Search results for " magnetic materials"

Ag5 nanoclusters with dual catalytic antiradical activities

2022

Silver nanoclusters of five atoms (Ag5) display outstanding catalytic activities for the deactivation of radicals. Using 2,2-diphenyl-1‑picrylhydrazyl (DPPH) radical as a model system, we observed a fast radical reduction to DPPH anions using only [Ag5] 3 to 4 orders of magnitude less than [DPPH]. Moreover, nanoclusters remain stable at the end of the reaction, and can deactivate again DPPH radicals at the same rate, indicating that they act as anti-radical catalysts. The radical scavenger catalytic activity of Ag5 proceeds selectively through the oxidation of methanol (used to dissolve the radical) to formaldehyde, which is supported by DFT calculations. The obtained catalytic rate constan…

The cryogenic anticoincidence detector for ATHENA-XMS: preliminary results from the new prototype

2012

ATHENA has been the re-scoped IXO mission, and one of the foreseen focal plane instrument was the X-ray Microcalorimeter Spectrometer (XMS) working in the energy range 0.3-10 keV, which was a kilo-pixel array based on TES (Transition Edge Sensor) detectors. The need of an anticoincidence (AC) detector is legitimated by the results performed with GEANT4 simulations about the impact of the non x-ray background onto XMS at L2 orbit (REQ. < 0.02 cts/cm2/s/keV). Our consortium has both developed and tested several samples, with increasing area, in order to match the large area of the XMS (64 mm2). Here we show the preliminary results from the last prototype. The results achieved in this work off…

Spectroelectrochemistry of cytochrome c and azurin immobilized in nanoporous antimony-doped tin oxide

2011

Stable immobilization of two redox proteins, cytochrome c and azurin, in a thin film of highly mesoporous antimony-doped tin oxide is demonstrated via UV-vis spectroscopic and electrochemical investigation.

Ionic liquid gels and antioxidant carbon nanotubes: Hybrid soft materials with improved radical scavenging activity

2019

Hypothesis: Performances of materials are frequently affected by the action of radicals that can induce their degradation. To overcome the above issue, natural antioxidants (AOs) can be added during manufacturing. Considering the high instability of AOs, they have been adsorbed on carbon nanomaterials surface. However, the inclusion of functionalized carbon nanomaterials into gel matrix could enhance the antioxidant efficiency and represent an easy way to disperse and handle the active species.Experiments: Carboxypropyl functionalized carbon nanotubes (f-CNT), pure or with physically adsorbed alpha-tocopherol (f-CNT-VE) and quercetin (f-CNT-Q), were incorporated in some ionic liquid gels (I…

First total synthesis of antiostatin A1, a potent carbazole-based naturally occurring antioxidant.

2009

The first total synthesis of the potent antioxidant antiostatin A1 is reported, where its key features rely on a chemo- and regioselective rhodium-catalysed crossed alkyne cyclotrimerisation reaction applying functionalised ynamides and a palladium-catalysed arylamidation reaction.

Comparison of two different devices to assess intraocular lenses

2016

[EN] In this paper, we have compared the performance of two commercial systems, Kaleo-I and IOLA Plus, in the characterization of monofocal intraocular lenses (IOLs) according to the International Standard requirements (ISO 11979-2). The dioptric power (DP) and the Modulation Transfer Function (MTF) at 100.1p/mm and 3.0 mm aperture have been measured with both instruments in twenty commercial monofocal HEMA IOLs and their agreement was assessed by Bland Altman analysis. Compared with the designed power, IOLA Plus gave lower values in 85% of measures: Kaleo I errors are dependent on the power of the lens: measurements were higher than the designed power in the low-medium power range and lowe…

Structures for the synthesis of stable immitances with arbitrary zeros

1981

Photoassisted Oxidation of the Recalcitrant Cyanuric Acid Substrate in Aqueous ZnO Suspensions

2007

The photoassisted oxidative transformation of the highly recalcitrant cyanuric acid was examined in the liquid−solid regime at pH 3 and natural pH 7.5 under UV irradiation in oxygen- and ozone-saturated ZnO suspensions using ZnO as a photomediator. Loss of cyanuric acid was assayed by HPLC UV absorption spectroscopy, whereas intermediates and final products were determined by HPLC ion chromatography (IC), by MS techniques using an electrospray ionization mass spectrometer operated in the negative-ion mode, and by FT-IR spectroscopy. Final reaction products were CO2 gas and NO3- ions. The measure of nitrate in solution quantified the degree of mineralization of the substrate; its concentrati…

Converting p-terphenyl into a novel organo-catalyst for LED-driven energy and electron transfer photoreactions in water.

2021

p-Terphenyl is a potent photoredox catalyst under UV-irradiation. Aiming for more sustainable reaction conditions, we added two sulfonate groups to this key structure to achieve water solubility and incorporated an SO2-bridge thereby shifting the absorption spectrum towards the visible. The resulting photocatalyst shows unexpected triplet reactivity in several test reactions.

Influence of temperature on the synthesis of thiol-stabilized CdTe nanoparticles in aqueous solutions

2010

We have investigated the evolution of thiol-capped cadmium telluride nanocrystals prepared in aqueous solutions at low and room temperature followed by heating at 50–100 °C. The UV–visible absorption spectra, as well as transmission electron microscopy, atomic force microscopy, and dynamic light scattering observations made it possible to reveal differences in size and structure originating from different heating temperatures. It was shown that minimization of the nucleation process temperature provided formation of larger nanoparticles than at higher temperatures.