Search results for " release"

showing 10 items of 535 documents

Experimental Tests of Fatigue Induced Delamination in Gfrp and Cfrp Laminates

2007

This work deals with the experimental analysis of the delamination phenomena in various composite materials under different loading conditions. Quasi-static and fatigue tests are performed on specimens made of glass-fibre reinforced plastic (GFRP) and carbon-fibre reinforced plastic (CFRP). In particular, under both quasi-static and fatigue loading, single fracture modes I and II (using standard DCB and ENF test configurations) and mixed modes I+II (using the MMB test configuration) with several mode mixtures, have been analysed. Further experiments of delamination growth with mode mixture that varies with the crack length, will be performed.

Strain energy release rateMaterials scienceDelaminationFatigue loadingFibre-reinforced plasticComposite materialSingle fracture
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Thermodynamics and continuum fracture mechanics for nonlocal-elastic plastic materials

2002

Nonlocal elasticity is used as an improved elasticity model which engenders no crack-tip stress singularities and thus makes applicable the classical stress-based failure criteria. Considering nonlocal-elastic plastic materials exposed to softening by particle decohesion in a process surface and to subsequent surface separation by fracture, fracture mechanics is addressed within the framework of irreversible internal-variable thermodynamics in the hypothesis of small strains and arbitrary (but sufficiently regular) fracture surface (crack surface plus process surface). The state equations and the energy dissipation densities are derived for the bulk material and for the process surface, for…

Strain energy release rateMaterials scienceMechanical EngineeringGeneral Physics and AstronomyThermodynamicsFracture mechanicsCrack growth resistance curvePhysics::GeophysicsCrack closureCohesive zone modelFracture toughnessMechanics of MaterialsGeneral Materials ScienceStress intensity factorStress concentrationEuropean Journal of Mechanics - A/Solids
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Mixed mode energy release rates for bonded composite joints

2011

Abstract: Analytical formulae developed by Luo and Tong (2009) to determine the mixed mode strain energy release rates of laminated and co-cured composite structures and joints are reviewed. The effects of varying loading conditions and geometries on the mode mixity found analytically are investigated via a parametric study. A critical evaluation of the analytical formulae indicates that the formulae are robust in calculating the total strain energy release rate, but may underestimate the mode II component compared with the finite element analysis and experimental results. Possible reasons for this discrepancy are discussed, including the effect of stress concentrations and singularities at…

Strain energy release rateMaterials sciencebusiness.industryDelaminationComposite numberGravitational singularityMechanicsStructural engineeringbusinessFinite element methodParametric statisticsStrain energyStress concentration
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Competition between the buckling-driven delamination and wrinkling in compressed thin coatings

2012

Abstract The competition between two common failure modes of a thin coating under in-plane compression, the surface wrinkling and the buckling-driven delamination, is studied to assess the critical strain when the mechanical instability may occur at given geometrical and material parameters. A buckling map is constructed based on results of a finite element analysis, which relates the critical applied strain for the onset of instability to the interface adhesion and elastic properties of materials. An approximate scaling relation is derived for the energy release rate of buckling-driven delamination of a coating deposited on a compliant substrate.

Strain energy release rateMaterials sciencebusiness.industryDelaminationStructural engineeringengineering.materialCondensed Matter PhysicsCompression (physics)InstabilityAtomic and Molecular Physics and OpticsFinite element methodSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCoatingBucklingengineeringElectrical and Electronic EngineeringComposite materialSafety Risk Reliability and QualitybusinessMaterial propertiesMicroelectronics Reliability
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Crack growth analysis at adhesive–adherent interface in bonded joints under mixed mode I/II

2008

The propagation of an interface crack subjected to mixed mode I/II was investigated for two 2024-T351 aluminum thin layers joined by means of DP760 epoxy adhesive produced by 3M©. On the basis of beam theory, an analytical expression for computing the energy release rate is presented for the mixed-mode end loaded split (MMELS) test. The analytical strain energy release rate was compared by finite element (FE) analysis using the virtual crack closure technique (VCCT). Several fatigue crack growth tests were carried out in a plane bending machine to compare the experimental energy release rates to those of the analytical and FE solutions. Experimental results showed the relationship between t…

