Search results for " liquid crystal"
showing 10 items of 100 documents
Characterization of membrane-spacer industrial distillers using thermochromic liquid crystals
2011
Experimental Analysis via Thermochromic Liquid Crystals of the Temperature Local Distribution in Membrane Distillation Modules
2013
A reliable and optimized design of channels for Membrane Distillation (MD) requires knowledge of local temperature distributions within the module. This information is essential to measure the temperature polarization, choice the module configuration (net spacer features, channel size, etc) providing the best process performance. Notwithstanding such crucial aspects, only few studies have been devoted to the experimental characterization of MD channels and none of them includes data on the local temperature distribution. In the present work, an experimental technique based on the use of Thermochromic Liquid Crystals (TLCs) and digital image processing, previously proposed by the authors (Pi…
ortho -Fluorination of azophenols increases the mesophase stability of photoresponsive hydrogen-bonded liquid crystals
2018
Photoresponsive liquid crystals (LCs) whose alignment can be controlled with UV-Visible light are appealing for a range of photonic applications. From the perspective of exploring the interplay between the light response and the self-assembly of the molecular components, supramolecular liquid crystals are of particular interest. They allow elaborating the structure-property relationships that govern the optical performance of LC materials by subtle variation of the chemical structures of the building blocks. Herein we present a supramolecular system comprising azophenols and stilbazoles as hydrogen-bond donors and acceptors, respectively, and show that ortho-fluorination of the azophenol dr…
An experimental study for the characterization of fluid dynamics and heat transport within the spacer-filled channels of membrane distillation modules
2018
Abstract The thermo-fluid dynamic behavior of spacer-filled channels for membrane distillation was investigated experimentally. Several different geometry were investigated thanks to customized reference spacers manufactured using a 3D printer. In particular, two sets of experiments were conducted: in the first set, cylindrical filaments were orthogonally arranged and the flow attack angle was made to vary from 0o to 90o; in the second set, the flow attack angle was kept symmetrical and the filament angle was made to vary from 30° to 150°. Each spacer was tested for Reynolds numbers between 200 and 900 in the hot channel, while maintaining a constant temperature difference of 13 °C between …
Star-shaped conjugated compounds forming nematic discotic systems
2004
Abstract Star-shaped compounds, having a benzene ( 9a,b ) or a 1,3,5-triazine ( 11a,b ) core and stilbenoid arms were prepared. Hexyloxy chains, attached in the middle of the arms, provide nematic discotic phases ND, which are unusual for such systems. The position of the sidechains prevents the micro-segregation, which is valid for star-shaped discs of columnar phases. The stilbenoid character of 9a,b and 11a,b guarantees a high light sensitivity. Apart from the statistical CC bond formation by irradiation in solution or in the LC phases, a topochemically controlled chemo-, regio- and stereoselective photocyclodimerization 11a → 12 was found in the crystalline state. The structure determin…
Self-assembly in surfactant-based mixtures driven by acid–base reactions: bis(2-ethylhexyl) phosphoric acid–n-octylamine systems
2013
Structural and dynamic features of bis(2-ethylhexyl) phosphoric acid (HDEHP)-n-octylamine (NOA) mixtures as a function of the NOA mole fraction (X-NOA) have been investigated by SAXS, WAXS, IR, dielectric spectroscopy and polarized optical microscopy. In the 0 <= X-NOA < 0.5 range, mixtures are transparent liquids, while the abrupt formation of a waxy solid characterized by an hexagonal bidimensional structure occurs at X-NOA = 0.5. Such a composition-induced phase transition results from the synergetic effect of the progressive increase in number density of ordered HDEHP-NOA nanodomains with X-NOA. Mainly driven by an HDEHP to NOA proton transfer, the increase of structural order with X-NO…
Measurements of temperature polarization phenomena in membrane distillation channels by a thermographic technique
2014
In the present work, a recently presented experimental technique, based on the use of thermochromic liquid crystals (TLCs) and digital image processing, has been employed in order to measure the temperature and local heat transfer coefficient distribution on the membrane surface in a MD spacer-filler channel
Experimental and Numerical Simulations of Flow and Heat Transfer in Heat Exchanger Elements Using Liquid Crystal Thermography
2004
Experimental and numerical investigation of heat transfer and fluid flow were conducted for classic heat exchanger elements (flat plate with fin-tubes in-line, staggered and with vortex generators) and corrugated-undulated ducts under transitional and weakly turbulent conditions. The dependence of average heat transfer and pressure drop on Reynolds number and geometrical parameters was investigated. Distributions of local heat transfer coefficient were obtained by using liquid crystal thermography and surface-averaged values were computed. Three-dimensional numerical simulations were conducted by a finite-volume method using a low-Reynolds number k-e model under the assumption of fully deve…
Transient Development of Rayleigh-Bénard Convection: a TLC Study
2011
Improved Liquid Crystal Thermography by Using True-Colour Image Processing Technology
2002
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