Search results for " interfaces"
showing 10 items of 1158 documents
Surface versus bulk composition of a phosphate glass
1994
Transmission and conversion electron Mossbauer spectroscopy as well as photoelectron spectroscopy were applied to study alterations of the surface layer of an iron containing industrial phosphate glass as compared with its bulk. In the surface layer, after polishing and exposure to ambient atmosphere, Fe 2+ is partially oxidized to Fe 3+ . This oxidation, however, does not increase the O/P ratio in this layer, because it goes along with a strong leaching of network modifiers. This leaching leads to a net decrease of the O/P ratio because it overcompensates the relative oxygen increase by Fe 2+ oxidation and by uptake of water
Electronic structure of adsorbed organic molecules
1997
We report on investigations of chiral organic molecules in the gas phase and physisorbed on graphite. The measurements were carried out by means of angle-resolving VUV photoelectron spectroscopy. The emission from specific orbitals in oriented molecules can be forbidden because of dipole selection rules. Due to the lack of certain features in the spectra, it was possible to determine the adsorption geometry of cyclohexanone and camphor as being with their ring system parallel to the surface. By comparison of gas-phase and adsorbate spectra of ethyl benzene derivatives, adsorption could be proved to be molecular without decomposition. For amino acids on graphite, the occurrence of characteri…
Low-temperature molecular layer deposition using monifunctional aromatic precursors and ozone-based ring-opening reactions
2017
Molecular layer deposition (MLD) is an increasingly used deposition technique for producing thin coatings consisting of purely organic or hybrid inorganic-organic materials. When organic materials are prepared, low deposition temperatures are often required to avoid decomposition, thus causing problems with low vapor pressure precursors. Monofunctional compounds have higher vapor pressures than traditional bi- or trifunctional MLD precursors, but do not offer the required functional groups for continuing the MLD growth in subsequent deposition cycles. In this study, we have used high vapor pressure monofunctional aromatic precursors in combination with ozone-triggered ring-opening reactions…
Thiopeptide-Supported Lipid Layers on Solid Substrates
1997
The sequential layer-by-layer formation of peptide-supported bimolecular lipid membranes at solid supports is described. In the first step, thiol-derivatized peptide sequences of 5 and 7 amino acids are assembled on a Au substrate. After activation of their COOH-terminus phospholipid molecules (DMPE) are covalently attached via an amid bond to form a tethered monolayer on the Au electrode. The different preparation steps are analyzed by Fourier transform IR, X-ray reflectometry, and surface plasmon spectroscopy. The latter technique is then also used to on-line monitor at the solid/solution interface the formation of a bilayer by fusion of vesicles prepared from a fluid lipid mixture with a…
OpenMolcas: From Source Code to Insight
2019
In this article we describe the OpenMolcas environment and invite the computational chemistry community to collaborate. The open-source project already includes a large number of new developments realized during the transition from the commercial MOLCAS product to the open-source platform. The paper initially describes the technical details of the new software development platform. This is followed by brief presentations of many new methods, implementations, and features of the OpenMolcas program suite. These developments include novel wave function methods such as stochastic complete active space self-consistent field, density matrix renormalization group (DMRG) methods, and hybrid multico…
Halloysite nanotubes-based nanocomposites for the hydrophobization of hydraulic mortar
2021
Abstract The treatment of stone surfaces for their protection from ageing caused by natural and anthropogenic effects is an open issue in materials development for Cultural Heritage. We thought interesting to verify the suitability of a modified cellulose biofilm filled with halloysite nanotubes as wax compatibilizers to design a protecting layer. A hydraulic mortar was selected as a stone prototype. To improve the physico-chemical properties of the covering layer, wax microparticles have been incorporated to control transport, consolidation and wettability features. In particular, different application protocols have been studied, namely brushing and spraying, to assess whether the propos…
Impact of very low crop residues cover on wind erosion in the Sahel
2011
International audience; In the Sahel, with average annual precipitation in the order of 500 mm yr− 1, wind erosion occurs mainly on cultivated millet fields whose surfaces are only partially covered by crop residues. The impact of these residues on wind erosion was not clearly established. The objective of this study is thus to quantify the actual amount of crop residues in traditional Sahelian fields and to determine their impacts on wind erosion by reference to a bare surface throughout the seasonal cycle over several years. At the beginning of the year during dry season, Sahelian farmers use to "clean" their fields, i.e. cut and lay flat on the soil surface any millet stalks still standi…
Probing Protein−Membrane Interactions Using Solid Supported Membranes
2011
International audience; Tethered bilayer lipid membranes have been used as a model system to mimic the interactions between the whey protein β-lactoglobulin and a lipid interface. The approach allowed for a detailed study of the lipid-protein interactions, the results being of possible importance in food and cosmetic applications. For such applications, lipid-protein interactions and the interfacial behavior are vital factors in controlling and manipulating process conditions such as emulsion stabilization and gelification. Lipid composition as well as the structural properties of the protein governed their interactions, which were probed by a combination of surface plasmon spectroscopy, ne…
Hyaluronan alkyl derivatives-based electrospun membranes for potential guided bone regeneration: Fabrication, characterization and in vitro osteoindu…
2020
Item does not contain fulltext The aim of the work was to determine the effects of the chemical functionalization of hyaluronic acid (HA) with pendant aliphatic tails at different lengths and free amino groups in terms of chemical reactivity, degradation rate, drug-eluting features, and surface properties when processed as electrospun membranes (EM) evaluating the osteoinductive potential for a possible application as guided bone regeneration (GBR). To this end, a series of HA derivatives with different aliphatic tails (DD-Cx mol% ≈ 12.0 mol%) and decreasing derivatization of free amino groups (DD(EDA) mol% from 70.0 to 30.0 mol%) were first synthesized, namely Hn. Then dexamethasone-loaded…
WiSHFUL : enabling coordination solutions for managing heterogeneous wireless networks
2017
The paradigm shift toward the Internet of Things results in an increasing number of wireless applications being deployed. Since many of these applications contend for the same physical medium (i.e., the unlicensed ISM bands), there is a clear need for beyond-state-of-the-art solutions that coordinate medium access across heterogeneous wireless networks. Such solutions demand fine-grained control of each device and technology, which currently requires a substantial amount of effort given that the control APIs are different on each hardware platform, technology, and operating system. In this article an open architecture is proposed that overcomes this hurdle by providing unified programming i…