Search results for " ionic liquid"
showing 10 items of 88 documents
Microscopic structural and dynamic features in triphilic room temperature ionic liquids
2019
Here we report a thorough investigation of the microscopic and mesoscopic structural organization in a series of triphilic fluorinated room temperature ionic liquids, namely [1-alkyl, 3-methylimidazolium][(trifluoromethanesulfonyl)(nonafluorobutylsulfonyl)imide], with alkyl=ethyl, butyl, octyl ([C(n)mim][IM14], n = 2, 4, 8), based on the synergic exploitation of X-ray and Neutron Scattering and Molecular Dynamics simulations. This study reveals the strong complementarity between X-ray/neutron scattering in detecting the complex segregated morphology in these systems at mesoscopic spatial scales. The use of MD simulations delivering a very good agreement with experimental data allows us to g…
Emerging Evidences of Mesoscopic-Scale Complexity in Neat Ionic Liquids and Their Mixtures
2017
Ionic liquids (ILs) represent a blooming class of continuously developing advanced materials, with the aiming of a green chemical industry. Their appealing physical and chemical properties are largely influenced by their micro- and mesoscopic structure that is known to possess a high degree of hierarchical organization. High-impact application fields are largely affected by the complex morphology of neat ionic liquids and their mixtures. This Perspective highlights new arising research directions that point to an enhanced level of structural complexity in several IL-based systems, including mixtures. The latter represent a change in paradigm in the approach to formulate new, task-specific I…
Pressure-responsive mesoscopic structures in room temperature ionic liquids
2015
Among the most spectacular peculiarities of room temperature ionic liquids, their mesoscopically segregated structural organization keeps on attracting attention, due to its major consequences for the bulk macroscopic properties. Herein we use molecular dynamics simulations to explore the nm-scale architecture in 1-octyl-3-methylimidazolium tetrafluoroborate, as a function of pressure. This study reveals an intriguing new feature: the mesoscopic segregation in ionic liquids is characterized by a high level of pressure-responsiveness, which progressively vanishes upon application of high enough pressure. These results are in agreement with recent X-ray scattering data and are interpreted in …
Natural eutectogels: sustainable catalytic systems for C–C bond formation reactions
2021
Natural eutecto gels were prepared combining properties of amino acids with the ones of deep eutectic solvents. Soft materials obtained were fully characterised determining the gel-sol transition temperatures and analysing mechanical and morphological features through rheological measurements and polarised optical microscopy. All eutecto gels were tested as catalytic reaction media for the enantioselective aldol reaction and, the best performing one was also used to carry out the Michael addition. In both cases, eutecto gels proved to have a great potential as sustainable reaction media, allowing to perform processes under mild conditions, obtaining excellent yields and, in some cases, also…
SINTESI E PROPRIETÁ DI SALI ORGANICI POLICATIONICI UTILIZZATI COME MEZZI DI REAZIONE
High crystallinity polyethylene obtained in biphasic polymerization using pyridinium chloroaluminate ionic liquid
2014
A series of N-n-alkylpyridinium chloroaluminate ionic liquids [C n -py][AlCl4] (where n-alkyl = n-butyl, n-hexyl, and n-octyl) was applied as a medium of the Cp2TiCl2 catalyst, activated by AlEtCl2 or AlEt2Cl, to evaluate the influence of the studied ionic liquids on the performance of the biphasic ionic liquid/hexane ethylene polymerization and the properties of the produced polyethylene (PE). The best results were obtained using N-n-butylpyridinium chloroaluminate. The polyethylene obtained in the biphasic polymerization have the high crystallinity, which was confirmed by DSC, WAXS and PALS methods, as well as the bulk density comparable to commercial HDPE. These unique properties results…
Ionic tactile sensors as promising biomaterials for artificial skin: Review of latest advances and future perspectives
2021
Abstract Ionic tactile sensors (ITS) are an emerging subfield of wearable electronics, capable of mimicking the human skin, including not only the typical anisotropic structure, mechanical behaviour, and tactile functions but even the mechanosensitive ionic channels that are crucial for the human sense of touch. With the rapid development of intelligent technology, such bioinspired materials constitute the core foundation of intelligent systems and are a candidate to be the next generation e-skins, offering a more accurate and evolved biointerface. In the latest years, a wealth of novel ultra-stretchable ITS was proposed, progressively refining the choice of soft materials, including ion ge…
Oxidized graphene in ionic liquids for assembling chemically modified electrodes: a structural and electrochemical characterization study
2012
Dispersions of graphene oxide (GO) nanoribbons in ionic liquids, ILs (either 1-butyl-3-methylimidazolium chloride (BMIM-Cl-) or 1-butylpyridinium chloride (-Bupy-Cl-)) have been used to assemble modified screen printed electrodes (SPEs). The graphene oxide/ionic liquid dispersions have been morphologically and structurally characterized by the use of several techniques: X-ray photoelectron spectroscopy (XPS), Fourier transform-infrared (FT-IR) spectroscopy, high-resolution-transmission electron microscopy (HR-TEM). The assembled modified SPEs have then been challenged with various compounds and compared to several electro-active targets. In all cases high peak currents were detected, as wel…