Search results for " hydrogen"

showing 10 items of 319 documents

A high power liquid hydrogen target for the Mainz A4 parity violation experiment

2005

We present a new powerful liquid hydrogen target developed for the precise study of parity violating electron scattering on hydrogen and deuterium. This target has been designed to have minimal target density fluctuations under the heat load of a 20$\mu$A CW 854.3 MeV electron beam without rastering the electron beam. The target cell has a wide aperture for scattered electrons and is axially symmetric around the beam axis. The construction is optimized to intensify heat exchange by a transverse turbulent mixing in the hydrogen stream, which is directed along the electron beam. The target is constructed as a closed loop circulating system cooled by a helium refrigerator. It is operated by a …

PhysicsNuclear and High Energy PhysicsNatural convectionHydrogenFOS: Physical scienceschemistry.chemical_elementElectronHelium-3 refrigeratorchemistryHeat transferCathode rayPhysics::Accelerator PhysicsNuclear Experiment (nucl-ex)Atomic physicsNuclear ExperimentInstrumentationLiquid hydrogenBeam (structure)Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
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The atomic cascade of kaonic and pionic hydrogen

1990

Abstract The X-ray intensities of kaonic and pionic hydrogen atoms are calculated as functions of the hydrogen density and are compared to experimental data. Data on kaonic hydrogen are statistically not very significant, the comparison with the cascade results allows to test their intrinsic consistency. X-ray intensities from pionic hydrogen agree reasonably with the results of the cascade model.

PhysicsNuclear physicsHydrogen densityNuclear and High Energy PhysicsHydrogenchemistryCascadeKaonic hydrogenNuclear Theorychemistry.chemical_elementPhysics::Atomic PhysicsAtomic physicsNuclear ExperimentPhysics Letters B
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Predictions for the ${\vec{\Lambda }_b \rightarrow J/\psi ~ \Lambda (1405)}$ Λ b → J / ψ Λ ( 1405 ) decay

2015

We calculate the shape of the [Formula: see text] and [Formula: see text] invariant mass distributions in the [Formula: see text] and [Formula: see text] decays that are dominated by the [Formula: see text] resonance. The weak interaction part is the same for both processes and the hadronization into the different meson-baryon channels in the final state is given by symmetry arguments. The most important feature is the implementation of the meson-baryon final-state interaction using two chiral unitary models from different theoretical groups. Both approaches give a good description of antikaon-nucleon scattering data, the complex energy shift in kaonic hydrogen and the line shapes of [Formu…

PhysicsParticle physicsPhysics and Astronomy (miscellaneous)MesonUnitarityKaonic hydrogenQuark modelHigh Energy Physics::PhenomenologyNuclear TheoryElementary particleWeak interaction7. Clean energyHadronizationTheoretical physicsInvariant massHigh Energy Physics::Experimentddc:530Nuclear ExperimentEngineering (miscellaneous)
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A diffusion Monte Carlo study of small para-Hydrogen clusters

2007

Abstract An improved Monte Carlo diffusion model is used to calculate the ground state energies and chemical potentials of parahydrogen clusters of three to forty molecules, using two different p-H2-p-H2 interactions. The improvement is due to three-body correlations in the importance sampling, to the time step adjustment and to a better estimation of statistical errors. In contrast to path-integral Monte Carlo results, this method predicts no magic clusters other than that with thirteen molecules.

PhysicsPhysicsQC1-999FOS: Physical sciencesGeneral Physics and AstronomyFísica36.40.-cTime stepSpin isomers of hydrogenMolecular physicsmolecular clusterspara-hydrogen clusters67.40.db61.46.bcCluster (physics)Physics::Atomic and Molecular ClustersMoleculeDiffusion Monte CarloPhysics - Atomic and Molecular ClustersAtomic and Molecular Clusters (physics.atm-clus)Ground stateImportance samplingPath integral Monte Carlo
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Electro-generation of H2O2 and abatement of organic pollutant in water by an electro-Fenton process in a microfluidic reactor

2013

The electro-generation of H2O2 and the abatement of the model organic pollutant Acid Orange 7 (AO7) in water by an electro-Fenton process were performed both in a conventional undivided macro cell and, for the first time, in a microfluidic reactor. Under optimized operative conditions, the reduction of oxygen in the microdevice gave rise, using graphite cathode, to a concentration of H2O2 of about 6 mM, one order of magnitude higher than that achieved in conventional cells. Similarly, when electro-Fenton was performed in the microfluidic reactor a dramatic increase of the abatement of COD was achieved with respect to that obtained in a conventional cell. Keywords: Wastewater treatments, Mic…

PollutantChemistryMicrofluidicschemistry.chemical_elementWastewater treatments Micro reactor Hydrogen peroxide Electro-Fenton Acid orange 7Settore ING-IND/27 - Chimica Industriale E TecnologicaOxygenCathodelaw.inventionlcsh:Chemistrychemistry.chemical_compoundlcsh:Industrial electrochemistrylcsh:QD1-999Chemical engineeringlawEnvironmental chemistryElectrochemistryGraphiteMicroreactorHydrogen peroxideOrder of magnitudelcsh:TP250-261Electrochemistry Communications
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Novel conception materials based on polymeric Matrix for H2 storage

