Search results for " network"
showing 10 items of 6428 documents
Supramolecular isomerism in spin crossover networks with aurophilic interactions
2004
Assembly of FeII, 3-cyanopyridine and [Au(CN)2]– affords, in one-pot reaction, three coordination polymers that represent a genuine example of supramolecular isomerism with strong influence in the spin crossover regime of the FeII ions. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es
Re-entrant glass transition in a colloid-polymer mixture with depletion attractions.
2002
Performing light scattering experiments we show that introducing short-ranged attraction to a colloidal suspension of nearly hard spheres by addition of free polymer produces new glass transition phenomena. We observe a dramatic acceleration of the density fluctuations amounting to the melting of a colloidal glass. Increasing the strength of the attractions the system freezes into another nonergodic state sharing some qualitative features with gel states occurring at lower colloid packing fractions. This reentrant glass transition is in qualitative agreement with recent theoretical predictions.
Monte Carlo and molecular dynamics simulation of the glass transition of polymers
1998
Two coarse-grained models for polymer chains in dense glass-forming polymer melts are studied by computer simulation: the bond-fluctuation model on a simple cubic lattice, where a bond-length potential favors long bonds, is treated by dynamic Monte Carlo methods, and a bead-spring model in the continuum with a Lennard-Jones potential between the beads is treated by Molecular Dynamics. While the dynamics of both models differ for short length scales and associated time scales, on mesoscopic spatial and temporal scales both models behave similarly. In particular, the mode coupling theory of the glass transition can be used to interpret the slowing down of the undercooled polymer melt. For the…
Dynamics-based assessment of nanoscopic polymer-network mesh structures and their defects.
2018
Polymer-network gels often exhibit complex nanoscopic architectures. First, the polymer-network mesh topology on scales of 1–10 nm is usually not uniform and regular, but disordered and irregular. Second, on top of that, many swollen polymer networks display spatial inhomogeneity of their polymer segmental density and crosslinking density on scales of 10–100 nm. This multi-scale structural complexity affects the permeability, mechanical strength, and optical clarity of the polymer gels, which is of central relevance for their performance in popular applications. As a result, there is a need to characterize the polymer network structures on multiple scales. On the scale of the spatial inhomo…
Interfacial properties of glassy polymer melts: A Monte Carlo study
1996
The properties of the interface between a polymer melt and a solid wall are studied over a wide range of temperatures by dynamic Monte Carlo simulations. It is shown that in the supercooled state near the glass transition of the melt an “interphase” forms, the structure of which is influenced by the wall. The thickness of this interphase is determined from the monomer density profile near the surface and is strongly temperature dependent. At low glass-like temperatures it is larger than the bulk radius of gyration of the chains.
Optical Hole Burning and Thermal Irreversibility of Non-Ergodic Systems: Polymers, Proteins, Glasses
1989
A spectral hole is used to probe configurational dynamics of non-ergodic systems far below the glass transition temperature
From orientational glasses to structural glasses: What computer simulations have contributed to understand experiments
2002
Abstract Orientational glasses, produced by random dilution of molecular crystals, exhibit a freezing transition of the quadrupole moments. Monte Carlo simulations of lattice models (generalization of the Edwards–Anderson spin glass model) have been used to elucidate this behavior. While short range models exhibit a static glass transition at zero temperature only, the infinite range Potts glass exhibits a transition where a glass order parameter appears discontinuously. At higher temperature, a dynamical transition occurs, described by mode-coupling theory (MCT). MCT has also been tested by Monte Carlo and molecular dynamics simulations of coarse-grained models of glass-forming polymers. W…
Fundamental and practical aspects concerning the characterization of smart textiles
2017
The research aims towards a novel methodology of ZnO impregnation onto polyamide supports, in order to attain a special inorganic-organic hybrid polymer material, with increased UV-barrier attributes and high hydrophobicity. The experimental approach employed ZnO micro particles powder. Solutions with different concentrations of ZnO powder dispersed in methanol are prepared as anti-UV finishing agent and applied onto polyamide fabric. The responsive behaviour of this complex polymer network to UV irradiation, the photo protective performance and its time stability, also the hydrophobic character are assessed by different characterization techniques. The proposed method has advantages, like:…
La eclosión de la opinión del alumnado sobre la enseñanza de la Geografía. El geoforo iberoamericano en 2015
2015
Los datos que se aportan en esta síntesis anual nos indican que existe un crecimiento muy relevante no sólo en las visitas sino, sobre todo, en la participación del Geoforo Iberoamericano a través de las opiniones de alumnos y docentes. La didáctica de la Geografía se transforma en educación ciudadana por medio de las redes sociales, una aspiración que se ha gestado desde el año 2009. La colaboración de las personas de un lado y otro del Océano Atlántico nos permitirá definir con más rigor y precisión los desafíos de la formación docente en los próximos años.
La comunità educante di fronte alla pandemia: possibili strategie di intervento e nuovi scenari in un’ottica di rete
2022
Quando nel mese di marzo 2020, anche i servizi educativi 0-6 in Italia furono chiusi in base alle misure di sicurezza per pandemia da Covid 19, ci si ritrovò da un giorno all’altro e senza alcuna esperienza pregressa, ad organizzare delle forme di educazione a distanza e di sostegno alle famiglie e ai bambini. Nell’articolo, in particolare, descrivo come si è cercato di far fronte all’emergenza nei nidi e nelle scuole dell’infanzia gestiti dal Comune di Palermo e come l’esperienza del primo lock down abbia permesso di mettere a fuoco alcune strategie di intervento che si sono rivelate una risorsa potenzialmente trasferibile in situazioni di normalità. Sottolineo, inoltre, come la necessità …