Search results for " plastics"
showing 10 items of 2628 documents
Size, Form and Flexibility of the Rubber Molecule
1962
Abstract Natural rubber can be brominated in dilute cyclohexane solution, whereby the molecular weight, corresponding to the bromine content, increases. For brominated rubber, increasing bromine content makes cyclohexane an increasingly poorer solvent, which is shown by a contraction of the molecule coils and a decrease in the second virial coefficient. Quantitative results were obtained through viscosity and light scattering measurements. Cyclohexane solutions of brominated rubber containing about 43% bromine have a θ point at room temperature. Here the second virial coefficient is zero and the coil has an ideal Gaussian density distribution. In this state the coil diameter is about 1.6 ti…
Functionalized Polystyrene Nanoparticles Trigger Human Dendritic Cell Maturation Resulting in Enhanced CD4+T Cell Activation
2012
Nanoparticles (NP) represent a promising tool for biomedical applications. Here, sulfonate- and phosphonate-functionalized polystyrene NP are analyzed for their interaction with human monocyte-derived dendritic cells (DC). Immature dendritic cells (iDC) display a higher time- and dose-dependent uptake of functionalized polystyrene NP compared to mature dendritic cells (mDC). Notably, NP induce an enhanced maturation of iDC but not of mDC (upregulation of stimulatory molecules and cytokines). NP-triggered maturation results in a significantly enhanced T cell stimulatory capacity (increased CD4(+) T cell proliferation and IFN-γ production), indicating a shift to a pronounced Th1 response. Imm…
Effect of stiffness on the phase behavior of cubic lattice chains
2005
Gran canonica Monte Carlo (GCMC) simulazioni assistite da tecniche di riponderazione istogramma sono stati utilizzati per studiare l'effetto della flessibilità catena sul comportamento di soluzione fase di cubi catene reticolari corti con 4-32 segmenti. Ciò è stato fatto variando un parametro di rigidità gradualmente fino alla media calcolata end-to-end distanza avvicinato la lunghezza totale. Per entrambe le catene flessibili e rigide si è riscontrato che la temperatura critica, ottenuta tramite mista analisi dei campi di dimensioni finite, aumentata lunghezza della catena e la densità critica trasferisce a valori più bassi, in accordo con le osservazioni sperimentali. Il estrapolato lungh…
Hyaluronic Acid–Silica Nanohybrid Gels
2013
Excessive water sorption and low mechanical properties are a severe drawback in some biomedical applications of hyaluronic acid (HA). A way to improve these properties is here explored through the novel concept of nanohybrid hydrogels consisting of a HA matrix including different amounts of silica-derived species. This inorganic filler phase controls the mechanical and swelling properties of HA cross-linked matrices. Below a 2 wt % of silica in the systems, nanoparticle aggregates of tens of nanometers and silica oligomers are distributed more or less homogeneously throughout the organic matrix, without percolating. This morphology of the silica phase is accompanied by an increased swelling…
Rheological and Mechanical Behavior of LDPE/Calcium Carbonate Nanocomposites and Microcomposites
2012
The increase of the interest in polymer nanocomposites has been leading to continuous growing search toward nanofillers alternative to the widely known clay-based ones. One of these possible alternatives is represented by calcium carbonate nanoparticles, which have not been widely investigated in such context. In this article, a study on the rheological and morphological behavior of dif- ferent low density polyethylene-calcium carbonate nanocomposites, compared with a reference calcium carbonate microcomposite, is presented. Several different nanosized calcium carbonates at different amounts were used. The results from the rheological and me- chanical tests outlined that only minor changes …
Composite Hydrogels of Alkyl Functionalized Gellan Gum Derivative and Hydroxyapatite/Tricalcium Phosphate Nanoparticles as Injectable Scaffolds for b…
2021
An alkyl functionalized gellan gum derivative was here used to produce hydrogels containing hydroxyapatite and tricalcium phosphate nanoparticles as injectable nanostructured scaffolds for bone regeneration. The amphiphilic nature of the polysaccharide derivative along with its thermotropic behavior and ionotropic crosslinking features made possible to produce injectable bone mimetic scaffolds that can be used to release viable cells and osteoinductive biomolecules. The influence of different nanoparticles concentration on the rheological and physicochemical properties of the injectable systems was studied. We found that the presence of inorganic nanoparticles reinforces the three-dimension…
TENACITÀ ALLA FRATTURA INTERLAMINARE DI COMPOSITI CFRP SOTTOPOSTI A PROCESSI DI INVECCHIAMENTO IDROTERMICO
2011
In questo lavoro si è condotto uno studio degli effetti dell’invecchiamento idrotermico sulla tenacità alla frattura interlaminare in Modo I di laminati in composito CFRP con lay-up unidirezionale. I pannelli realizzati impiegano una resina epossidica DGEBA. Provini DCB sono stati ricavati in accordo con la norma ASTM D5528. Prove dinamico meccaniche DMTA sono state condotte per analizzare l’influenza dell’invecchiamento sulla temperatura di transizione vetrosa, e quindi sul grado di fragilità della matrice. Il lavoro descrive il set-up sperimentale per la determinazione delle Curve R, evidenziando l’influenza della morfologia del tessuto in carbonio. I valori di GIC di innesco e di propaga…
Analysis of the mechanical performance of hybrid (SPR/bonded) single-lap joints between CFRP panels and aluminum blanks
2013
Abstract The increasing use of innovative materials in manufacturing of modern mechanical components has led to the development of reliable joints between innovative (composite materials etc.) and traditional materials (steel, aluminum etc.). In the last few years, hybrid joints, combining the advantages of the adhesive joints and traditional mechanical joints as bolted or riveted joints, have been shown an increasing industrial interest especially in automotive and aerospace sectors. In the present paper a systematic experimental study of hybrid lap joints was carried out with the aim to detect the optimal joint configuration. Tensile tests on hybrid joints made by combining adhesive bondi…
Structural Characterization of Isomeric Dimers from the Oxidative Oligomerization of Catechol with a Biomimetic Catalyst
2007
In a previous paper, it has been reported about the formation of catechol di-, tri- and tetramers within an oxidative polymerization catalyzed by synthetic water-soluble iron-porphyrin as an efficient alternative to bio-labile natural peroxidase. It has also been demonstrated the occurrence of both C-C and C-O-C coupling mechanisms. However, since the coupling products were determined by mass spectroscopy, the exact bonding position could not have been precisely ascertained for the C-C bonded isomeric dimers that are the dominant products of catechol oligomerization. Therefore, here isolation and characterization of catechol isomeric dimers, obtained by oxidative coupling under the catalysi…
Catechol-Initiated Polyethers: Multifunctional Hydrophilic Ligands for PEGylation and Functionalization of Metal Oxide Nanoparticles
2012
Bifunctional CA-PEG (catechol-poly(ethylene glycol)) and multifunctional CA-PEG-PGA/PEVGE (poly(glycidyl amine)/poly(ethylene glycol vinyl glycidyl ether)) ligands for the functionalization and solubilization of nanoparticles are introduced. Tunable polymers with polydispersities1.25 and molecular weights in the range 500-7700 g mol(-1) containing a catechol moiety for conjugation to metal oxide nanoparticles were prepared. The functional PEG ligands were synthesized starting from the acetonide-protected catechol initiator 2,2-dimethyl-1,3-benzodioxole-5-propanol (CA-OH) for oxyanionic polymerization. CA-OH was used both for homopolymerization of ethylene oxide (EO) as well as copolymerizat…