Search results for " solution"
showing 10 items of 3084 documents
Partition of Indicaxanthin in Membrane Biomimetic Systems. A Kinetic and Modeling Approach
2009
The solubilization site of indicaxanthin (Ind) in lipid bilayers was investigated by the kinetics of Ind oxidation by peroxyl radicals in water and in aqueous/L-alpha-dipalmitoyl-phosphatidylcholine (DPPC) vesicles, pH 7.4, and 37.0 and 48.0 degrees C, that is, in a gel-like and a crystal liquidlike bilayer state, respectively. The time-dependent Ind absorbance decay, matched with a successful simulation of the reaction kinetic mechanism by Gepasi software, supported a multistep pathway. Computer-assisted analysis allowed calculation of the rate constants associated with the reactions involved, the values of which decreased with increasing DPPC concentration. The binding constant calculated…
Interaction of Novel Metal Complexes with DNA: Synthetic and Structural Aspects
2009
Metal ions bind to nucleic acids at various positions. This binding can be modulated by using metal complexes with appropriate ligands. Novel mono- and especially dinuclear metal complexes could be a powerful tool to detect rare, but still physiologically relevant, forms of DNA, e.g. the left-handed Z-DNA. In this review, our recent research activities in this area of bioinorganic chemistry are summarized. A special emphasis is laid on the synthetic challenges that arose upon the synthesis of the polyamine ligands. Further, some rather unusual approaches to elucidate the solution structure of copper bound to guanosine monophosphate with the help of pulsed EPR techniques like ENDOR and HYSC…
Crystal and solution structures of di-n-butyltin(IV) complexes of 5-[(E)-2-(4-methoxyphenyl)-1-diazenyl]quinolin-8-ol and benzoic acid derivatives: E…
2009
Abstract Reactions of nBu2SnCl(L1) (1), where L1 = acid residue of 5-[(E)-2-(4-methoxyphenyl)-1-diazenyl]quinolin-8-ol, with various substituted benzoic acids in refluxing toluene, in the presence of triethylamine, yielded dimeric mixed ligand di-n-butyltin(IV) complexes of composition [nBu2Sn(L1)(L2–6)]2 where L2 = benzene carboxylate (2), L3 = 2-[(E)-2-(2-hydroxy-5-methylphenyl)-1-diazenyl]benzoate (3), L4 = 5-[(E)-2-(4-methylphenyl)-1-diazenyl]-2-hydroxybenzoate (4), L5 = 2-{(E)-4-hydroxy-3-[(E)-4-chlorophenyliminomethyl]-phenyldiazenyl}benzoate (5) and L6 = 2-[(E)-(3-formyl-4-hydroxyphenyl)-diazenyl]benzoate (6). All complexes (1–6) have been characterized by elemental analyses, IR, 1H,…
Coordination abilities of N-methyl alkylaminomethane-1,1-diphosphonic acids towards zinc(II), magnesium(II) and calcium(II) metal ions. Equilibrium s…
2017
Abstract Complex-formation abilities of a series of N-methyl alkylaminomethane-1,1-diphosphonic acids (1–7) with a common tertiary nitrogen atom (CH3−N−R) bearing linear or branched alkyl, cycloheptyl or phenylalkyl R substituents towards zinc(II), magnesium(II) and calcium(II) in aqueous solution have been studied by means of pH-potentiometry, ESI-MS spectrometry, 1H NMR and 31P NMR methods. The obtained results indicate that in the all presented systems mononuclear protonated equimolar and bis complexes are formed. In acidic and neutral solution, the formation of the protonated dinuclear species has been confirmed. The comparative analysis of the potentiometric and NMR data reveal that th…
PEG 400/Cerium Ammonium Nitrate Combined with Microwave-Assisted Synthesis for Rapid Access to Beta-Amino Ketones. An Easy-to-Use Protocol for Discov…
2018
Compound libraries are important requirement in target-based drug discovery. In the present work, a small focused compound library based on β-aminoketone scaffold has been prepared combining microwave-assisted organic synthesis (MAOS) with polymer-assisted solution phase synthesis (PASPS) and replacing reaction workup standard purification procedures with solid phase extraction (SPE). Specifically, the effects of solvent, such as dioxane, dimethylformamide (DMF), polyethylene glycol 400 (PEG 400), temperature, irradiation time, stoichiometric ratio of reagents, and catalysts (HCl, acetic acid, cerium ammonium nitrate (CAN)) were investigated to maximize both conversion and yield. The optimi…
Solutions of the LPD equation and multi-parametric rogue waves
2022
Quasi-rational solutions to the Lakshmanan Porsezian Daniel equation are presented. We construct explicit expressions of these solutions for the first orders depending on real parameters. We study the patterns of these configurations in the (x, t) plane in function of the different parameters. We observe in the case of order 2, three rogue waves which move according to the two parameters. In the case of order 3, six rogue waves are observed with specific configurations moving according to the four parameters.
From particular polynomials to rational solutions to the mKdV equation
2022
Rational solutions to the modified Korteweg-de Vries (mKdV) equation are given in terms of a quotient of determinants involving certain particular polynomials. This gives a very efficient method to construct solutions. We construct very easily explicit expressions of these rational solutions for the first orders n = 1 until 10.
N order solutions with multi-parameters to the Boussinesq and KP equations and the degenerate rational case
2021
From elementary exponential functions which depend on several parameters, we construct multi-parametric solutions to the Boussinesq equation. When we perform a passage to the limit when one of these parameters goes to 0, we get rational solutions as a quotient of a polynomial of degree N (N + 1) − 2 in x and t, by a polynomial of degree N (N + 1) in x and t for each positive integer N depending on 3N parameters. We restrict ourself to give the explicit expressions of these rational solutions for N = 1 until N = 3 to shortened the paper. We easily deduce the corresponding explicit rational solutions to the Kadomtsev Petviashvili equation for the same orders from 1 to 3.
From particular polynomials to rational solutions to the PII equation
2022
The Painlevé equations were derived by Painlevé and Gambier in the years 1895 − 1910. Given a rational function R in w, w ′ and analytic in z, they searched what were the second order ordinary differential equations of the form w ′′ = R(z, w, w ′) with the properties that the singularities other than poles of any solution or this equation depend on the equation only and not of the constants of integration. They proved that there are fifty equations of this type, and the Painlevé II is one of these. Here, we construct solutions to the Painlevé II equation (PII) from particular polynomials. We obtain rational solutions written as a derivative with respect to the variable x of a logarithm of a…
Multi-parameters rational solutions to the mKdV equation
2021
N-order solutions to the modified Korteweg-de Vries (mKdV) equation are given in terms of a quotient of two wronskians of order N depending on 2N real parameters. When one of these parameters goes to 0, we succeed to get for each positive integer N , rational solutions as a quotient of polynomials in x and t depending on 2N real parameters. We construct explicit expressions of these rational solutions for orders N = 1 until N = 6.