Search results for " relationships"
showing 10 items of 317 documents
Structure and performance properties of environmentally-friendly biocomposites based on poly(ɛ-caprolactone) modified with copper slag and shale dril…
2018
The potential application of two types of industrial wastes, drill cuttings (DC) and copper slag (CS), as silica-rich modifiers of poly(ɛ-caprolactone) (PCL) was investigated. Chemical structure and physical properties of DC and CS fillers were characterized using X-ray diffractometer, X-ray fluorescence spectroscopy, particle size and density measurements. PCL/DC and PCL/CS composites with a variable content of filler (5 to 50 parts by weight) were prepared by melt compounding in an internal mixer. It was observed that lower particle size of DC filler enhanced processing of biocomposites comparing to CS filler. Smaller particles of DC filler and thus the higher specific surface area, enabl…
Structural, mechanical and thermal behavior assessments of PCL/PHB blends reactively compatibilized with organic peroxides
2018
Abstract The efficiency of two commercially available organic peroxides, dicumyl peroxide (DCP) and di-(2-tert-butyl-peroxyisopropyl)-benzene (BIB), during reactive processing of poly(e-caprolactone)/poly(3-hydroxybutyrate) (PCL/PHB) blends was investigated. The changes in chemical structure of PCL/PHB blends, as a function of organic peroxide type (DCP/BIB) and content (in range: 0–1.0 parts by weight - pbw), were characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis combined with infrared spectroscopy, and headspace analysis combined with gas chromatography with flame ionization detector. Performance properties of PCL/PHB blends were evaluated based on diffe…
Synthesis and biological evaluation of papain-family cathepsin L-like cysteine protease inhibitors containing a 1,4-benzodiazepine scaffold as antipr…
2014
Novel papain-family cathepsin L-like cysteine protease inhibitors endowed with antitrypanosomal and antimalarial activity were developed, through an optimization study of previously developed inhibitors. In the present work, we studied the structure-activity relationships of these derivatives, with the aim to develop new analogues with a simplified and more synthetically accessible structure and with improved antiparasitic activity. The structure of the model compounds was significantly simplified by modifying or even eliminating the side chain appended at the C3 atom of the benzodiazepine scaffold. In addition, a simple methylene spacer of appropriate length was inserted between the benzod…
Ocho notas sobre la Casa Farnsworth de Ludwig Mies van der Rohe
2020
Mies was in the top of his career when he built the Farnsworth House. The analysis of this work shows some characteristics of his architectural thought: the relationships between architecture and nature, the definition of the pavilion type, his concept of architectural space, the role of structure and limits, the idea free plan and the meaning of construction
La atención a la situación del mundo en la educación científica
2021
Protagonizamos en la actualidad una epoca de profundas y aceleradas transformaciones que, unida a una multiplicidad de problemas medioambientales y sociales cuyos efectos vienen agravandose a nivel planetario, ha convertido la "situacion del mundo" en objeto directo de preocupacion. En la Conferencia de las Naciones Unidas sobre Medio Ambiente y Desarrollo, celebrada en Rio de Janeiro en 1992 y conocida como Primera Cumbre de la Tierra, se reclamo una decidida accion de los educadores, de todas las areas, para que los ciudadanos y ciudadanas adquieran una correcta percepcion de cual es esa situacion y puedan participar en la toma de decisiones fundamentadas. Un primer proposito de esta inve…
Parenting, Peer Relationships, Academic Self-efficacy, and Academic Achievement: Direct and Mediating Effects
2017
The aim of the present study is to analyze the relation between authoritative and permissive parenting styles with the kinds of adolescent peer relationships (attachment, victimization, or aggression), and of the latter ones, in turn, with academic self-efficacy, and academic performance, in three waves that range from the early-mid adolescence to late adolescence. Five hundred Spanish adolescents, of both sexes, participated in a three-wave longitudinal study in Valencia, Spain. In the first wave, adolescents were either in the third year of secondary school or the fourth year of secondary school. The mean age in the first wave was 14.70 (SD = 0.68; range = 13–16 years). Child Report of Pa…
Promoting Children's Wellbeing. Policies, Practices and Current Trends
2015
Abstract Mastering emotions and developing relationship skills are considered vital in this century of change. The current study meets the need of active experimentation with new ways of building educational relationships at early ages. The chosen theme is relevant and timely for both theory and educational practice. An innovation of the relationship models that is to place an accent on children's involvement and value in the educational process is required. We appreciate that we cannot value the voice of children in their absence. A re-examination and reconstruction of adult attitudes to create a better world for children becomes the new trend.
Benchmarking plant diversity of Palaearctic grasslands and other open habitats
2021
© 2021 The Authors.
Chemical communication in termites: syn-4,6-Dimethylundecan-1-ol as 3 trail-following pheromone, syn-4,6-dimethylundecanal and 4 (5E)-2,6,10-trimethy…
2011
The trail-following pheromone and sex pheromones were investigated in the Indomalayan termite Hodotermopsis sjoestedti belonging to the new family Archotermopsidae. Gas chromatography coupled to mass spectrometry (GC-MS) after solid phase microextraction (SPME) of the sternal gland secretion of pseudergates and trail-following bioassays demonstrated that the trailfollowing pheromone of H. sjoestedti was syn-4,6-dimethylundecan-1-ol, a new chemical structure for termite pheromones. GC-MS after SPME of the sternal gland secretion of alates also allowed the identification of sex-specific compounds. In female alates, the major sex-specific compound was identified as (5E)-2,6,10-trimethylundeca-…
Study of relationships between the structure of aroma compounds and their retention-release between vapour phase and dairy gels
2010
An integrated approach physicochemistry and structures activity relationships has been carried out to study the aroma compounds retention-release phenomenon in a fat free dairy gel added with pectin. This study aimed to identify the molecular properties that govern this phenomenon assuming that modifying the structure leads automatically to a change in the retention-release of aroma compounds. For this purpose, we have determined the partition coefficients of 28 aroma compounds in water, in pectin gels and in dairy gels supplemented or not supplemented with pectin, at equilibrium conditions using the PRV method (Phase Ratio Variation). Then, we have performed a structure-retention relations…