Search results for " diffusion"
showing 10 items of 521 documents
In vitro Antifungal Activity of Biopolymeric Foam Activated with Carvacrol
2020
Background: Active packaging represents a defining strategy to improve food quality and safety of the packaged foods. This study aimed to evaluate the in vitro ability of commercial biopolymeric foams, namely Mater-Bi (MB), activated with 20% of carvacrol, to develop a completely biodegradable and compostable packaging to inhibit the growth of spoilage and pathogenic yeasts.
 Methods: MB foams, with and without carvacrol, were produced by melt mixing and the foaming process was performed in a laboratory press. The antifungal activity of foams containing carvacrol was tested applying the disk diffusion method. Statistical analysis was done using XLStat software version 7.5.2 for Excel.&…
Le site de Gaillardon à Ménétru-le-Vignoble (Jura) : un établissement de hauteur de l'Antiquité tardive et du haut Moyen Âge
2011
L'étude de l'établissement de Gaillardon à Ménétru-le-Vignoble s'inscrit dans le cadre d'un programme de recherche pluridisciplinaire engagé sur les sites de hauteur de l'Antiquité tardive et du haut Moyen Âge dans le département du Jura. Créé ex nihilo vers le début du ve siècle, ce lieu semble avoir été occupé de manière permanente jusqu'au vie siècle. Les aménagements identifiés à l'intérieur de l'enceinte maçonnée, qui enserre une superficie de 1,5 ha, suggèrent une concentration d'activités artisanales diversifiées. Certaines catégories de mobilier reflètent un niveau de vie aisé d'une partie des occupants ainsi que la présence d'une garnison ou d'une milice armée. Cet établissement pa…
Indigenismo y migracionismo. Aspectos de la neolitización en la fachada oriental de la Península Ibérica
1996
This paper discusses various aspects on the origins of the Neolithic in the Iberian Peninsula. The dual model is proposed as an alternative to the dichotomy of demie (migrationist) and non-demic (indigenist) explanations. The application of this model in eastern Spain offers an opportunity to evaluate its potential to account for diversity in processes associated with the origins of food production and their spatial organisation.
Diffusion of oxygen in nickel: A variable charge molecular dynamics study
2010
Abstract Variable charge molecular dynamics have been performed to study the diffusion mechanisms of oxygen atoms (O) in nickel (Ni) in the temperature range 950 K–1600 K. It is observed that oxygen does not diffuse via jumps of oxygen through interstitial sites but via a vacancy diffusion mechanism. The oxygen diffusivity can be well described by an Arrhenius law over the temperature range considered. The oxygen diffusion coefficient has been analysed and indicates a value of E a = 1.99 eV for the activation energy and D 0 = 39.2 cm 2 s − 1 for the pre-exponential factor. Our numerical results were compared with a compilation of experimental and theoretical studies, and exhibit a good agre…
Dependence of O2 diffusion dynamics on pressure and temperature in silica nanoparticles
2013
An experimental study of the molecular O2 diffusion process in high purity non-porous silica nanoparticles having 50 m2/g BET specific surface and 20 nm average radius was carried out in the temperature range from 127 to 177 °C at O2 pressure in the range from 0.2 to 66 bar. The study was performed by measuring the volume average interstitial O2 concentration by a Raman and photoluminescence technique using a 1,064 nm excitation laser to detect the singlet to triplet emission at 1,272 nm of the molecular oxygen in silica. A dependence of the diffusion kinetics on the O2 absolute pressure, in addition to temperature dependence, was found. The kinetics can be fit by the solution of Fick’s dif…
O2 Diffusion in Amorphous SiO2 Nanoparticles Probed by Outgassing
2012
An experimental study of the O2 diffusion process in nanoparticles of amorphous SiO2 in the temperature range from 98 to 157 °C was carried out by Raman and photoluminescence techniques. We studied O2 diffusion in high purity silica nanoparticles with a mean diameter of 14, 20, and 40 nm detecting the outgassing of molecules trapped during the manufacturing. The kinetics of diffusion is well described for all the investigated nanoparticles by the Fick’s equation proving its applicability to nanoscale systems. The diffusion coefficient features an Arrhenius law temperature dependence in the explored temperature range, and the diffusion coefficient values are in good agreement with extrapolat…
Memory effects and coverage dependence of surface diffusion in a model adsorption system
1999
We study the coverage dependence of surface diffusion coefficients for a strongly interacting adsorption system O/W(110) via Monte Carlo simulations of a lattice-gas model. In particular, we consider the nature and emergence of memory effects as contained in the corresponding correlation factors in tracer and collective diffusion. We show that memory effects can be very pronounced deep inside the ordered phases and in regions close to first and second order phase transition boundaries. Particular attention is paid to the details of the time dependence of memory effects. The memory effect in tracer diffusion is found to decay following a power law after an initial transient period. This beha…
Quasi-elastic Neutron Scattering Investigation of the Hydrogen Surface Self-Diffusion on Polymer Electrolyte Membrane Fuel Cell Catalyst Support
2008
International audience; Quasi-elastic neutron scattering (QENS) measurements have been performed to investigate the surface selfdiffusion of hydrogen molecules. A monolayer of molecular hydrogen was adsorbed on a carbon material commonly used in polymer electrolyte membrane fuel cells, called XC-72. QENS spectra were recorded at the time-of-flight spectrometer IN5 at Institut Laue-Langevin (ILL) in Grenoble at 40, 50, 60, and 70 K. By using the Chudley & Elliott model for jump diffusion, we found the diffusion coefficient at each temperature. The logarithm of the diffusion coefficient was plotted versus the inverse of the temperature to give the coefficient in the Arrhenius equation. From t…
H-2, H-3(+) and the age of molecular clouds and prestellar cores
2012
Measuring the age of molecular clouds and prestellar cores is a difficult task that has not yet been successfully accomplished although the information is of paramount importance to help in understanding and discriminating between different formation scenarios. Most chemical clocks suffer from unknown initial conditions and are therefore difficult to use. We propose a new approach based on a subset of deuterium chemistry that takes place in the gas phase and for which initial conditions are relatively well known. It relies primarily on the conversion of H 3 + into H 2D + to initiate deuterium enrichment of the molecular gas. This conversion is controlled by the ortho/para ratio of H2 that i…
Observed versus simulated mountain waves over Scandinavia – improvement of vertical winds, energy and momentum fluxes by enhanced model resolut…
2017
Abstract. Two mountain wave events, which occurred over northern Scandinavia in December 2013 are analysed by means of airborne observations and global and mesoscale numerical simulations with horizontal mesh sizes of 16, 7.2, 2.4 and 0.8 km. During both events westerly cross-mountain flow induced upward-propagating mountain waves with different wave characteristics due to differing atmospheric background conditions. While wave breaking occurred at altitudes between 25 and 30 km during the first event due to weak stratospheric winds, waves propagated to altitudes above 30 km and interfacial waves formed in the troposphere at a stratospheric intrusion layer during the second event. Global an…