Search results for " hydrogen"

Photocatalytic solar light H2 production by aqueous glucose reforming

2018

A series of tungsten and nitrogen doped Pt-TiO2 samples were prepared with the aim to extend the TiO2 absorption to the visible light region and to enhance the separation efficiency of the photogenerated electron/hole pairs. The physicochemical features of the powders were characterized by Xray diffraction (XRD), UV/Vis reflectance spectra, specific surface area (SSA) determinations, and transmission electron microscopy (TEM) analyses. The influence of the presence of different doping agents was evaluated, under anaerobic conditions, in the aqueous photo-reforming of glucose to form H2 at ambient pressure and temperature under a halogen lamp or natural solar light irradiation. Arabinose, er…

Photocatalytic Performance of Brookite in Hydrogen Production by Photo-Steam Reforming

2010

TiO2-CeO2 based catalysts for photocatalytic oxidation of VOC and water splitting reactions

2016

Photocatalysis with TiO2 is one of the most promising green process for the decomposition of organic pollutants and the hydrogen production . Photo-oxidation of 2-propanol, representative of volatile organic compounds (VOC) and photo-catalytic water splitting for H2 production were investigated over TiO2 catalysts doped with a metal (Au and Ag at 1wt. %) and/or ceria (10 wt.%).

Post UV irradiation annealing of E’ centers in silica controlled by H2 diffusion

2004

Abstract We investigate the isothermal annealing of E′ centers generated by UV photons (266 nm) of a pulsed Nd:YAG laser in two natural silica types differing for their OH content. Electron spin resonance and absorption spectra recorded at room temperature at different delays from the laser exposure evidenced a partial reduction of E′ centers, more pronounced in the wet silica. These post irradiation kinetics complete within 10 5 s, regardless the silica type, and they are consistent with a diffusion limited reaction between the E′ centers and the molecular hydrogen H 2 . Analysis of our data is done by theoretical fits using the Waite's equation and compared with the H 2 diffusion paramete…

Synthesis of C2-Symmetrical Bis-(β-Enamino-Pyran-2,4-dione) Derivative Linked via 1,6-Hexylene Spacer: X-ray Crystal Structures, Hishfeld Studies and…

2021

The synthesis of C2-symmetrical bis(β-enamino-pyran-2,4-dione) derivative 3 connected via 1,6-hexylene linker was reported for the first time. X-ray structures and Hirshfeld studies of the new bis- β-enamino-pyran-2,4-dione derivative 3 along with two structurally related pyran-2,4-dione derivatives 2a,b were discussed. A comparative analysis of the different intermolecular contacts affecting the crystal stability was presented. Generally, the H…H, O…H, and H…C interactions are common in all compounds and are considered the most abundant contacts. In addition, DFT calculations were used to compute the electronic properties as well as the 1H and 13C NMR spectra of the studied systems. All co…

Excitation levels and magic numbers of small parahydrogen clusters (N⩽40)

2008

The excitation energies of parahydrogen clusters have been systematically calculated by the diffusion Monte Carlo technique in steps of one molecule from 3 to 40 molecules. These clusters possess a very rich spectra, with angular momentum excitations arriving up to L=13 for the heavier ones. No regular pattern can be guessed in terms of the angular momenta and the size of the cluster. Clusters with N=13 and 36 are characterized by a peak in the chemical potential and a large energy gap of the first excited level, which indicate the magical character of these clusters. From the calculated excitation energies the partition function has been obtained, thus allowing for an estimate of thermal e…

Experimental evidence of E × B plasma rotation in a 2.45 GHz hydrogen discharge

2015

An experimental observation of a rotating plasma structure in a 2.45 GHz microwave-driven hydrogen discharge is reported. The rotation is presumably produced by E × B drift. The formation of the rotating plasma structure is sensitive to the strength of the off-resonance static magnetic field. The rotation frequency is on the order of 10 kHz and is affected by the neutral gas pressure and applied microwave power.

Constant-adiabaticity ultralow magnetic field manipulations of parahydrogen-induced polarization: application to an AA'X spin system

2021

The field of magnetic resonance imaging with hyperpolarized contrast agents is rapidly expanding, and parahydrogen-induced polarization (PHIP) is emerging as an inexpensive and easy-to-implement method for generating the required hyperpolarized biomolecules. Hydrogenative PHIP delivers hyperpolarized proton spin order to a substrate via chemical addition of H2 in the spin-singlet state, but it is typically necessary to transfer the proton polarization to a heteronucleus (usually 13C) which has a longer spin lifetime. Adiabatic ultralow magnetic field manipulations can be used to induce the polarization transfer, but this is necessarily a slow process, which is undesirable since the spins co…

Non-perturbative chiral approach to S-wave interactions

1998

The s-wave meson-nucleon interaction in the $S = -1$ sector is studied by means of coupled-channel Lippmann Schwinger equations, using the lowest order chiral Lagrangian and a cut off to regularize the loop integrals. The method reproduces succesfully the $\Lambda (1405)$ resonance and the $K^- p \to K^- p, \bar{K}^0 n, \pi^0 \Lambda, \pi^0 \Sigma, \pi^+ \Sigma^-, \pi^- \Sigma^+$ cross sections at low energies. The inclusion of the $\eta \Lambda, \eta \Sigma^0$ channels in the coupled system is found very important and allows a solution in terms of only the lowest order Lagrangian.

Lithium isotopes beyond the drip line

2008

The unbound isotopes 10Li, 12Li and 13Li have been observed after nucleon-knockout reactions at relativistic energies with 11Li and 14Be beams impinging on a liquid hydrogen target. The channels , and were analysed in the ALADIN-LAND setup at GSI. The 10Li data confirm earlier findings, while the 12Li and 13Li nuclei were observed for the first time. The relative-energy spectrum shows that the ground state of 12Li can be described as a virtual s-state with a scattering length of -13.7(1.6) fm. A broad energy spectrum was found for the channel. Based on the assumption that the relative-energy spectrum is dominated by a correlated background presumably stemming from initial correlations in th…