Strain energy release rateMaterials sciencebusiness.industryMechanical EngineeringDelaminationCrack tip opening displacementFracture mechanicsStructural engineeringParis' lawCrack growth resistance curveCrack closureMechanics of Materialsmental disordersGeneral Materials ScienceAdhesiveComposite materialbusiness
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Impact of Destroying the Structure of Model Gels on Volatile Release

2007

International audience; The release of a strawberry aroma from different composite gels taken as models of fruit preparations and from a sucrose solution was investigated. The composition of the model systems differed with regard to the gelling agent, either pectin or carrageenan, and to the rigidity of the gel. With the use of atmospheric pressure chemical ionization−mass spectrometry, the release profiles of the aroma compounds were determined under stirring. At the same time, purge and trap measurements were performed to determine the release profiles of the aroma compounds without stirring. The comparison of the patterns obtained using these two complementary methods made it possible to…

Sucrosefood.ingredientPectinflavor profileMass spectrometry01 natural sciencesFragariachemistry.chemical_compound0404 agricultural biotechnologyfood[CHIM.ANAL]Chemical Sciences/Analytical chemistryrelease rateAroma compound[CHIM]Chemical SciencesstructureCaproatesFlavorAromaChromatographyVolatilisationbiology010401 analytical chemistrydiffusionfood and beveragesAPCI-MS04 agricultural and veterinary sciencesGeneral Chemistrybiology.organism_classification040401 food science0104 chemical sciencesCarrageenanSolutionsAroma release[CHIM.POLY]Chemical Sciences/PolymerschemistryModels ChemicalFruitOdorantsVolatilizationGeneral Agricultural and Biological SciencesVolatility (chemistry)Gels
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Polymeric drug delivery micelle-like nanocarriers for pulmonary administration of beclomethasone dipropionate

2017

In this paper, the potential of novel polymeric micelles as drug delivery systems for Beclomethasone Dipropionate (BDP) administration into the lung is investigated. These nanostructures are obtained starting from α,β-poly(N-2-hydroxyethyl)-D,L-aspartamide (PHEA), which was subsequently functionalized with O-(2-aminoethyl)-O’-methylpolyethylenglycole (PEG2000), ethylenediamine (EDA) and lipoic acid (LA), obtaining PHEA-PEG2000-EDA-LA graft copolymer. Empty and drug-loaded micelles possess adequate chemical-physical characteristics for pulmonary administration such as spherical shape, slightly positive surface charge and mean size of about 200 nm. Besides, BDP-loaded micelles, obtained …

Surface PropertieAnti-Inflammatory AgentsBiocompatible MaterialsMucin permeation02 engineering and technologyPharmacology030226 pharmacology & pharmacyMicelleAntioxidantsDrug Delivery Systems0302 clinical medicineNanoparticleColloid and Surface ChemistryCopolymerDrug CarrierLungMicellesmedia_commonCell uptakeBiocompatible MaterialDrug CarriersLipoic acidThioctic AcidChemistryBeclomethasoneSurfaces and InterfacesGeneral Medicinerespiratory systemEthylenediamines021001 nanoscience & nanotechnologyPolyaspartamideAnti-Inflammatory AgentDrug deliveryPeptideAntioxidant0210 nano-technologyDrug carrierSurfaces and InterfaceHumanBiotechnologyDrugBiocompatibilitySurface PropertiesCell Survivalmedia_common.quotation_subjectEthylenediamineBronchi03 medical and health sciencesMicroscopy Electron TransmissionPolymeric micelleHumansSurface chargeParticle SizePhysical and Theoretical ChemistryEpithelial CellEthanolEpithelial CellsMicroscopy FluorescenceSettore CHIM/09 - Farmaceutico Tecnologico ApplicativoNanoparticlesNanocarriersPeptidesDrug Delivery SystemNuclear chemistrySustained releaseMicelle
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Halloysite nanotubes filled with salicylic acid and sodium diclofenac: effects of vacuum pumping on loading and release properties

2021

AbstractIn this work, we investigated the effects of the vacuum pumping on both the loading efficiencies and the release kinetics of halloysite nanotubes filled with drug molecules dissolved in ethanol. As model drugs, salicylic acid and sodium diclofenac were selected. For comparison, the loading of the drug molecules was conducted on platy kaolinite to explore the key role of the hollow tubular morphology on the filling mechanism of halloysite. The effects of the pressure conditions used in the loading protocol were interpreted and discussed on the basis of the thermodynamic results provided by Knudsen thermogravimetry, which demonstrated the ethanol confinement inside the halloysite cavi…

Sustained release Clay nanoparticles Drug loading Halloysite nanotubes Knudsen thermogravimetryMaterials scienceKineticsNanochemistryDiclofenac Sodiumengineering.materialHalloysiteThermogravimetryChemical engineeringengineeringKaoliniteMoleculeFourier transform infrared spectroscopySettore CHIM/02 - Chimica FisicaJournal of Nanostructure in Chemistry
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CD4+CD25+ regulatory T cells suppress mast cell degranulation and allergic responses through OX40-OX40L interaction.

