and film thickness.
Sub-gap defect density characterization of molybdenum oxide: An annealing study for solar cell applications
2020
AbstractThe application of molybdenum oxide in the photovoltaic field is gaining traction as this material can be deployed in doping-free heterojunction solar cells in the role of hole selective contact. For modeling-based optimization of such contact, knowledge of the molybdenum oxide defect density of states (DOS) is crucial. In this paper, we report a method to extract the defect density through nondestructive optical measures, including the contribution given by small polaron optical transitions. The presence of defects related to oxygen-vacancy and of polaron is supported by the results of our opto-electrical characterizations along with the evaluation of previous observations. As part…
Disorder-induced vibrational anomalies from crystalline to amorphous solids
2021
The origin of boson peak -- an excess of density of states over Debye's model in glassy solids -- is still under intense debate, among which some theories and experiments suggest that boson peak is related to van-Hove singularity. Here we show that boson peak and van-Hove singularity are well separated identities, by measuring the vibrational density of states of a two-dimensional granular system, where packings are tuned gradually from a crystalline, to polycrystals, and to an amorphous material. We observe a coexistence of well separated boson peak and van-Hove singularities in polycrystals, in which the van-Hove singularities gradually shift to higher frequency values while broadening th…
Structural, electronic, and magnetic properties of pseudomorphic CrFe nanostripes on W(110)
2007
We have grown pseudomorphic binary ${\mathrm{Cr}}_{1\ensuremath{-}x}{\mathrm{Fe}}_{x}$ alloy monolayers and sequences of Cr and Fe nanostripes on W(110) by molecular-beam epitaxy in ultrahigh vacuum. By coadsorption of Cr and Fe a pseudomorphic random CrFe alloy grows on the W(110) substrate. At a substrate temperature of $700\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ the CrFe alloy forms monolayer stripes in the step flow growth mode. We have measured magnetic properties of the monolayer alloy for $0.75\ensuremath{\leqslant}x\ensuremath{\leqslant}1$ using Kerr magnetometry. At a constant relative temperature $t=T∕{T}_{C}$ the saturation value of the Kerr rotation shows a maximum at $x=0.95$ an…
Subwavelength mapping of surface photonic states
2003
We show that the spectral tailoring of optical local density of states (LDOS) may be achieved by lithographically designed nanostructures and that the subwavelength mapping of the spectral variation of the optical LDOS is feasible by varying the driving frequency of the effective dipole used in an illumination mode scanning near-field optical microscope.
The Single Molecule Probe: Nanoscale Vectorial Mapping of Photonic Mode Density in a Metal Nanocavity
2009
International audience; We use superresolution single-molecule polarization and lifetime imaging to probe the local density of states (LDOS) in a metal nanocavity. Determination of the orientation of the molecular transition dipole allows us to retrieve the different LDOS behavior for parallel and perpendicular orientations with respect to the metal interfaces. For the perpendicular orientation, a strong lifetime reduction is observed for distances up to 150 nm from the cavity edge due to coupling to surface plasmon polariton modes in the metal. Contrarily, for the parallel orientation we observe lifetime variations resulting from coupling to characteristic λ/2 cavity modes. Our results are…
Imaging the Local Density of States of Optical Corrals
2002
International audience; This paper reports the experimental observation, at optical frequencies, of the electromagnetic local density of states established by nanostructures corresponding to the recently introduced concept of optical corral [G. Colas des Francs et al., Phys. Rev. Lett. 86, 4950 (2001)]. The images obtained by a scanning near-field optical microscope under specific operational conditions are found in agreement with the theoretical maps of the optical local density of states. A clear functionality of detection by the scanning near-field optical microscope is thereby identified since the theoretical maps are computed without including any specific tip model.
Element-Specific Magnetic and Electronic Properties of Epitaxial Heusler Films
2015
X-ray magnetic circular dichroism (XMCD) provides an experimental access to element-specific electronic properties of thin epitaxial films of Heusler alloys. The combination of bulk-sensitive transmission and surface-sensitive electron yield methods reveals quantitative information on bulk and interface properties. Extreme cases of magnetically dead and life layers at interfaces illustrate the high potential of XMCD. The dependence of XMCD on disorder, structure and composition is discussed as well as dynamic properties investigated by a combination of ferromagnetic resonance and XMCD. Examples are shown where spectroscopic information provided by XMCD is exploited to discuss subtle changes…
Direct interpretation of near-field optical images.
2001
The interpretation of the detection process in near-field optical microscopy is reviewed on the basis of a discussion about the possibility of establishing direct comparisons between experimental images and the solutions of Maxwell equations or the electromagnetic local density of states. On the basis of simple physical arguments, it is expected that the solutions of Maxwell equations should agree with images obtained by collecting mode near-field microscopes, while the electromagnetic local density of states should be considered to provide a practical interpretation of illumination mode near-field microscopes. We review collecting mode near-field microscope images where the conditions to o…
High-frequency vibrational density of states of a disordered solid.
2013
We investigate the high-frequency behavior of the density of vibrational states in three-dimensional elasticity theory with spatially fluctuating elastic moduli. At frequencies well above the mobility edge, instanton solutions yield an exponentially decaying density of states. The instanton solutions describe excitations, which become localized due to the disorder-induced fluctuations, which lower the sound velocity in a finite region compared to its average value. The exponentially decaying density of states (known in electronic systems as the Lifshitz tail) is governed by the statistics of a fluctuating-elasticity landscape, capable of trapping the vibrational excitations.