2012

Polymer functionalization Chemical-physical characterisation Hydrogen storage measurements
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Hydrogen Production from Methanol-Water Solution and Pure Water Electrolysis Using Nanocomposite Perfluorinated Sulfocationic Membranes Modified by P…

2022

In this work, we report the preparation of Nafion membranes containing two different nanocomposite MF-4SC membranes, modified with polyaniline (PANI) by the casting method through two different polyaniline infiltration procedures. These membranes were evaluated as a polymer electrolyte membrane for water electrolysis. Operating conditions were optimized in terms of current density, stability, and methanol concentration. A study was made on the effects on the cell performance of various parameters, such as methanol concentration, water, and cell voltage. The energy required for pure water electrolysis was analyzed at different temperatures for the different membranes. Our experiments showed …

Polymers and PlasticsGeneral ChemistryQuímicawater electrolysis; methanol electrolysis; perfluorinated sulfocationic membranes; polyaniline; PEMWE; hydrogen productionQuímica orgànicaPolymers
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A Comparative Study of Poly(Azure A) Film-Modified Disposable Electrodes for Electrocatalytic Oxidation of H₂O₂: Effect of Doping Anion.

2018

In the present paper, poly(azure A) (PAA) films were electrosynthetized in the presence of different doping anions on disposable screen-printed carbon electrodes (SPCEs). The anions used included inorganic monoatomic (chloride and fluoride), inorganic polyatomic (nitrate and sulfate) and organic polyatomic (dodecyl sulfate, DS) species. The coated electrodes thus obtained were characterized by electrochemical techniques and SEM. They showed improved electrocatalytic activities towards hydrogen peroxide oxidation compared to that of a bare SPCE. In particular, the insertion of DS anions inside PAA films provided a special sensitivity to the electrocatalysis of H2O2, which endowed these elect…

Polymers and PlasticsInorganic chemistryelectrochemical sensorhydrogen peroxideAzure A02 engineering and technologyOverpotential010402 general chemistryElectrocatalystElectrochemistrypoly(azure A)01 natural sciencesChlorideArticlelcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistrymedicinedisposable screen-printed electrodesconducting polymersConductive polymerChemistryconducting polymers; poly(azure A); sodium dodecyl sulfate; electrochemical sensor; disposable screen-printed electrodes; hydrogen peroxidePolyatomic ionGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesElectrochemical gas sensorsodium dodecyl sulfate0210 nano-technologymedicine.drugPolymers
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Electrodeposited nickel–zinc alloy nanostructured electrodes for alkaline electrolyzer

2022

Abstract Over the last decade, as a consequence of the global decarbonization process, the interest towards green hydrogen production has drastically increased. In particular a substantial research effort has focused on the efficient and affordable production of carbon-free hydrogen production processes. In this context, the development of more efficient electrolyzers with low-cost electrode/electrocatalyst materials can play a key role. This work, investigates the fabrication of electrodes of nickel-zinc alloys with nanowires morphology cathode for alkaline electrolyzers. Electrodes are obtained by the simple method of template electrosynthesis that is also inexpensive and easily scalable.…

Potassium hydroxideMaterials scienceRenewable Energy Sustainability and the EnvironmentAlkaline water electrolysisNanowireEnergy Engineering and Power TechnologyOverpotentialCondensed Matter PhysicsElectrosynthesisElectrocatalystElectrochemistrychemistry.chemical_compoundSettore ING-IND/23 - Chimica Fisica ApplicataFuel TechnologyAlkaline electrolyzer Hydrogen evolution reaction Nanostructured electrodes Nanowires Nickel–zinc alloy Template electrosynthesischemistryChemical engineeringSettore ING-IND/17 - Impianti Industriali MeccaniciHydrogen productionInternational Journal of Hydrogen Energy
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Conformational investigation of alpha,beta-dehydropeptides. VIII. N-acetyl-alpha,beta-dehydroamino acid N'-methylamides: conformation and electron de…

2009

The Fourier transform infrared spectra are analyzed in the regions of Vs(N-H), amide I, amide II and Vs(C alpha = C beta) bands for a series of Ac-delta Xaa-NHMe, where delta Xaa = delta Ala, (Z)-delta Abu, (Z)-delta Leu, (Z)-delta Phe and delta Val, to determine the predominant solution conformation of these alpha,beta-dehydropeptide-related molecules and the electron distribution perturbation in their amide bonds. The measurements were performed in dichloromethane (DCM). To confirm and rationalize the assignments, the spectra of the respective series of saturated Ac-Xaa-NHMe, recorded in DCM, and the spectra of these two series of unsaturated and saturated compounds, recorded in acetonitr…

Protein ConformationαAb initioElectronsBiochemistrychemistry.chemical_compoundEndocrinologyDehydroalanineComputational chemistryAb initio quantum chemistry methodsamidic resonanceAmideSpectroscopy Fourier Transform InfraredMoleculePeptide bondC5 hydrogen bondC5 conformationFourier transform infrared spectroscopyamide bond lengthβ‐dehydroamino acidsHydrogen bondab initio calculationsdehydroalanineAmidesMolecular WeightCrystallographyFTIR spectroscopychemistryPeptidesΔ‐electron conjugationThe journal of peptide research : official journal of the American Peptide Society
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