Search results for " liquid crystal"
showing 10 items of 100 documents
ASSESMENT OF TEMPERATURE POLARIZATION IN MEMBRANE DISTILLATION CHANNELS BY LIQUID CRYSTAL THERMOGRAPHY
2014
AbstractThe measurement of local temperature distributions within a membrane distillation (MD) channel is a crucial step for the optimization of the channel and spacer geometry. This information allows the estimation of temperature polarization phenomena, which can dramatically influence the thermal efficiency of the process and the optimal choice of the geometric configuration (net spacer features, channel size, etc.). In the present work, a recently presented experimental technique, based on the use of thermochromic liquid crystals and digital image analysis, has been employed in order to assess the temperature polarization phenomena. The local heat transfer coefficient distribution on th…
Transient photoconductivity in a discotic hexagonal plastic crystal
1996
Discotic Liquid Crystals - A New Class of Fast Photoconductors
1993
We showed for the first time that discotic liquid crystals are well suited for a new class of fast photoconducting materials. Due to their spontaneous orientation and their dynamical fluctuations in the mesophase, they show exceptionally high mobilities of 1·10−3 cm2/Vs, about two to three orders of magnitude higher than those obtained for conventional amorphous polymers. Further on, the Gaussian transport (for holes in the mesophase) is remarkable, which is characterized by the existence of a conduction band and the absence of trapping states. In contrast, the charge carrier transport in amorphous photoconductors is generally trap-dominated which limits technical properties, leading to low…
Experimental investigation of two-side heat transfer in spacer-filled channels
2020
Abstract In Membrane Distillation (MD), spacers support the membranes and promote mixing, thus reducing temperature polarization. Their efficient design requires a knowledge of the distribution of the local heat transfer coefficient h and of its dependence on Reynolds number, spacer geometry and flow-spacer relative orientation. In previous work, we applied Thermochromic Liquid Crystals (TLC) and digital image processing to the measurement of h distributions for different spacer configurations; data were used to validate CFD simulations and select turbulence models. For constructive reasons, the test section allowed only one-side heat transfer, while in most MD configurations (e.g. spiral-w…
Triphenanthro‐anellierte [18]Annulene mit Alkoxy‐Seitenketten — Eine neue Klasse discotischer Flüssigkristalle
1994
Triphenanthro-Anellated [18]Annulenes with Alkoxy Side Chains - A Novel Class of Discotic Liquid Crystals Two different types 6 and 16 of [18]annulenes condensed with phenanthrene systems were prepared by cyclocondensation reactions (Schemes 2 and 3). The central 18-membered rings do not show a macrocyclic diamagnetic ring current. Conformational analyses and X-ray analyses in the solid state reveal non-planar structures in which aromatic “islands” are connected by (E)-configurated olefinic bridges. The introduction of long alkoxy side chains yields a new class of discotic liquid crystals; either ND or hexagonal columnar phases are generated, which were characterized by DSC, microscopy with…
Di- and Tricationic Organic Salts: an Overview of Their Properties and Applications
2014
During recent years growing interest has been devoted to the synthesis and applications of polycationic organic salts. Among them, di- and tricationic organic salts can be considered the natural evolution of monocationic ones. These last have given rise to the large class of ionic liquids. In the cases of di- and tricationic organic salts, the potential to change their structural features simply by varying the properties either of the charged heads or of the spacers separating them provides the opportunity to obtain materials suitable for different applications. This review article highlights recent progress in the study of the properties of di- and tricationic organic salts, as well as in …
Ionic liquid crystals based on 3-perfluoalkyl-1,2,4-triazol-4-ium salts
2016
Liquid-crystalline ionic liquids (LC-ILs) are a class of organic materials that of great current interest: they are defined as organic salts that possess the properties of two interesting kinds of material – ionic liquids (ILs) and liquid crystals (LCs). LC-ILs combine many interesting features of ILs (e.g. low volatility and the ability to dissolve solutes with a range of polarities) as well as many attractive properties of LCs (e.g. their intrinsic order and anisotropy). This provides unique opportunities that can be exploited in many different fields, for example their use as solvents for extraction processes as well as electrolytes for batteries, fuel cells, and dye-sensitised solar cel…
Oxadiazolyl-pyridinium based organic salts
2011
Modes of Structure Formation in Doped Discotic Polymers and Low Molar Mass Model Systems
1991
By doping low molar mass or polymeric liquid crystals containing flat disc-like units with electron acceptors one achieves a stabilization of columnar phases, the induction of a columnar phases in otherwise discotic nematic or even in amorphous systems. Theoretical models based on the assumption of strong electron donator-acceptor (EDA) complex formation are able to account for the structure formation on a molecular level and the thermodynamic properties of the mixtures and the model of diffusion limited aggregation (DLA) for the structure formation on a supermolecular structure.
Transient photoconductivity in a discotic liquid crystal
1993
Using a time-of-flight technique, different transport mechanisms, deep trapping, multiple shallow trapping, and ideal itrinsic transport, can be observed in the different temperature and phase regions of the liquid-crystalline photoconductor hexapentyloxytriphenylene. The temperature and field dependences of carrier mobilities up to 1\ifmmode\times\else\texttimes\fi{}${10}^{\mathrm{\ensuremath{-}}3}$ ${\mathrm{cm}}^{2}$/V s have been determined; this value exceeds considerably the mobilities of the most commonly used organic photoconductors. The experiments reflect a variety of transport phenomena which are novel in the field of liquid-crystalline systems.