Search results for " gases"

showing 10 items of 941 documents

A Rapid and Sensitive Strip-Based Quick Test for Nerve Agents Tabun, Sarin, and Soman Using BODIPY-Modified Silica Materials

2016

Test strips that in combination with a portable fluorescence reader or digital camera can rapidly and selectively detect chemical warfare agents (CWAs) such as Tabun (GA), Sarin (GB), and Soman (GD) and their simulants in the gas phase have been developed. The strips contain spots of a hybrid indicator material consisting of a fluorescent BODIPY indicator covalently anchored into the channels of mesoporous SBA silica microparticles. The fluorescence quenching response allows the sensitive detection of CWAs in the mu g m(-3) range in a few seconds.

Boron CompoundsSarinSilicon dioxideSomanAnalytical chemistrynerve gases010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundSomanQUIMICA ANALITICAmedicineChemical Warfare AgentsTabunNerve agenthybrid sensor materialsChromatography010405 organic chemistryOrganic ChemistryQUIMICA INORGANICAGeneral ChemistrySilicon DioxideFluorescenceSarinOrganophosphates0104 chemical scienceschemistrychemical warfare agentstest strip analysisProthrombin TimefluorescenceBODIPYMesoporous materialNerve Agentsmedicine.drug
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Driven Bose-Hubbard Model with a Parametrically Modulated Harmonic Trap

2016

We investigate a one-dimensional Bose–Hubbard model in a parametrically driven global harmonic trap. The delicate interplay of both the local interaction of the atoms in the lattice and the driving of the global trap allows us to control the dynamical stability of the trapped quantum many-body state. The impact of the atomic interaction on the dynamical stability of the driven quantum many-body state is revealed in the regime of weak interaction by analyzing a discretized Gross–Pitaevskii equation within a Gaussian variational ansatz, yielding a Mathieu equation for the condensate width. The parametric resonance condition is shown to be modified by the atom interaction strength. In particul…

Bose–Hubbard modelquantum many-body systemsFOS: Physical sciencesHarmonic (mathematics)02 engineering and technologyBose–Hubbard modelWeak interaction01 natural sciencessymbols.namesakeQuantum mechanics0103 physical sciencesAtomquantum gas010306 general physicsQuantumAnsatzPhysicsCondensed Matter::Quantum Gasesta114021001 nanoscience & nanotechnologyMathieu functionQuantum Gases (cond-mat.quant-gas)symbolsParametric oscillator0210 nano-technologyCondensed Matter - Quantum Gasesharmonic trap
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Probing the bond order wave phase transitions of the ionic Hubbard model by superlattice modulation spectroscopy

2017

An exotic phase, the bond order wave, characterized by the spontaneous dimerization of the hopping, has been predicted to exist sandwiched between the band and Mott insulators in systems described by the ionic Hubbard model. Despite growing theoretical evidences, this phase still evades experimental detection. Given the recent realization of the ionic Hubbard model in ultracold atomic gases, we propose here to detect the bond order wave using superlattice modulation spectroscopy. We demonstrate, with the help of time-dependent density-matrix renormalization group and bosonization, that this spectroscopic approach reveals characteristics of both the Ising and Kosterlitz-Thouless transitions …

BosonizationHubbard model[PHYS.COND.GAS]Physics [physics]/Condensed Matter [cond-mat]/Quantum Gases [cond-mat.quant-gas]SuperlatticeGeneral Physics and AstronomyIonic bondingFOS: Physical sciences01 natural sciencesCondensed Matter - Strongly Correlated ElectronsPhysics and Astronomy (all)0103 physical sciencesBosonizationCold atoms010306 general physicsPhysicsCondensed Matter::Quantum GasesCondensed matter physicsDensity Matrix Renormalization GroupStrongly Correlated Electrons (cond-mat.str-el)010308 nuclear & particles physicsMott insulatorBerezinskii-Kosterlitz-Thouless transitionIsing transitionRenormalization groupBond orderQuantum Gases (cond-mat.quant-gas)Ising modelCondensed Matter::Strongly Correlated ElectronsCondensed Matter - Quantum Gases
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Accessing finite momentum excitations of the one-dimensional Bose-Hubbard model using superlattice modulation spectroscopy

