Search results for " electrodes"
showing 10 items of 72 documents
Ultrafast cycling of lead-acid battery with nanostructured Pb and PbO2 electrodes
2013
Water desalination by capacitive electrodialysis: Experiments and modelling
2020
Abstract Electrodialysis-related technologies keep spreading in multiple fields, among which water desalination still plays a major role. A new technology that has not yet been thoroughly investigated is capacitive electrodialysis (CED), which couples the standard ED with capacitive electrodes. CED has a number of advantages such as removal of toxic products and system simplification. Little mention is made of this technology in the literature and, to the best of our knowledge, no modelling works have ever been presented. In this work, the CED process has been studied through experiments and modelling. A CED model is presented for the first time. With a simple calibration based on macroscop…
Soil ionization of earth electrodes under high pulse transient currents
2007
This paper proposes a numerical model of soil ionization phenomena that can occur when earth electrodes are injected by high pulse transient currents. The model is solved by a finite difference time domain numerical scheme. It has been developed from a thorough analysis of the available studies in technical literature about the peculiar physical dynamics of soil ionization phenomena. As already underlined, soil ionization can occur, for example, when the earth electrode has to drain a lightning current into the soil. In this case, the electric field can overcome the electrical strength and conductive plasma paths can locally grow. The dimension of these ionized air channels are strictly dep…
Safety Concerns on Ground Fault Application Transfer Phenomenon in HV Installations
2007
When a fault to ground occurs in HV/MV substations supplied by a combined overhead-cable line, most of the fault current can be transferred and injected into the soil several kilometers far away from the fault location. This phenomenon is called "fault application transfer" and mostly concerns transition stations, where cables are connected to the overhead line. If the transition station is a dead-end steel pole structure, usually accessible to the general public, the local ground electrode could be inadequate to maintain ground potential rise within safety limits. Hence, dangerous touch and step voltages may appear at exposed locations. In the paper results of various computer simulations …
Results of the research on global earthing systems: A contribution to the problem of their identification
2013
The paper presents a study on the factors that can have influence on the rise of a Global Earthing System. The first part of the work deals with: - the definition of proximity, interconnection and quasi-equipotential; - the influence of the presence of HV/MV stations on the dangerous voltages and on the permissible voltage limits; - the dependence of the hazardous condition for persons on the different kind of fault; - the effects on safety of the coexistence of HV, MV and LV systems. In the second part, starting from the discussion on the themes above-mentioned and on the results of the studies, measurement campaigns and simulations on interconnected earthing systems done in the last fifte…
Earthing System's Design in presence of non-uniform soil
2007
The Authors propose a practical approach for facing the problem of the design of the earthing systems in two-layer soils. The approach is based on the calculation of an equivalent resistivity of the non-uniform soil through which the designer can treat this one as it was uniform. The purpose of the Authors is to provide an innovative simple method and some easy-to-use graphs for an easy earthing systems’ design in two-layer soils.
TCO/Ag/TCO transparent electrodes for solar cells application
2014
Among transparent electrodes, transparent conductive oxides (TCO)/metal/TCO structures can achieve optical and electrical performances comparable to, or better than, single TCO layers and very thin metallic films. In this work, we report on thin multilayers based on aluminum zinc oxide (AZO), indium tin oxide (ITO) and Ag deposited by RF magnetron sputtering on soda lime glass at room temperature. The TCO/Ag/TCO structures with thicknesses of about 50/10/50 nm were deposited with all combinations of AZO and ITO as top and bottom layers. While the electrical conductivity is dominated by the Ag intralayer irrespective of the TCO nature, the optical transmissions show a dependence on the natur…
Electronic structure and energy decomposition analyses as a tool to interpret the redox potential ranking of naphtho-, biphenyl- and biphenylenequino…
2016
By calling on modelling approaches we have performed a comparative study on the redox properties of various naphtho-, biphenyl- and biphenylene-quinone isomers. These different compounds exhibit as a whole a redox potential range between 2.09 and 2.90 V vs. Li+/Li. A specific methodology was used to decrypt the interplay among isomerism, aromaticity and antiaromaticity modifications and the stabilization/destabilization effects due to other molecular components on this key electrochemical feature for electrode materials of batteries. In particular, energy decomposition analysis, within the Quantum Theory of Atoms in Molecules, along with the electron and electron spin population changes upo…
Ni-Fe alloy nanostructured electrodes for water splitting in alkaline electrolyser
2021
Abstract In this work, nickel-iron alloy nanostructured electrodes obtained by template electrosynthesis method are investigated for both hydrogen and oxygen evolution reactions. Electrodes consist of nanowire arrays with high surface area that are able to ensures a high electrolytic activity. To obtain different alloy compositions, the concentration of the elements in the deposition baths is appropriately tuned. Results show that the composition of nanowires does not change linearly with the composition of deposition bath but are richer in Fe. Nanostructured electrodes are tested as both cathodes and anodes in 30 wt% KOH aqueous solution, at room temperature to determine the best alloy com…