Search results for " stability"
showing 10 items of 1355 documents
Slope units-based flow susceptibility model: using validation tests to select controlling factors
2011
A susceptibility map for an area, which is representative in terms of both geologic setting and slope instability phenomena of large sectors of the Sicilian Apennines, was produced using slope units and a multiparametric univariate model. The study area, extending for approximately 90 km2, was partitioned into 774 slope units, whose expected landslide occurrence was estimated by averaging seven susceptibility values, determined for the selected controlling factors: lithology, mean slope gradient, stream power index at the foot, mean topographic wetness index and profile curvature, slope unit length, and altitude range. Each of the recognized 490 landslides was represented by its centroid po…
Robust H-Infinity Filter Design for Uncertain Linear Systems Over Network with Network-Induced Delays and Output Quantization
2009
This paper investigates a convex optimization approach to the problem of robust H-Infinity filtering for uncertain linear systems connected over a common digital communication network. We consider the case where quantizers are static and the parameter uncertainties are norm bounded. Firstly, we propose a new model to investigate the effect of both the output quantization levels and the network conditions. Secondly, by introducing a descriptor technique, using Lyapunov-Krasovskii functional and a suitable change of variables, new required sufficient conditions are established in terms of delay-dependent linear matrix inequalities (LMIs) for the existence of the desired network-based quantize…
Flots de Smale en dimension 3: présentations finies de voisinages invariants d'ensembles selles
2002
Abstract Given a vector field X on a compact 3-manifold, and a hyperbolic saddle-like set K of that vector field, we consider all the filtering neighbourhood of K: by such, we mean any submanifold which boundary is tranverse to X, the maximal invariant of which is equal to K and which intersection with every orbit of X is connected. Up to topological equivalence, there is only a finite number of such neighbourhoods. We give a finite combinatorial presentation of the global dynamics on any such neighbourhood. A key step is the construction of a unique model of the germ of X along K; this model is, roughly speaking, the simplest three-dimensional manifold and the simplest Smale flow exhibitin…
Chiral donor–π-acceptor azobenzene dyes
2009
Abstract Four chiral donor–π-acceptor azobenzene dye conjugates were synthesized and characterized. Chiral moieties, namely (S)-(+)-2-(6-methoxy-2-naphthyl)propionic acid (naproxen) and (S)-2-aminopropionic acid ( l -alanine), were attached to either the donor end or the acceptor site of the azo compound using ester or amide bonds, respectively. The structures of the molecules were verified using 1H NMR, 13C NMR and ESI TOF mass spectrometry; spectral properties were evaluated with UV–vis and CD spectrometry whilst thermal stability was determined by TGA. The compounds displayed a broad absorption maximum in the visible region between 433 and 483 nm. All compounds showed relatively high the…
The Other J.M.: John Maurice Clark and the Keynesian Revolution
2009
This paper suggests that Clark's views regarding the Keynesian Revolution illuminate some of the limitations of the Keynesian orthodoxy that developed after the war, bringing more institutional detail and a greater preoccupation with dynamic analysis. Clark developed the multiplier in dynamic terms and coupled it with the accelerator to provide the framework for business cycle theory. His analysis was not formalized and emphasized time lags and non-linearities, similar to Harrod. In addition, Clark was concerned with the inflationary consequences of Keynesian policies and he was dissatisfied with those mechanical interpretations of the income flow analysis, which came to be known as hydraul…
Effect of linker distribution in the photocatalytic activity of multivariate mesoporous crystals
2021
The use of Metal-Organic Frameworks as crystalline matrices for the synthesis of multiple component or multivariate solids by the combination of different linkers into a single material has emerged as a versatile route to tailor the properties of single-component phases or even access new functions. This approach is particularly relevant for Zr6-MOFs due to the synthetic flexibility of this inorganic node. However, the majority of materials are isolated as polycrystalline solids, which are not ideal to decipher the spatial arrangement of parent and exchanged linkers for the formation of homogeneous structures or heterogeneous domains across the solid. Here we use high-throughput methodologi…
Thermal stability, structural properties and catalytic activity of Pd catalysts supported on Al2O3–CeO2–BaO mixed oxides prepared by sol–gel method
2003
Abstract Al2O3–CeO2–BaO oxides with constant Al/Ba mass ratio and increasing cerium content were prepared, using the sol–gel procedure, and calcined at 1000 °C for 5 h. The influence of barium oxide on the thermal stability and on the morphological and structural properties of the corresponding supports, in terms of increasing surface area of alumina and ceria dispersion, was studied. The corresponding Pd (1 wt.%) catalysts were prepared by a stepwise impregnation method with a solution of palladium acetylacetonate in benzene. Palladium was introduced in two sequential steps by impregnation 0.5 wt.% of Pd each time. The structural and textural properties of the materials were studied by X-r…
Ab Initio Study of BiFeO3: Thermodynamic Stability Conditions
2015
BiFeO3 is investigated intensively, mainly as a multiferroic material. In this paper, the state-of-the-art ab initio hybrid functional approach with atomic basis sets was employed for a study of the stability range of BiFeO3 with respect to its decomposition into binary oxides and elementary metals, as a function of temperature and oxygen partial pressure. The calculated atomic and electronic structure of BiFeO3 was compared with previous LDA+U calculations using plane-wave basis sets. Based on performed calculations, the phase diagram was constructed, which allows us to predict the stability region of stoichiometric BiFeO3.
Coordinating properties of the Cephalexine antibiotic. A potentiometric study of the complexes formation between Cephalexine and Co(II), Ni(II) and C…
1989
Abstract The formation of complexes between Co(II), Ni(II) and Cu(II) with Cephalexine has been investigated using potentiometric techniques. The stability constants of the complexes formed were calculated using the non-linear least-squares computer program SUPERQUAD. The obtained values were: Co(II) logβ1=2.40, logβMLOH=8.89; Ni(II) logβ1=2.80, logβ2=5.10, logβML2OH=12.09; Cu(II) logβ1=4.094 (25 °C, 0.1 M KNO3). The compound [Ni(CEX)(OH2)4]BPh4 has been synthesized and characterized by electronic, IR and NMR spectroscopies as well as by magnetic measurements. From these studies it is proposed that the Cephalexinate anion acts as a bidentate ligand and is bound to the metal ion through the …
MR3090050 Reviewed Belabbas, Mohamed Ali On global stability of planar formations. IEEE Trans. Automat. Control 58 (2013), no. 8, 2148–2153. (Reviewe…
2014
The focus of the paper is planar formation control, i.e. the design of control laws to stabilize agents at given distances from each other, under the constraint that the dynamics of each agent only depends on a subset of the other agents. The main contribution of the paper is the following: It is shown that a simple four-agent formation cannot be globally stabilized using twice differentiable control laws (this is not the case for three-agent formations), even up to sets of measure zero of initial conditions. This suggests that for four-agent formations one needs to look for control laws that are either not differentiable (or even not continuous) or of higher order in the dynamics. The appr…