Search results for " molecule"
showing 10 items of 1523 documents
Design of a lambda configuration in artificial coherent nanostructures
2015
The implementation of a three-level Lambda System in artificial atoms would allow to perform advanced control tasks typical of quantum optics in the solid state realm, with photons in the $\mathrm{\mu m}$/mm range. However hardware constraints put an obstacle since protection from decoherence is often conflicting with efficient coupling to external fields. We address the problem of performing conventional STImulated Raman Adiabatic Passage (STIRAP) in the presence of low-frequency noise. We propose two strategies to defeat decoherence, based on "optimal symmetry breaking" and dynamical decoupling. We suggest how to apply to the different implementations of superconducting artificial atoms, …
Toward the Physical Interpretation of Inductive and Resonance Substituent Effects and Reexamination Based on Quantum Chemical Modeling
2017
An application of a charge of the substituent active region concept to 1-Y,4-X-disubstituted derivatives of bicyclo[2.2.2]octane (BCO) [where Y = NO2, COOH, OH, and NH2 and X = NMe2, NH2, OH, OMe, Me, H, F, Cl, CF3, CN, CHO, COMe, CONH2, COOH, NO2, and NO] provides a quantitative information on the inductive component of the substituent effect (SE). It is shown that the effect is highly additive but dependent on the kind of substituents. An application of the SE stabilization energy characteristics to 1,4-disubstituted derivatives of BCO and benzene allows the definition of inductive and resonance contributions to the overall SE. Good agreements with empirical approaches are found. All calc…
Design of a Lambda system for population transfer in superconducting nanocircuits
2013
The implementation of a Lambda scheme in superconducting artificial atoms could allow detec- tion of stimulated Raman adiabatic passage (STIRAP) and other quantum manipulations in the microwave regime. However symmetries which on one hand protect the system against decoherence, yield selection rules which may cancel coupling to the pump external drive. The tradeoff between efficient coupling and decoherence due to broad-band colored Noise (BBCN), which is often the main source of decoherence is addressed, in the class of nanodevices based on the Cooper pair box (CPB) design. We study transfer efficiency by STIRAP, showing that substantial efficiency is achieved for off-symmetric bias only i…
The use of quantum dots in organic chemistry
2009
Abstract We discuss the main mechanisms of interaction between quantum dots (QDs) of different types and organic molecules within the framework of the use of photo-physical properties of colloidal semiconductor nanoparticles for sensing organic and biochemical compounds. We reviewed the recent literature in the field to provide a picture of the state of the art of our knowledge and perspectives on this challenging field. Bearing in mind analysis in organic chemistry based on luminescence and electrochemical changes, we discuss surface interaction based on the use of QDs capped with thiol, cystein, citrate, surfactant, purine and nitroxides, and we explain ligand-analyte, bioconjugate-analyt…
Collective Effects of Organic Molecules based on Holstein-Tavis-Cummings Model
2021
We study the collective effects of an ensemble of organic molecules confined in an optical cavity based on Holstein-Tavis-Cummings model. By using the quantum Langevin approach and adiabatically eliminating the degree of freedom of the vibrational motion, we analytically obtain the expression of the cavity transmission spectrum to analyze the features of polaritonic states. As an application, we show that the dependence for the frequency shift of the lower polaritonic state on the number of molecules can be used in the detection of the ultra-cold molecules. We also numerically analyze the fluorescence spectrum. The variation of the spectral profile with various numbers of molecules gives si…
Dynamic effects in nonlinear magneto-optics of atoms and molecules: review
2004
A brief review is given of topics relating to dynamical processes arising in nonlinear interactions between light and resonant systems (atoms or molecules) in the presence of a magnetic field.
Light flavor and heavy quark spin symmetry in heavy meson molecules
2012
We propose an effective field theory incorporating light SU(3)-flavor and heavy quark spin symmetry to describe charmed meson-antimeson bound states. At lowest order the effective field theory entails a remarkable simplification: it only involves contact range interactions among the heavy meson and antimeson fields. We show that the isospin violating decays of the X(3872) can be used to constrain the interaction between the D and a (D) over bar* mesons in the isovector channel. As a consequence, we can rule out the existence of an isovector partner of the X(3872). If we additionally assume that the X(3915) and Y(4140) are D*(D) over bar* and D*(s)(D) over bar*(s) molecular states, we can de…
Spontaneous lifetimes and relaxation cross-sections of the D1Π state of NaRb
2003
Abstract The time-resolved intensity of dispersed laser induced fluorescence following the Ar + -laser D 1 Π←X 1 Σ + excitation was measured for both 23 Na 85 Rb and 23 Na 87 Rb isotopomers in a thermal cell. Spontaneous radiative lifetime values determined for v ′ ( J ′ ) rovibronic levels of the D 1 Π state in the v ′ range from 0 to 17 and J ′ from 8 to 131 varied from 22.5 to 17.3 ns. Averaged collisional quenching cross-section values of (3–6)×10 −14 cm 2 were obtained for NaRb (D 1 Π, v ′ , J ′ ) + Rb collisions from the Stern–Volmer plots.
Design and pharmacology of quinuclidine derivatives as M2-selective muscarinic receptor ligands
2001
In our search for M2-selective muscarinic receptor antagonists, we synthesized 1,3-disubstituted indenes. The effects of different basic moieties with regard to binding and selectivity towards the five distinct muscarinic receptor subtypes were investigated. The results show that the quinuclidine series afforded the most promising compounds in terms of both receptor affinity and M2-subtype selectivity.
Intermolecular potential and rovibrational states of the H2O–D2 complex
2012
International audience; A five-dimensional intermolecular potential for H2O-D-2 was obtained from the full nine-dimensional ab initio potential surface of Valiron et al. [P. Valiron, M. Wernli, A. Faure, L. Wiesenfeld, C. Rist, S. Kedzuch, J. Noga, J. Chem. Phys. 129 (2008) 134306] by averaging over the ground state vibrational wave functions of H2O and D-2. On this five-dimensional potential with a well depth D-e of 232.12 cm (1) we calculated the bound rovibrational levels of H2O-D-2 for total angular momentum J = 0-3. The method used to compute the rovibrational levels is similar to a scattering approach-it involves a basis of coupled free rotor wave functions for the hindered internal r…