2008

T regulatory (Treg) cells play a role in the suppression of immune responses, thus serving to induce tolerance and control autoimmunity. Here, we explored whether Treg cells influence the immediate hypersensitivity response of mast cells (MCs). Treg cells directly inhibited the FcεRI-dependent MC degranulation through cell-cell contact involving OX40-OX40L interactions between Treg cells and MCs, respectively. When activated in the presence of Treg cells, MCs showed increased cyclic adenosine monophosphate (cAMP) concentrations and reduced Ca2+ influx, independently of phospholipase C (PLC)-γ2 or Ca2+ release from intracellular stores. Antagonism of cAMP in MCs reversed the inhibitory effec…

T-LymphocytesCELLIMMUNO; Animals; Calcium; Cell Line Tumor; Gene Knockdown Techniques; Histamine Release; Humans; Hypersensitivity; Mast Cells; Membrane Glycoproteins; Mice; Mice Inbred BALB C; Mice Inbred C57BL; Phospholipase C gamma; Receptors OX40; T-Lymphocytes Regulatory; Tumor Necrosis Factors; Cell Degranulation; Immunology and Allergy; Infectious Diseases; ImmunologyInbred C57BLmedicine.disease_causeHistamine ReleaseT-Lymphocytes RegulatoryCell DegranulationAutoimmunityMicechemistry.chemical_compoundReceptorsImmunology and AllergyOX40Mast CellsInbred BALB CMice Inbred BALB CTumorMembrane GlycoproteinsDegranulationhemic and immune systemsRegulatoryhumanitiesCell biologyTregInfectious DiseasesGene Knockdown TechniquesTumor Necrosis FactorsMembrane GlycoproteinMast cell; Treg; OX40-OX40L interactionIntracellularHumanCell DegranulationImmunologyInfectious Diseasechemical and pharmacologic phenomenaBiologybehavioral disciplines and activitiesArticleCell LineMast cellImmune systemCell Line TumorHypersensitivitymedicineAnimalsHumansCyclic adenosine monophosphatePhospholipase CAnimalPhospholipase C gammaReceptors OX40Mice Inbred C57BLchemistryCELLIMMUNOCell cultureGene Knockdown TechniqueImmunologyOX40-OX40L interactionCalciumTumor Necrosis Factor
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Azobenzene Polyesters Used as Gate-Like Scaffolds in Nanoscopic Hybrid Systems

2012

The synthesis and characterisation of new capped silica mesoporous nanoparticles for on-command delivery applications is reported. Functional capped hybrid systems consist of MCM-41 nanoparticles functionalised on the external surface with polyesters bearing azobenzene derivatives and rhodamine¿B inside the mesopores. Two solid materials, Rh-PAzo8-S and Rh-PAzo6-S, containing two closely related polymers, PAzo8 and PAzo6, in the pore outlets have been prepared. Materials Rh-PAzo8-S and Rh-PAzo6-S showed an almost zero release in water due to steric hindrance imposed by the presence of anchored bulky polyesters, whereas a large delivery of the cargo was observed in the presence of an esteras…

TECNOLOGIA DE ALIMENTOSazo compoundsPolyestersenzymesNanoparticlemesoporous materialspolyestersCatalysischemistry.chemical_compoundDrug Delivery SystemsQUIMICA ORGANICAPolymer chemistryHumanschemistry.chemical_classificationOrganic ChemistryQUIMICA INORGANICAGeneral ChemistryPolymerMesoporous silicaHydrogen-Ion ConcentrationSilicon DioxideControlled releaseMesoporous materialsEnzymesPolyesterAzobenzenechemistryChemical engineeringDrug deliveryDrug deliverydrug deliveryNanoparticlesCamptothecinMesoporous materialAzo CompoundsPorosityHeLa Cells
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