Search results for " mineralogia."

Formation of secondary carbonates and native sulphur in sulphate-rich Messinian strata, Sicily

2010

Abstract Microbially formed authigenic carbonates accompanied by native sulphur are present in the ‘Calcare Solfifero’ below a thick succession of gypsum deposited during the Messinian salinity crisis in Sicily. We sampled these carbonates and associated sulphur in five former sulphur mines to subject them to a detailed petrographic and geochemical study in order to explore their different modes of formation. Native sulphur formed in conjunction with microbial sulphate reduction, which is reflected in its depletion in 34S (δ34S values as low as − 2‰ vs. V-CDT) and an enrichment of 34S in the residual sulphate (δ34S values as high as + 61‰). The oxidation of organic matter by sulphate reduct…

Ordering kinetics in synthetic Mg(Al,Fe3+)2O4 spinels: Quantitative elucidation of the whole Al-Mg-Fe partitioning, rate constants, activation energi…

2014

A novel procedure, based on the application of the kinetics simulator Gepasi, has been successfully applied for modeling the cation ordering process in two synthetic Mg(Al2-yFe3+y)O4 spinels (y~ 0.39 and 0.54, samples F39 and F54, respectively). The kinetic profiles suggested a two-stage mechanism, with rapid inter-site exchange of Fe3+ with Mg followed by slow exchange of Al with Mg. The trial to apply the classical approaches, based on the explicit solutions of the differential equations corresponding to single-cation (Sha-Chappel model) or two-cation (Müller model) exchange reactions, proved not feasible in the whole time range, thus implying a lack of information about the exchange proc…

Reconstruction of the paleoenvironmental changes around the Miocene-Pliocene boundary along a W-E transect across the Mediterranean

2006

Abstract In order to reconstruct the environmental changes at the end of the Messinian salinity crisis, a multidisciplinary study has been carried out with a high sampling resolution of the late Messinian–early Zanclean (Zone MPl 1) sediments along a West–East Mediterranean transect. The studied examples comprise sections from southern Spain (Vera/Almanzora), Balearic Basin (ODP Site 975), Tyrrhenian Basin (ODP Site 974), Sicily (Eraclea Minoa), Zakynthos (Kalamaki), Corfu (Aghios Stefanos), Crete (Aghios Vlasis). Previously analyzed sections from the Levantine Basin (Cyprus and ODP Sites 968 and 969) are used for comparison. The sections have been correlated using planktonic foraminiferal …

The scientific instruments of the historical Mineralogical Museum of Palermo: testimonies of almost two centuries of mineralogical and petrographic s…

The scientific collections of the historic Museum of Mineralogy of Palermo are located on the second floor of via Archirafi 36 and are preserved by the Dipartimento di Scienze della Terra e del Mare (DiSTeM) of the University of Palermo. The historical edifice was designed by the architect Antonio Zanca and completed in the years 1933-1934. From the beginning, it has hosted the Institute of Physics at the ground and first floors, today entitled in honour of the famous physicians Emilio Segrè, and the Institute of Mineralogy at the second floor, which has kept one of the richest and ancient collections of Sicilian minerals. Today, the collections are partially exposed and are the subject of …

Kinetic and equilibrium studies for the adsorption of acid nucleic bases onto K10 montmorillonite

2011

Abstract The kinetic of the adsorption of two nucleic acid bases, namely adenine (A) and cytosine (C), on K10 montmorillonite (MMT) clay has been investigated over a wide range of nitrogenous bases concentrations, by using the spectrophotometric method. The measurements have been performed at T = 25.0 °C and pH = 4.0 where adenine and cytosine exist both in their protonated and neutral forms. Preliminary to the kinetic data treatment, the adsorption isotherms have been gathered and, then, analyzed by using the Freundlich and the Dubinin–Radushkevich model. The obtained results allow to draw the conclusion that physisorption of adenine and cytosine on MMT occurs and the process is mainly gov…

Accurate and precise lattice parameters by selected-area electron diffraction in the transmission electron microscope

2009

8 páginas, 6 figuras, 7 tablas.

Evidences on alterations in skeleton composition and mineralization in a site-attached fish under naturally acidified conditions in a shallow CO2 vent

2021

Abstract Background Ocean acidification may affect fish mineralized structures (i.e. otoliths and skeleton). Methods Here, we compared the elemental composition of muscle and skeleton and the mineral features of skeleton in the site-attached fish Gobius bucchichi naturally exposed to high pCO2/low pH conditions in a shallow CO2 vent with fish of the same species exposed to normal pH. Results Overall, no skeleton malformations were found in both pH conditions, but among-site differences were found in the elemental composition. Interestingly, higher Ca/P values, inducing a moderate skeleton maturation, were found in fish exposed to acidified conditions than in controls. Conclusion Our finding…

Un approccio integrato allo studio delle "argille ceramiche" della Sicilia Centrale e Occidentale

2011

Iteratively reweighted least squares in crystal structure refinements

2011

The use of robust techniques in crystal structure multipole refinements of small molecules as an alternative to the commonly adopted weighted least squares is presented and discussed. As is well known, the main disadvantage of least-squares fitting is its sensitivity to outliers. The elimination from the data set of the most aberrant reflections (due to both experimental errors and incompleteness of the model) is an effective practice that could yield satisfactory results, but it is often complicated in the presence of a great number of bad data points, whose one-by-one elimination could become unattainable. This problem can be circumvented by means of a robust least-squares regression that…

New tailor-made bio-organoclays for the remediation of olive mill waste water

2013

A systematic study aimed at obtaining new organoclays for the treatment of Olive Mill Waste water (OMW) has been performed. Several organoclays have been prepared by loading different amounts of the biocompatible surfactant Tween20 onto the K10 montmorillonite (MMT). Complementary kinetic and equilibrium studies on the adsorption of the Tween20 onto the MMT have been carried out and the characterization of the new tailor-made bio-materials has been performed by means of the XRD and FT-IR measurements. Finally the prepared bio-organoclays have been successfully applied for the OMW remediation and they proved to be highly effective in decreasing the organic content (OC) to an extent that depe…