Search results for " fluxes"
showing 9 items of 49 documents
Relationships between metabolic fluxes and enzyme amino acid composition
2013
AbstractMetabolic fluxes are a key parameter of metabolic pathways being closely related to the kinetic properties of enzymes and could be conditional on their sequence characteristics. This study examines possible relationships between the metabolic fluxes and the amino acid (AA) composition (AAC) for enzymes from the yeast Saccharomyces cerevisiae glycolysis pathway. Metabolic fluxes were quantified by the COPASI tool using the kinetic models of Hynne and Teusink at 25 mM, 50 mM, and 100 mM of external glucose or employing literature data for cognate kinetic or stoichiometric models. The enzyme sequences were taken from the UniProtKB, and the AAC computed by the ExPASy/ProtParam tool. Mul…
Monitoring water and carbon fluxes at fine spatial scales using HyspIRI-like measurements
2012
Remotely sensed observations in the visible to the shortwave infrared (VSWIR) and thermal infrared (TIR) regions of the electromagnetic spectrum can be used synergistically to provide valuable products of land surface properties for reliable assessments of carbon and water fluxes. The high spatial, spectral and temporal resolution VSWIR and TIR observations provided by the proposed Hyperspectral - InfraRed (HyspIRI) mission will enable a new era of global agricultural monitoring, critical for addressing growing issues of food insecurity. To enable predictions at fine spatial resolution (<100m), modeling efforts must rely on a combination of high-frequency temporal and highresolution spa…
Volcanic Gas Emissions Along the Colombian Arc Segment of the Northern Volcanic Zone (CAS-NVZ): Implications for volcano monitoring and volatile budg…
2019
Studying spatial and temporal trends in volcanic gas compositions and fluxes is crucial both to volcano monitoring and to constrain the origin and recycling efficiency of volatiles at active convergent margins. New volcanic gas compositions and volatile fluxes are here reported for Nevado del Ruiz, Galeras, and Purace, three of the most persistently degassing volcanoes located in the Colombian Arc Segment of the Northern Volcanic Zone. At Nevado del Ruiz, from 2014 to 2017, plume emissions showed an average molar CO2/S-T ratio of 3.9 +/- 1.6 (S-T is total sulfur, S). Contemporary, fumarolic chemistry at Galeras progressively shifted toward low-temperature, S-depleted fumarolic gas discharge…
Measurements of volcanic SO2 and CO2 fluxes by combined DOAS, Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes
2014
Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO2 emissions. However, measurements of CO2 emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO2 emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO2 emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO2/SO2 ratios of exc…
Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy
2014
Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…
Statistical upscaling of ecosystem CO2 fluxes across the terrestrial tundra and boreal domain: Regional patterns and uncertainties
2021
The regional variability in tundra and boreal carbon dioxide (CO2) fluxes can be high, complicating efforts to quantify sink-source patterns across the entire region. Statistical models are increasingly used to predict (i.e., upscale) CO2 fluxes across large spatial domains, but the reliability of different modeling techniques, each with different specifications and assumptions, has not been assessed in detail. Here, we compile eddy covariance and chamber measurements of annual and growing season CO2 fluxes of gross primary productivity (GPP), ecosystem respiration (ER), and net ecosystem exchange (NEE) during 1990–2015 from 148 terrestrial high-latitude (i.e., tundra and boreal) sites to a…
Influence of land cover in the atmospheric water vapor content and the generation of summer storms in the Turia River Basin
2022
Les tronades d'estiu representen una font d’aigua important en la conca mediterrània, ja que aporten aigua durant els mesos més secs de l’any, amb la qual cosa ajuden a mantenir els cabdals dels principals rius. Aquests sistemes convectius estan associats a les circulacions de brisa que dominen durant l'estiu. La brisa es canalitza a través de les valls assolint les capçaleres dels principals rius on es generen línies de convergència, és a dir, zones on les masses d’aire superficials s’injecten a capes més altes de l’atmosfera i donen lloc a aquest tipus de fenòmens meteorològics. A part de la topografia, altres factors que poden influenciar la formació de tronades d'estiu són els fluxos su…
Simulació de fluxos de carboni terrestres mitjançant teledetecció i modelització d'ecosistemes
2018
The main goal of this thesis is the establishment of a framework to analyze the Spanish forest ecosystems in terms of their role in the carbon cycle. In particular, the carbon fluxes that they exchange with atmosphere are modeled to evaluate their potential as carbon sinks and biomass reservoirs. Gross fluxes are estimated by a production efficiency model relying on the Monteith’s approach. The emphasis is put in characterizing the water stress effects on the light use efficiency and, eventually, on the GPP. Six alternatives are evaluated. Among them, the ones using the ratio between the MODIS actual and potential evapotranspiration, and the soil moisture from SMOS demonstrate that it is po…
Chemistry and fluxes of major and trace element from worldwide passive degassing volcanoes: a critical review
2015
Volcanic emissions represent one of the most important natural sources of trace elements (e.g. As, Cd, Cu, Hg, Pb, Sb, Tl and Zn) into the atmosphere, sequentially influencing the hydrosphere, lithosphere and biosphere. The human health hazard during episodic volcanic eruptions generally follows from deposition of coarse and fine particles (2.5-10 and < 2.5 μm) that produces effects such as asthma and lung and respiratory disease. Regarding passive degassing volcanoes, the harmful effects of fluorine fumigation are known both for vegetation (foliar necrosis) and human/animals (fluorosis), but only a few studies have been focused on the effects of potentially toxic trace elements. From a …