Search results for " elements"
showing 10 items of 732 documents
Rare‐earth cyclobutadienyl sandwich complexes: Synthesis, structure and dynamic magnetic properties
2018
The potassium cyclobutadienyl [K2{η4‐C4(SiMe3)4}] (1) reacts with MCl3(THF)3.5 (M=Y, Dy) to give the first rare‐earth cyclobutadienyl complexes, that is, the complex anions [M{η4‐C4(SiMe3)4}{η4‐C4(SiMe3)3‐κ‐(CH2SiMe2}]2−, (2M), as their dipotassium salts. The tuck‐in alkyl ligand in 2M is thought to form through deprotonation of the “squarocene” complexes [M{η4‐C4(SiMe3)4}2]− by 1. Complex 2Dy is a single‐molecule magnet, but with prominent quantum tunneling. An anisotropy barrier of 323(22) cm−1 was determined for 2Dy in an applied field of 1 kOe, and magnetic hysteresis loops were observed up to 7 K. nonPeerReviewed
Major and trace elements characterization of atmospheric deposition in volcanic, urban, and industrial areas of Sicily (Italy): preliminary results
2022
The source of chemical elements dissolved in rainwater can be both natural and anthropogenic. A group of trace elements has been recently brought to attention for their possible environmental impacts, the Technology-critical elements (TCEs). The current knowledge about the geochemical cycle of TCEs is still scarce, nevertheless recent studies [e.g. Brugnone et al., 2020] evidenced a contribution from the volcanic activity for some of them (Te, Tl, and REE). Our research aims to produce a geochemical database on major and trace element depositions in different areas of Sicily: a volcanic area (Etna), two urban areas (Palermo, Catania), two industrial areas (Milazzo, Priolo), and a rural moni…
Trace elements in carbonate raw materials being used in cement and lime industry in Opole Province
2009
Patterns and rates of nucleotide substitution, insertion and deletion in the endosymbiont of antsBlochmannia floridanus
2009
Genome reduction is a general process that has been studied in numerous symbiotic bacteria associated with insects. We investigated the last stages of genome degradation in Blochmannia floridanus, a mutualistic bacterial endosymbiont of the ant Camponotus floridanus. We determined the tempo (rates of insertion and deletion) and mode (size and number of insertion-deletion events) of the process in the last 200,000 years by analysing a total of 16 intergenic regions in several strains of this endosymbiont from different ant populations. We provide the first calculation of the reduction rate for noncoding DNA in this endosymbiont (2.2 x 10(-8) lost nucleotides/site/year) and compare it with th…
The determination of trace element concentrations in fly ash samples using ultrasound-assisted digestion followed with inductively coupled plasma opt…
2009
A method of ultrasound-assisted digestion followed by inductively coupled plasma optical emission spectrometry (ICP-OES) used for the determination of trace element (chromium, copper, lead, nickel, vanadium and zinc) concentrations in fly ash samples was developed. All the measurements were performed in robust plasma conditions. Ultrasound-assisted digestion procedures using digestion solutions of aqua regia and hydrofluoric acid (HF) resulted in recovery rates of over 80% for all the analyte elements. Ultrasound-assisted two-step digestion with digestion solutions of 6 mL of HNO₃(Step 1) and 3 mL of HNO₃+ 3 mL of HF (Step 2) resulted in recovery rates of over 92% for all the analyte elemen…
Current Acquaintance on Agronomic Biofortification to Modulate the Yield and Functional Value of Vegetable Crops: A Review
2023
Fresh vegetables and fruits have always been the mainstays of good nutrition as providers of fiber, beneficial phytochemicals (such as vitamins and phenolic compounds), and minerals. Today and in the future, biofortification is a promising strategy to increase the concentration of these compounds. Considering the importance of minerals in human health, the enrichment of fresh produce for consumption has been considered through specific agronomic approaches. This review discusses, in detail, the latest findings on vegetable agronomic biofortification, aimed at increasing the concentration of crucial minerals, such as iron (Fe), zinc (Zn), iodine (I), selenium (Se), molybdenum (Mo), and silic…
Kalcīts un tā veidošanās apstākļi augšējā devona Daugavas svītas dolomītos Latvijas centrālajā un austrumu daļā
2017
Bakalaura darbā “Kalcīts un tā veidošanās apstākļi augšējā devona Daugavas svītas dolomītos Latvijas centrālajā un austrumu daļā” ir raksturotas minerāla kalcīta fizikālās īpašības, mikroelementu saturs un veidošanās apstākļi. Pētījumi veikti 8 dolomīta atradnēs; ģeoloģiskajā griezumā un atradņu teritorijā salīdzinātas kalcīta īpašības. Testētas kalcīta fluorescences izpausmes, pētīti plānslīpējumi, raksturoti kalcītā sastopamie mikroelementi un oglekļa stabilo izotopu attiecības tajā. Secināts, ka kalcīts kristalizējies no atmosfēras ūdeņiem sauszemes apstākļos. Šis minerāls veidojies paleokarsta procesa beigu stadijā pēc iegruvumu izveidošanās. Atslēgas vārdi: mineraloģija, paleokarsts, f…
Active biomonitoring (moss-bags) of volcanic emissions on Mt. Etna
2011
Biomonitoring may be defined as the use of organisms and biomaterials (biomonitors) to obtain information on certain characteristics of a particular medium (atmosphere, hydrosphere etc.). In particular, mosses accumulate large amounts of trace metals, making them good bioaccumulators to estimate atmospheric pollution. The moss-bags technique, introduced in the early 1970’, has become very popular. Such active biomonitoring technique is particularly useful in highly polluted areas and has been extensively used in industrial and/or urban areas to examine deposition patterns and to recognize point sources of pollution. The main objective of this study, which represents the first application of…
Drāmas elementu izmantošana jaunāko pusaudžu motivācijas veicināšanai angļu valodas gramatikas apgūšanā
2020
Šis diplomdarbs sniedz teorētisku pamatojumu un piedāvā praktiskus padomus drāmas tehnikas izmantošanai angļu valodas stundās pamatskolā. Uzsvars tika likts uz gramatikas kompetences attīstību. Pētījuma mērķis bija noskaidrot, vai ir iespējama drāmas elementu izmantošana pamatskolas angļu valodas stundās un noskaidrot vai tā attīsta izglītojamo gramatikas kompetenci. Prakses laikā tika veikta izpēte, izmantojot gadījuma pētījumu, kā galveno pētījumu metodi. Darbā tika izmantotas tādas datu vākšanas metodes kā novērojumi, anketas un gala testa analīze. Rezultāti pierādīja, ka drāmas paņēmienus var piemērot nodarbībām ar jaunākiem pusaudžiem, kuri studē angļu valodu, arī tika parādīts, ka tā …
Indirect chronology method employing rare earth elements to identify Sagunto Castle mortar construction periods
2017
A novel indirect chronology method has been developed to identify Sagunto Castle construction periods. The method is based on the use of inductively coupled plasma mass spectrometry (ICP-MS) to determine rare earth elements (REE) and other trace elements in mortars. Additionally, a no destructive geochemical analysis based on X-ray fluorescence (XRF) was employed for major elements determination. Collected chemical data were processed through Principal Component Analysis (PCA) to highlight any differences among the mortars belonging to different buildings and construction periods. The results show that PCA analysis permits to discriminate construction periods according to mortar sample REE …