Search results for " interfaces"
showing 10 items of 1158 documents
Photoemission study of the reactivity of barium towards SiOx thermal films
2011
Abstract Barium was deposited at room temperature on a thermal silicon oxide layer and the interfacial reaction was monitored by synchrotron induced photoemission (both core level and valence band). The first step of the growth consists of an interfacial reaction which leads to the formation of an interfacial silicate layer. The next step consists in formation of barium oxide while metallic barium occurs subsequently. The deposit can be also homogenized by annealing above 575 K. This results in the formation of several layers of silicate by consumption of silicon oxide. In the case of fractional coverage, subsequent annealing at 975 K induces the decomposition of barium silicate. However, s…
Highly textured Gd2Zr2O7 films grown on textured Ni-5at.%W substrates by solution deposition route: Growth, texture evolution, and microstructure dep…
2012
Abstract Growth, texture evolution and microstructure dependency of solution derived Gd 2 Zr 2 O 7 films deposited on textured Ni-5 at.%W substrates have been extensively studied. Influence of processing parameters, in particular annealing temperature and dwell time, as well as thickness effect on film texture and morphology are investigated in details. It is found that a rotated cube-on-cube epitaxy of Gd 2 Zr 2 O 7 //NiW in-plane texture forms as soon as the (004) out-plane texture appears, implying that epitaxial growth dominates the crystallization processes. Thermal energy plays an important role in minimizing the difference of interfacial energy along two directions in the anisotropic…
Low-temperature atomic layer deposition of ZnO thin films: Control of crystallinity and orientation
2011
Abstract Low-temperature atomic layer deposition (ALD) processes are intensely looked for to extend the usability of the technique to applications where sensitive substrates such as polymers or biological materials need to be coated by high-quality thin films. A preferred film orientation, on the other hand, is often required to enhance the desired film properties. Here we demonstrate that smooth, crystalline ZnO thin films can be deposited from diethylzinc and water by ALD even at room temperature. The depositions were carried out on Si(100) substrates in the temperature range from 23 to 140 °C. Highly c-axis-oriented films were realized at temperatures below ~ 80 °C. The film crystallinit…
Positron Microscopy Studies of Wear Tracks on a Copper Surface
2014
Positron microscopy was used for studies of defects induced by ball indentation or sliding on the surface of well-annealed copper samples. A focused positron beam of 24.5-keV energy was used to scan the deformed region of the indenter impression, and measurements of the annihilation line parameter were performed. In the case of ball indentation, the measured defect distribution correlates well with the von Mises stress distribution of the Hertz contact and the von Mises yield criterion. For the wear track produced by pin on disc dry sliding, an asymmetric defect distribution near the wear track is observed. It indicates the presence of a tangential force that additionally deforms the sample.
Luminescence of Eu ion in alumina prepared by plasma electrolytic oxidation
2015
Abstract Eu ion luminescence in aluminium oxide nanocrystals and layers prepared by plasma electrolytic oxidation (PEO) are investigated in this study. The Eu ion in PEO coatings has intense luminescence allowing such material to be used for preparation of various phosphor materials. In this study, Eu ion doped coatings were prepared with two methods: anodization and pulsed bipolar plasma electrolytic oxidation. Also, for comparative studies, alumina nanocrystals with the same amount of Eu ions were prepared using Sol Gel and molten salts methods. Obtained Eu-doped coatings were studied using luminescence methods. Typical Eu ion luminescence bands were observed, however intensity and spectr…
Characterizing the Glassy Phase of a Statistical Copolymer Monolayer
1999
Monolayers of a statistical copolymer with a poly(methacrylate) chain and hydrophilic and hydrophobic side groups are investigated at the air/water interface. The isotherms suggest a fluid and a frozen phase. With in-situ X-ray reflectivity the monolayer thickness is determined to be 2.5 nm or less. The shear viscosity in the fluid phase is extremely high yet can be described in the framework of the free area model. However, the parameter which characterizes the overlap of holes available for a diffusing monomer unit is a factor of 2 higher than expected, suggesting local diffusion barriers formed by nanosized clusters. In the glassy phase single-molecule fluorescence shows anomalous diffus…
Prediction and analysis of high velocity oxy fuel (HVOF) sprayed coating using artificial neural network
2019
Abstract Thermal spray comprises a group of coating processes for coating manufacturing in which metallic or nonmetallic materials are deposited in a molten or semi-molten condition. Most often, the coating properties are significantly influenced by the operating parameters. However, obtaining a comprehensive modeling or analytical analysis of the thermal spray process is too difficult to be practical due to the complex chemical and thermodynamic reactions. Accordingly, the present study aims at applying an artificial neural network (ANN) model to predict the HVOF sprayed Cr3C2−25NiCr coatings and analyze the influence of operating parameters regardless of the intermediate process. The proce…
Quantification of Plasma Sprayed Coating Adhesion Using Pulsed Laser Induced Decohesion Technique
2001
Abstract The aim of the present study is to compare a laser ultrasonic technique with a conventional indentation test for the determination of intrinsic properties and the adhesion of alumina coatings, of different thicknesses (30–350 µm), deposited on stainless steel substrates by atmospheric plasma spraying (APS). For this purpose, a pulsed Nd:YAG laser is used to irradiate the coated specimens, and the ultrasonic waves generated by the laser are recorded at the epicenter using a laser interferometer. In the thermoelastic regime, the good agreement between the experiment and computation allows determination of the longitudinal wave velocity as well as the Young's modulus of the oxide coat…
Preparation and properties of radio-frequency-sputtered half-Heusler films for use in solar cells
2011
Abstract The class of half-Heusler compounds opens possibilities to find alternatives for II–VI or III–V compound semiconductors. We aim to find suitable substitutes for the cadmium sulphide buffer layer in chalcopyrite-based thin film solar cells, where the buffer layer is located between the p-type chalcopyrite absorber and an n-type transparent window layer. We report here the preparation of radio-frequency-sputtered lithium copper sulphide “LiCuS” and lithium zinc phosphide “LiZnP” films. The optical analysis of these films revealed band gaps between 1.8 and 2.5 eV, respectively. Chemical properties of the film surface and both interfaces between the film and a Cu ( In , Ga ) Se 2 layer…
Geometry, electronic structure, morphology, and photoluminescence emissions of BaW1-xMoxO4 (x = 0, 0.25, 0.50, 0.75, and 1) solid solutions: Theory a…
2019
Abstract The design of a solid solution with tunable electro-optical properties and multifunctionality is a promising strategy for developing novel materials. In this work, BaW1-xMoxO4 (x = 0, 0.25, 0.5, 0.75, and 1) solid solutions have been successfully prepared for the first time by a co-precipitation method. Their crystal structure and phase composition were determined by X-ray diffraction and Rietveld refinements. Fourier transform infrared and micro Raman spectroscopy in combination with field-emission scanning electron microscopy (FE-SEM) were used to describe the microstructures and chemical compositions of the synthesized materials. The influence of chemical composition on morpholo…