Search results for " nitrogen"
showing 10 items of 319 documents
Recent Advances in Catalytic Enantioselective Synthesis of Pyrazolones with a Tetrasubstituted Stereogenic Center at the 4-Position
2020
AbstractPyrazolone [2,4-dihydro-3H-pyrazol-4-one] represents one of the most important five-membered nitrogen heterocycles which is present in numerous pharmaceutical drugs and molecules with biological activity. Recently, many catalytic methodologies for the asymmetric synthesis of chiral pyrazolones have been established with great success, specially, for the synthesis of pyrazolones bearing a tetrasubstituted stereocenter at C-4. This review summarizes these excellent research studies since 2018, including representative examples and some mechanistic pathways explaining the observed stereochemistry.1 Introduction2 Catalytic Enantioselective Synthesis of Chiral Pyrazolones with a Full Car…
Detection of reactive nitrogen containing particles in the tropopause region? Evidence for a tropical nitric acid trihydrage (NAT) belt
2008
The detection of nitric acid trihydrate (NAT, HNO<sub>3</sub>&times;3H<sub>2</sub>O) particles in the tropical transition layer (TTL) harmonizes our understanding of polar stratospheric cloud formation. Large reactive nitrogen (NO<sub>y</sub>) containing particles were observed on 8 August 2006 by instruments onboard the high altitude research aircraft M55-Geophysica near and below the tropical tropopause. The particles, most likely NAT, have diameters less than 6 &mu;m and concentrations below 10<sup>-4</sup> cm<sup>&minus;3</sup>. The NAT particle layer was repeatedly detected at altitudes between 15.1 and 17.5 km ove…
Organic and chemical N fertilization on coriander (Coriandrum sativum L.)
2014
Coriander (Coriandrum sativum L.) is an annual herbaceous Medicinal and Aromatic Plant (MAP) dealing with a great industrial interest because of its strongly-scented fruits (“seeds”). The role of N fertilization in coriander seed yield is matter of debate as far; information is missing, for instance, about the effects of organic N fertilization, a mandatory technique when the organic cropping management is chosen. Organic and chemical N fertilizers have been supplied on coriander from 2001–2002 to 2006–2007 in a Mediterranean semi-arid environment, and their effects on the formation of biomass and seeds yield have been evaluated. Different organic fertilizers, allowed by EU regulations conc…
N use and partitioning in coriander (Coriandrum sativum L.) after organic and conventional N fertilization
2010
In coriander, a well known spice herb, many studies concerning the effect of N fertilization have been conducted in special areas where the cultivation of such plant has a major importance, such as India. Limited information is available as concerns the response of coriander to N fertilization under Mediterranean climatic conditions, above all when organic N fertilizers (mandatory when organic cropping management is chosen) are used. This work refers about some observations realised from 2004 to 2006 by an experiment on organic and mineral N fertilization techniques in coriander, carried on in the experimental farm “Sparacia” (Cammarata, AG, Sicily). Similarly to what suggested for other sp…
Comparing encapsulation-dehydration and droplet-vitrification for cryopreservation of sugarcane (Saccharum spp.) shoot tips
2011
Abstract In this study, in vitro shoot tips of two sugarcane clones were successfully cryopreserved using encapsulation-dehydration and droplet-vitrification with two vitrification solutions, PVS2 and PVS3. For both clones, encapsulation-dehydration induced significantly higher recovery, reaching 60% for clone H70-144 and 53% for clone CP68-1026, compared with droplet-vitrification in which recovery was 33–37% for clone H70-144 and 20–27% for clone CP68-1026. Optimal conditions included preculture of encapsulated shoot apices for 24 h in liquid medium with 0.75 M sucrose and dehydration with silica gel to 20% moisture content (fresh weight basis) before direct immersion in liquid nitrogen. …
1,2,3-Triazole in Heterocyclic Compounds, Endowed with Biological Activity, through 1,3-Dipolar Cycloadditions
2014
1,3-Dipolar cycloaddition reactions can be considered a powerful synthetic tool in the building of heterocyclic rings, with applications in different fields. In this review we focus on the synthesis of biologically active compounds possessing the 1,2,3-triazole core through 1,3-dipolar cycloaddition reactions. The 1,2,3-triazole skeleton can be present as a single disubstituted ring, as a linker between two molecules, or embedded in a polyheterocycle. The cycloaddition reactions are usually catalysed by copper or ruthenium. Domino reactions can be achieved through dipolarophile anion formation, generally followed by cyclisation. The variety of attainable heterocyclic structures gives an ill…
KOSMOS 2018 Gran Canaria mesocosm study: water column biogeochemistry
2021
The data set compiles biogeochemical water column collected during a KOSMOS mesocosm experiment carried out in the frame work of the Ocean Artificial Upwelling project. The experiment was performed in the North-East Atlantic Ocean off the coast of Gran Canaria in autumn 2018 and lasted for 39 days. In this study we investigated the effect of different intensities of artificial upwelling combined with two upwelling modes (recurring additions versus one singular addition) on POC export and its potential transfer efficiency to depth. The data set includes the amounts of surface water that were exchanged with nutrient-rich deep water (from ~300 m depth), primary production and chlorophyll a, el…
KOSMOS 2018 Gran Canaria mesocosm study: particle flux data from sediment trap
2021
The data set compiles sinking flux data collected during a KOSMOS mesocosm experiment carried out in the frame work of the Ocean Artificial Upwelling project. The experiment was performed in the North-East Atlantic Ocean off the coast of Gran Canaria in autumn 2018 and lasted for 39 days. In this study we investigated the effect of different intensities of artificial upwelling combined with two upwelling modes (recurring additions versus one singular addition) on POC export and its potential transfer efficiency to depth. The data set includes the amounts of surface water that were exchanged with nutrient-rich deep water (from ~300 m depth). It also contains particle flux data, i.e. POC flux…
Stable isotope profiles of nitrogen gas indicate denitrification in oxygen-stratified humic lakes
2011
Mid-summer N(2) profiles were analyzed from nine oxygen-stratified, humic-acid-rich lakes using a continuous flow isotope ratio mass spectrometer and a Gasbench II device. Sample preparation steps were performed under water to avoid air contamination. The instrument precision for the δ(15)N measurement was high (0.03‰), but for the whole sampling and analysis procedure the mean deviation between replicate samples was 0.13‰ for the δ(15)N measurements and 5.5% for the N(2) gas concentration analysis. The results show that the Gasbench peripheral was suitable for measurement of the (15)N natural abundance of dissolved nitrogen gas, with denitrification indicated by the oversaturation and slig…
High Nitrogen Removal in a Constructed Wetland Receiving Treated Wastewater in a Cold Climate
2018
Constructed wetlands provide cost-efficient nutrient removal, with minimal input of human labor and energy, and their number is globally increasing. However, in northern latitudes, wetlands are rarely utilized, because their nutrient removal efficiency has been questioned due to the cold climate. Here, we studied nutrient retention and nitrogen removal in a boreal constructed wetland (4-ha) receiving treated nitrogen-rich wastewater. On a yearly basis, most of the inorganic nutrients were retained by the wetland. The highest retention efficiency was found during the ice-free period, being 79% for ammonium-nitrogen (NH4+-N), 71% for nitrate-nitrogen (NO3--N), and 88% for phosphate-phosphorus…