2018

We investigate the response to superlattice modulation of a bosonic quantum gas confined to arrays of tubes emulating the one-dimensional Bose-Hubbard model. We demonstrate, using both time-dependent density matrix renormalization group and linear response theory, that such a superlattice modulation gives access to the excitation spectrum of the Bose-Hubbard model at finite momenta. Deep in the Mott-insulator, the response is characterized by a narrow energy absorption peak at a frequency approximately corresponding to the onsite interaction strength between bosons. This spectroscopic technique thus allows for an accurate measurement of the effective value of the interaction strength. On th…

BosonizationPhysicsCondensed Matter::Quantum GasesCondensed matter physics[PHYS.COND.GAS]Physics [physics]/Condensed Matter [cond-mat]/Quantum Gases [cond-mat.quant-gas]Density matrix renormalization groupMott insulatorSuperlatticeFOS: Physical sciencesBose–Hubbard model01 natural sciencesAtomic and Molecular Physics and Optics010305 fluids & plasmasSuperfluidityBose-Hubbard modelQuantum Gases (cond-mat.quant-gas)Atomic and Molecular PhysicsDMRG0103 physical sciencesBosonizationand Optics010306 general physicsCondensed Matter - Quantum GasesFrequency modulationBoson
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Correlation Dynamics During a Slow Interaction Quench in a One-Dimensional Bose Gas

2014

We investigate the response of a one-dimensional Bose gas to a slow increase of its interaction strength. We focus on the rich dynamics of equal-time single-particle correlations treating the Lieb-Liniger model within a bosonization approach and the Bose-Hubbard model using the time-dependent density-matrix renormalization group method. For short distances, correlations follow a power-law with distance with an exponent given by the adiabatic approximation. In contrast, for long distances, correlations decay algebraically with an exponent understood within the sudden quench approximation. This long distance regime is separated from an intermediate distance one by a generalized Lieb-Robinson …

BosonizationPhysicsCondensed Matter::Quantum GasesLieb-Robinson boundBose gas[PHYS.COND.GAS]Physics [physics]/Condensed Matter [cond-mat]/Quantum Gases [cond-mat.quant-gas]General Physics and AstronomyFOS: Physical sciencesTomonaga-Luttinger LiquidRenormalization groupPower lawExponential functionAdiabatic theoremequal-time Green's functionsQuantum Gases (cond-mat.quant-gas)Light coneQuantum mechanicsinteraction quenchExponentCondensed Matter - Quantum GasesPACS: 67.85.−d 03.75.Kk 03.75.Lm 67.25.D−
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Topological Devil's staircase in atomic two-leg ladders

2019

Abstract We show that a hierarchy of topological phases in one dimension—a topological Devil’s staircase—can emerge at fractional filling fractions in interacting systems, whose single-particle band structure describes a topological or a crystalline topological insulator. Focusing on a specific example in the BDI class, we present a field-theoretical argument based on bosonization that indicates how the system, as a function of the filling fraction, hosts a series of density waves. Subsequently, based on a numerical investigation of the low-lying energy spectrum, Wilczek–Zee phases, and entanglement spectra, we show that they are symmetry protected topological phases. In sharp contrast to t…

Bosonizationcold-atoms; fractional topological phase; strongly correlated; two-leg ladderGeneral Physics and AstronomyFOS: Physical sciencesQuantum entanglementcold-atomTopology01 natural sciencesSettore FIS/03 - Fisica della Materia010305 fluids & plasmasUltracold atom0103 physical sciencesddc:530Limit (mathematics)010306 general physicsElectronic band structurePhysicsstrongly correlatedSeries (mathematics)Symmetry (physics)cold-atomsQuantum Gases (cond-mat.quant-gas)Topological insulatorfractional topological phaseCondensed Matter - Quantum Gasestwo-leg ladder
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Potential models for the simulation of methane adsorption on graphene: development and CCSD(T) benchmarks

2018

Different force fields for the graphene–CH4 system are proposed including pseudo-atom and full atomistic models. Furthermore, different charge schemes are tested to evaluate the electrostatic interaction for the CH4 dimer. The interaction parameters are optimized by fitting to interaction energies at the DFT level, which were themselves benchmarked against CCSD(T) calculations. The potentials obtained with both the pseudo-atom and full atomistic approaches describe accurately enough the average interaction in the methane dimer as well as in the graphene–methane system. Moreover, the atom–atom potentials also correctly provide the energies associated with different orientations of the molecu…

CCSD calculationsPotential modelsUNESCO::QUÍMICADimerGeneral Physics and AstronomyThermodynamics02 engineering and technology010402 general chemistry:QUÍMICA [UNESCO]7. Clean energy01 natural sciencesStability (probability)MethaneCCSD calculations Potential models methane adsorptionlaw.inventionchemistry.chemical_compoundlawPhysics::Atomic and Molecular ClustersMoleculePhysics::Chemical PhysicsPhysical and Theoretical ChemistryBond energymethane adsorptionCondensed Matter::Quantum GasesPhysicsGrapheneCharge (physics)Interaction energy021001 nanoscience & nanotechnology0104 chemical scienceschemistry0210 nano-technologyPhysical Chemistry Chemical Physics
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An overview of the geochemical characteristics of oceanic carbonatites: New insights from Fuerteventura carbonatites (Canary islands)

2021

The occurrence of carbonatites in oceanic settings is very rare if compared with their continental counterpart, having been reported only in Cape Verde and Canary Islands. This paper provides an overview of the main geochemical characteristics of oceanic carbonatites, around which many debates still exist regarding their petrogenesis. We present new data on trace elements in minerals and whole-rock, together with the first noble gases isotopic study (He, Ne, Ar) in apatite, calcite, and clinopyroxene from Fuerteventura carbonatites (Canary Islands). Trace elements show a similar trend as Cape Verde carbonatites, almost tracing the same patterns on multi-element and REE abundance diagrams. 3…

CalciteCape Verdelcsh:Mineralogylcsh:QE351-399.2010504 meteorology & atmospheric sciencesCape Verde Fuerteventura Noble gases isotopes Oceanic carbonatites Trace elementsnoble gases isotopesGeochemistrytrace elementsGeology010502 geochemistry & geophysicsGeotechnical Engineering and Engineering Geology01 natural sciencesLithospheric mantleMantle (geology)Cape verdeFuerteventurachemistry.chemical_compoundchemistryCarbonatiteoceanic carbonatitesGeology0105 earth and related environmental sciencesPetrogenesis
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The role of trapped fluids during the development and deformation of a carbonate/shale intra-wedge tectonic mélange (Mt. Massico, Southern Apennines,…

2020

Abstract Numerous studies exist on exhumed tectonic melanges along subduction channels whereas, in accretionary wedge interiors, deformation mechanisms and related fluid circulation in tectonic melanges are still underexplored. We combine structural and microstructural observations with geochemical (stable and clumped isotopes and isotope composition of noble gases in fluid inclusions of calcite veins) and U-Pb geochronological data to define deformation mechanisms and syn-tectonic fluid circulation within the Mt. Massico intra-wedge tectonic melange, located in the inner part of the central-southern Apennines accretionary wedge, Italy. This melange developed by shear deformation at the bas…

CalciteDécollementAccretionary wedge010504 meteorology & atmospheric sciencesSubductionStable and clumped isotopestable and clumped isotopesGeochemistryGeologyCrustMélange010502 geochemistry & geophysicsOverprinting01 natural sciencesFold and thrust beltTectonic mélangechemistry.chemical_compoundNoble gasechemistrytectonic mélange; fluid-rock interaction; stable and clumped isotopes; noble gases; fold and thrust beltnoble gasesFluid inclusionsFluid-rock interactionGeology0105 earth and related environmental sciences
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Recycled crustal carbon in the depleted mantle source of El Hierro volcano, Canary Islands

2021

The Canary Islands, in the eastern Atlantic, are among the most enigmatic Oceanic Island provinces on Earth, as the mantle source feeding its volcanism exhibits wide spatial heterogeneity and a multiplicity of sources. Multi-isotope whole-rock studies have long revealed the presence of a recycled oceanic crust/lithosphere component in the mantle source. However, noble gas systematics have been more challenging to interpret, and the available carbon isotope data is limited and cannot support/dismiss this interpretation. Here, we present the very first isotopic characterisation of CO2 and noble gases (He-Ne-Ar) in fluid inclusions (FI) in minerals hosted in mantle xenoliths from El Hierro, th…

Canary Islands El Hierro Fluid inclusions Mantle xenoliths Noble gases Recycled carbongeographygeography.geographical_feature_categoryEl HierroGeochemistryGeologyVolcanismCanary IslandFluid inclusionMantle xenolithMantle (geology)Noble gaseRecycled carbonVolcanoGeochemistry and PetrologyOceanic crustLithosphereArchipelagoFluid inclusionsXenolithGeologyLithos
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